Spectrum and energy levels of four-times ionized zirconium (Zr v)

Joseph Reader; Nicolo Acquista

doi:10.1364/JOSA.69.000239

Journal of the Optical Society of America
Vol. 69,
Issue 2,
pp. 239-253
(1979)
•https://doi.org/10.1364/JOSA.69.000239

Spectrum and energy levels of four-times ionized zirconium (Zr v)

Joseph Reader and Nicolo Acquista

Not Accessible

Your library or personal account may give you access

Get PDF
Email
Share
Get Citation
Copy Citation Text
Joseph Reader and Nicolo Acquista, "Spectrum and energy levels of four-times ionized zirconium (Zr v)," J. Opt. Soc. Am. 69, 239-253 (1979)

Export Citation
- BibTex
- Endnote (RIS)
- HTML
- Plain Text
Citation alert
Save article

Abstract

The spectrum of zirconium was observed in the region from 200 to 2670 Å with a sliding-spark discharge on the 10.7-m normal-and grazing-incidence spectrographs at NBS. About 580 lines were assigned to Zr v. From these observations the energy level system of Zr v (Kr i isoelectronic sequence, ground state 4s ²4p ^{6 1}S₀) has been extended to the complete 4s ² 4p ⁵ 5s, 6s, 7s, 5p, 4d, 5d, 4f, 5g, and 4s 4p ⁶ 4d configurations and the nearly complete 4s ²4p ⁵ 6d and 6g configurations. About 330 lines have been classified. All observed configurations have been theoretically interpreted. The energy parameters determined by least-squares fits to the observed levels are compared with Hartree-Fock calculations. The ionization energy derived from the 4p ⁵ n g, n = 5,6 levels is 648 050 ± 60 cm⁻¹ (80.349 ± 0.007 eV).

Full Article | PDF Article

More Like This

Spectrum and energy levels of eleven-times ionized zirconium (Zr xii)

Joseph Reader and Nicolo Acquista
J. Opt. Soc. Am. 69(12) 1659-1662 (1979)

Spectrum and energy levels of triply ionized zirconium (Zr iv)

Nicolo Acquista and Joseph Reader
J. Opt. Soc. Am. 70(7) 789-792 (1980)

Spectrum and energy levels of triply ionized yttrium (Y iv)

Gabriel L. Epstein and Joseph Reader
J. Opt. Soc. Am. 72(4) 476-492 (1982)

Previous Article Next Article

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Figures (7)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (8)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (333)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Observed spectral lines of Zr v. All wavelengths are in vacuum. Except for the 4p⁶, 4s4p⁶ 4d, and 4s4p⁶ 5p configurations, the levels given for the line classifications are all based on the 4p^{5 2}P core. The 4p⁶, 4p⁵ 4d, 4s4p⁶ 4d, and 4s4p⁶ 5p configurations are designated in LS coupling, all others in J₁l. Symbols: p, perturbed by close line; u, unresolved from close line.

