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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 45,
  • Issue 5,
  • pp. 916-917
  • (1991)

Absorption Cross Sections of Gaseous Dimethylnitramine at Selected Wavelengths between 185 and 325 nm

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Abstract

Dimethylnitramine (DMNA), (CH<sub>3</sub>)<sub>2</sub>N-NO<sub>2</sub>, has been extensively studied as a simple analog expected to exhibit some of the processes important in cyclic nitramine decomposition. Although many of these studies include its gas-phase dissociation following excitation with UV radiation, a reference for its gas-phase UV absorption cross sections has not been established. Since this is an important parameter in analyzing the results of DMNA dissociation, we report our results for room-temperature DMNA. Absorption cross sections at selected wave-lengths between 185 and 325 nm have been calculated from UV absorbance spectra with the use of Beer-Lambert's law.

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