Wavelength (Å)	Intensity	Wave number (cm⁻¹)	Classification
165.257	1	605 118	$4 p^{6} {¹ S}_{0} - 10 s 3 / 2 {[3 / 2]}_{1}^{°}$
168.943	1	591 916	$4 p^{6} {¹ S}_{0} - 9 s 3 / 2 {[3 / 2]}_{1}^{°}$
170.392	2	586 882	$4 p^{6} {¹ S}_{0} - 8 s 1 / 2 {[1 / 2]}_{1}^{°}$
171.403	1	583 420	$4 p^{6} {¹ S}_{0} - 7 d 1 / 2 {[3 / 2]}_{1}^{°}$
174.286	3	573 770	$4 p^{6} {¹ S}_{0} - 4 s 4 p^{6} 5 p {¹ P}_{1}^{°}$
175.016	2	571 377	$4 p^{6} {¹ S}_{0} - 8 s 3 / 2 {[3 / 2]}_{1}^{°}$
176.043	2	568 042	$4 p^{6} {¹ S}_{0} - 7 d 3 / 2 {[3 / 2]}_{1}^{°}$
180.988	7	552 522	$4 p^{6} {¹ S}_{0} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
183.042	20	546 323	$4 p^{6} {¹ S}_{0} - 6 d 1 / 2 {[3 / 2]}_{1}^{°}$
186.146	30	537 213	$4 p^{6} {¹ S}_{0} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
188.027	50	531 839	$4 p^{6} {¹ S}_{0} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
189.248	25p	528 406	$4 p^{6} {¹ S}_{0} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
204.798	80	488 286	$4 p^{6} {¹ S}_{0} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
209.872	100	476 480	$4 p^{6} {¹ S}_{0} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
211.339	100	473 173	$4 p^{6} {¹ S}_{0} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
216.307	125	462 306	$4 p^{6} {¹ S}_{0} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
220.310	30	453 906	$4 p^{6} {¹ S}_{0} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
280.779	40	356 152
284.333	20p	351 700
292.187	300	342 246	$4 p^{6} {¹ S}_{0} - 5 s 1 / 2 {[1 / 2]}_{1}^{°}$
294.570	30	339 478
294.938	40	339 054
295.159	70	338 800
297.480	60p	336 158
297.779	30p	335 797
298.190	70	335 357
298.316	50	335 215
298.427	70	335 090
298.533	80	334 971
298.813	70p	334 658
298.946	30	334 509
298.979	30	334 472
299.399	30	334 002
299.663	30	333 708
299.890	50	333 456
300.391	60p	332 884.5
300.673	30p	332 587.5
300.748	40p	332 504.5
301.587	20p	331 579.7
301.634	50p	331 527.5
301.958	80p	331 171.8
302.150	20	330 961.0
302.505	50	330 572.8
303.380	20p	329 619.9
303.752	20	329 215.5
303.831	30p	329 130.1
304.008	500	328 938.7	$4 p^{6} {¹ S}_{0} - 4 d {¹ P}_{1}^{°}$
304.076	60	328 864.6
304.142	80p	328 794.2
304.380	30	328 536.6
304.414	20	328 499.7
304.527	80p	328 377.8
305.236	300	327 615.4	$4 p^{6} {¹ S}_{0} - 5 s 3 / 2 {[3 / 2]}_{1}^{°}$
305.425	30	327 412.8
305.459	70	327 676.1
306.698	30	326 028.5
306.904	60p	325 834.4
307.236	30	325 482.8
307.753	60p	524 936.2
308.321	50p	324 337.1
308.489	80	324 161.1
308.621	60	324 021.9
308.857	20	323 744.8
309.421	30	323 184.7
309.728	15p	322 863.7
310.326	30	322 242.0
310.508	10	322 053.3
310.928	90	321 618.3
311.252	60	321 283.4
312.100	20	320 409.7
313.050	30	319 437.3
313.954	80	318 518.3
314.488	90	317 976.7
314.628	50	317 835.7
315.308	70	317 149.9
315.440	20p	317 017.5
317.280	40	315 179.0
317.298	40	315 161.1
319.842	60	312 654.4
321.845.	10	310 708.7
322.954	10	309 670.4
322.999	30	309 598.9
324.785	70p	307 896.4
325.030	70	307 663.9
325.213	50	307 490.7
325.410	30p	307 304.8
326.087	80	306 666.3
327.536	30p	305 309.7
329.271	30p	303 701.3
329.752	20	303 258.6
330.217	20	302 831.2
330.528	30	302 546.3
330.851	60	302 256.6
331.789	10	301 396.5
332.316	30p	300 918.1
333.007	30	300 294.1
333.232	60	300 091.0
333.945	60p	299 450.2
334.863	3	298 629.4
335.233	10	298 299.5
337.670	40	296 147.2
337.932	20	295 917.6
341.002	30	293 253.5
346.419	20	288 668.2
356.429	40	280 560.7
356.528	20	280 483.0
362.226	30	276 070.4
368.184	400p	271 603.3	$4 p^{6} {¹ S}_{0} - 4 d {³ D}_{1}^{°}$
368.441	30p	271 413.9
372.724	10p	268 295.0
373.218	20	267 939.6
376.582	10	265 546.4
377.293	10	265 046.6
378.680	10p	264 075.2
378.935	30	263 897.4
383.917	40	260 473.0
386.214	30	258 924.0
386.866	15	258 487.7
388.330	80	257 512.9
389.971	20	256 429.3
390.740	40	255 924.7
391.804	15	255 299.7
392.248	20	254 940.5
392.926	30	254 500.8
394.546	40	253 455.9
397.024	10	251 873.9
399.107	10	250 559.4
410.425	25	243 471.6
410.572	100p	243 562.6	$4 p^{6} {¹ S}_{0} - 4 d {³ P}_{1}^{°}$
411.291	40	243 136.9
429.983	7	232 567.3	$4 d {³ P}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
442.963	80	225 752.3	$4 d {³ P}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{3}$
453.610	30	220 453.9	$4 d {³ P}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
456.425	80	219 094.1	$4 d {³ P}_{0}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
458.698	40	218 008.6	$4 d {³ F}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{4}$
460.549	90	217 132.0	$4 d {³ P}_{1}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
461.009	80	216 915.5	$4 d {³ P}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
462.852	15	216 052.0	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
468.577	50	213 412.2	$4 d {³ F}_{2}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
469.917	90	212 803.6	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
470.078	70	212 730.8	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
470.558	6	212 513.7	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
477.364	50	209 483.7	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
482.745	70	207 148.6	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
483.060	50	207 013.7	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
483.231	60	206 940.5	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
483.902	60	206 653.4	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
485.632	50p	205 917.2	$4 d {³ D}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{4}$
486.454	40	205 569.3	$4 d {¹ D}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
488.571	70	204 678.5	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
488.929	90	204 528.5	$4 d {³ D}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
490.694	90	203 793.0	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{3}$
491.628	3	203 405.7	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
491.804	60	203 333.0	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
491.993	70	203 255.0	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
492.331	20	203 115.4	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
494.077	150	202 397.4	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[9 / 2]}_{5}$
494.629	15	202 171.7	$4 d {³ P}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
496.338	20	201 475.7	$4 d {³ D}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
498.046	150	200 784.7	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
499.471	125	200 211.8	$4 d {¹ D}_{2}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
499.535	125	200 186.1	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[7 / 2]}_{3}$
502.361	125	199 060.0	$4 d {³ D}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{3}$
508.727	70	196 569.2	$4 d {¹ F}_{3}^{°} - 4 f 1 / 2 {[5 / 2]}_{3}$
509.218	6	196 379.6	$4 d {³ F}_{3}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
509.896	8	196 118.6	$4 d {³ D}_{2}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
513.027	125	194 921.5	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
513.220	30	194 848.2	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
513.830	150	194 617.0	$4 d {¹ F}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{4}$
516.455	60	193 627.6	$4 d {¹ F}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
517.244	90	193 332.4	$4 d {³ P}_{0}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
518.746	150	192 772.6	$4 d {³ F}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
519.248	200	192 586.3	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
519.715	150	192 413.1	$4 d {³ D}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
520.170	60	192 244.9
520.296	125	192 198.1	$4 d {³ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
523.141	90	191 153.0	$4 d {³ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
525.943	50	190 134.8	$4 d {¹ D}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
527.106	125	189 715.1	$4 d {³ P}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
528.843	40	189 092.2	$4 d {³ D}_{1}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
529.452	70	188 874.4	$4 d {³ D}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
529.963	90	188 692.4	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
532.495	80	187 795.3	$4 d {³ P}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
534.802	90	186 985.2	$4 d {¹ D}_{2}^{°} - 4 f 3 / 2 {[7 / 2]}_{3}$
535.133	40	186 869.3	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
536.498	200	186 394.0	$4 d {³ F}_{4}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
537.310	100	186 112.4	$4 d {³ D}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
537.521	100	186 039.4	$4 d {³ D}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
538.087	30	185 843.4
538.153	80	185 820.8	$4 d {³ D}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
542.629	70	184 288.1	$4 d {³ D}_{3}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
543.704	90	183 923.5	$4 d {³ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
544.598	20	183 621.7	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
549.432	150	182 006.3	$4 d {³ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
551.609	60	181 287.8	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
556.873	100	179 574.3	$4 d {¹ D}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
560.121	100	178 533.0	$4 d {³ D}_{1}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
560.543	60	178 398.5	$4 d {³ F}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
563.717	100	177 394.0	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
563.844	100	177 354.0	$4 d {³ F}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
569.864	90	175 4 80.5	$4 d {³ D}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
574.280	150	174 131.1
578.069	100	172 989.8	$4 d {¹ F}_{3}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
581.952	2p	171 835.5	$4 d {³ D}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
583.380	50	171 414.9
589.559	50	169 618.2
591.914	40	168 929.3
592.379	30	168 810.9
592.946	60	168 649.4
595.426	60	167 949.0
599.343	60	166 849.3
601.229	80	166 325.9
604.893	1	165 318.5	$5 p 3 / 2 {[1 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
605.336	100	165 197.4	$4 d {¹ D}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
606.536	20p	164 870.8	$5 p 3 / 2 {[1 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
609.187	100	164 153.2	$4 d {¹ D}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
613.074	40	163 112.5	$4 d {³ D}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
613.411	100	163 022.9	$4 d {³ D}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
621.862	40	160 807.4
622.929	90	160 531.9	$4 d {¹ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
623.769	30	160 315.8	$5 p 3 / 2 {[5 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
623.988	5	1602 59.6	$5 p 1 / 2 {[3 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{0}^{°}$
625.525	20	159 865.8	$5 p 3 / 2 {[5 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
628.428	90	159 127.2	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
630.463	80	158 613.6	$4 d {¹ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
632.869	80	158 010.5	$5 p 3 / 2 {[5 / 2]}_{3} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
635.368	15	157 389.1	$5 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
638.867	50	156 527.1	$5 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
638.867	50	156 527.1	$5 p 1 / 2 {[3 / 2]}_{2} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
639.560	30	156 357.6	$5 p 3 / 2 {[3 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
639.606	10p	156 346.1
639.688	15	156 326.3
640.122	4	156 220.3	$5 p 1 / 2 {[1 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
641.196	9	155 958.6	$5 p 1 / 2 {[1 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{0}^{°}$
645.500	90	154 918.7	$4 d {³ P}_{0}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
648.389	15	154 228.5	$5 p 3 / 2 {[3 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
649.574	50	153 946.9
650.066	30	153 830.5
650.283	40	153 779.1	$5 p 3 / 2 {[3 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
650.427	15	153 745.2
650.821	10	153 652.1
652.177	60	153 332.7
652.647	15	153 222.3	$5 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
654.513	15	152 785.5
654.710	90	152 739.4	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
656.020	15	152 434.4	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
656.159	60	152 402.0	$5 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
657.387	60	152 117.4
659.143	20	151 712.1	$5 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
661.055	10	151 273.4
661.702	40	151 125.4
662.324	10	150 983.5	$5 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
664.250	3	150 545.7	$5 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
664.635	10	150 458.6
664.857	60	150 408.2	$5 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[7 / 2]}_{4}^{°}$
666.467	30	150 044.9
667.409	2	149 833.1	$5 p 1 / 2 {[1 / 2]}_{0} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
669.703	30	149 319.9
669.954	25	149 264.0	$5 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
673.340	60	148 513.4	$5 p 3 / 2 {[3 / 2]}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
673.686	100	148 437.1	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
674.034	5	148 360.5	$5 p 3 / 2 {[1 / 2]}_{0} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
674.134	200p	148 338.5	$4 d {³ P}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
675.342	30	148 073.0
675.526	200	148 032.8	$4 d {³ P}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
675.865	15	147 958.6
677.663	15	147 566.0	$5 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
678.056	50	147 480.4	$5 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
679.394	300	147 190.0	$4 d {¹ P}_{1}^{°} - 6 f 1 / 2 {[5 / 2]}_{2}$
683.536	5	146 298.0	$5 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
687.576	40	145 438.4	$5 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
688.268	200	145 292.2	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
690.520	100	144 818.4
703.026	200p	142 242.3	$4 d {³ F}_{3}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
712.488	40	140 353.2
712.855	50	140 281.1
713.053	40	140 242.1
716.978	150	139 474.3	$4 d {³ P}_{0}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
717.236	300	139 424.2	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
719.739	100	138 939.2	$4 d {³ F}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
721.323	150	138 634.1	$4 d {³ F}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
724.454	60	137 792.2
728.741	40	137 222.9
730.188	40	136 951.0
730.430	10	136 905.7
733.148	60	136 398.1	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
733.413	30	136 348.9
734.941	60	136 065.3	$4 s 4 p^{6} 4 d {³ D}_{1} - 6 g 3 / 2 {[5 / 2]}_{2}^{°}$
740.331	200	135 074.7	$4 d {¹ P}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
740.613	2000	135 023.3	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
742.181	25	134 738.0
742.736	500	134 637.3	$4 d {³ F}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
744.018	50	134 437.4
744.753	60	134 272.8
746.913	30	133 884.4	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
748.538	40	133 593.8	$4 s 4 p^{6} 4 d {³ D}_{3} - 6 g 3 / 2 {[7 / 2]}_{4}^{°}$
749.810	30	133 367.1
749.977	90	133337.4	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
752.020	40	132 975.2
752.484	300	132 893.1	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
753.160	30	132 773.9
754.582	20	132 523.8
756.107	70	132 256.4
762.852	70	131 087.1	$4 d {³ D}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
764.578	300	130 791.2	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
766.200	500	130 514.3	$4 d {³ P}_{0}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
766.388	20	130 482.1
769.567	15	129 943.2
771.180	20	129 671.4
773.804	200	129 231.6	$4 d {³ F}_{3}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
775.582	200	128 935.4	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
779.210	200	128 335.1	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
783.520	30	127 629.1
784.496	400	127 470.4	$4 d {³ F}_{4}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
785.350	80	127 331.8
785.481	40	137 310.5
795.295	100	125 739.5	$4 d {¹ D}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
796.029	100	125 623.6	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
797.227	400	125 434.7	$4 d {¹ D}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
797.780	50	125 347.8
800.001	10 000	124 999.8	$4 d {³ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
800.301	50	124 953.0
801.929	70	124 699.3	$4 d {³ D}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
803.902	60	124 393.2
806.887	10 000	123 933.2	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
808.810	80	123 638.5
809.419	20	123 545.4
809.754	200	123 494.3	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
812.052	10 000	123 144.8	$4 d {³ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
812.398	40	123 092.3
812.577	30	123 064.3
813.074	20	122 990.0
816.209	100	122 517.6	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
821.221	60	121 769.9	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
822.055	500	121 646.4	$4 d {³ D}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
822.415	60	121 593.1
823.461	300p	121 438.7	$4 d {¹ D}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
823.779	200	121 391.8	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
825.129	200	121 193.2	$4 d {¹ P}_{1}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
825.263	40p	121 173.5	$4 s 4 p^{6} 4 d {¹ D}_{2} - 6 g 3 / 2 {[7 / 2]}_{3}^{°}$
828.531	10u	120 695.5	$4 s 4 p^{6} 4 d {¹ D}_{2} - 6 g 3 / 2 {[5 / 2]}_{3}^{°}$
830.586	200	120 396.9	$4 d {³ D}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
836.566	400	119 536.3	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
841.399	3 000	118 849.7	$4 d {¹ F}_{3}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
849.110	30u	117 770.3	$4 f 3 / 2 {[9 / 2]}_{5} - 6 g 3 / 2 {[9 / 2]}_{5}^{°}$
851.390	70	117 455.0
852.764	90	117 265.7	$4 f 3 / 2 {[9 / 2]}_{5} - 6 g 3 / 2 {[11 / 2]}_{6}^{0}$
852.868	300p	117 251.4	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
853.429	60	117 174.3	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 1 / 2 {[7 / 2]}_{3}^{°}$
853.684	700	117 139.4	$4 d {³ D}_{3}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
855.399	20	116 904.5	$4 f 3 / 2 {[9 / 2]}_{4} - 6 g 3 / 2 {[9 / 2]}_{4}^{°}$
858.892	100	116 429.0	$4 f 3 / 2 {[9 / 2]}_{4} - 6 g 3 / 2 {[11 / 2]}_{5}^{°}$
859.126	15	116 397.3	$5 p 3 / 2 {[1 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
862.480	90	115 944.7	$4 f 1 / 2 {[7 / 2]}_{3} - 6 g 1 / 2 {[9 / 2]}_{4}^{°}$
862.674	20	115 918.6
863.561	60	115 799.6
867.930	40	115 216.6	$4 s 4 p^{6} 4 d {³ D}_{3} - 5 g 1 / 2 {[7 / 2]}_{4}^{°}$
869.776	100	114 972.1	$4 f 1 / 2 {[7 / 2]}_{4} - 6 g 1 / 2 {[9 / 2]}_{5}^{°}$
873.106	200	114 533.6	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
873.400	30	114 495.1
877.985	100	113 897.2	$4 f 3 / 2 {[7 / 2]}_{3} - 6 g 3 / 2 {[9 / 2]}_{4}^{°}$
884.799	100	113 020.1	$4 f 3 / 2 {[7 / 2]}_{4} - 6 g 3 / 2 {[9 / 2]}_{5}^{°}$
885.038	80	112 989.5	$4 f 1 / 2 {[5 / 2]}_{3} - 6 g 1 / 2 {[7 / 2]}_{4}^{°}$
885.481	30	112 933.0
885.679	300	112 907.7	$4 d {³ D}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
886.216	30	112 839.3	$4 f 3 / 2 {[7 / 2]}_{4} - 6 g 3 / 2 {[7 / 2]}_{4}^{°}$
887.596	10	112 663.9	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
888.610	3	112 535.3	$4 f 3 / 2 {[7 / 2]}_{4} - 6 g 3 / 2 {[11 / 2]}_{5}^{°}$
889.492	80	112 423.7	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
890.414	30	112 307.3
895.605	60	111 656.4
897.801	80	111 383.3	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
900.476	300	111 052.4	$4 d {³ D}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
904.941	100	110 504.4	$4 f 3 / 2 {[5 / 2]}_{3} - 6 g 3 / 2 {[7 / 2]}_{4}^{°}$
905.989	50	110 388.8
906.606	90p	110 301.4	$4 f 3 / 2 {[3 / 2]}_{1} - 6 g 3 / 2 {[5 / 2]}_{2}^{°}$
906.663	500	110 294.6	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
907.984	60	110 134.1	$4 f 3 / 2 {[5 / 2]}_{2} - 6 g 3 / 2 {[5 / 2]}_{3}^{°}$
908.590	15	110 060.6	$4 f 3 / 2 {[5 / 2]}_{3} - 6 g 3 / 2 {[5 / 2]}_{3}^{°}$
915.123	60	109 274.9
915.300	500	109 253.8	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
915.829	60	109 190.7
923.100	400	108 330.6	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
924.276	100	108 192.8	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
924.710	10	108 142.0	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
932.046	80	107 290.8	$4 f 3 / 2 {[3 / 2]}_{2} - 6 g 3 / 2 {[7 / 2]}_{3}^{°}$
932.793	80	107 204.9
933.763	30	107 093.5
936.170	100	106 818.2	$4 d {¹ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
936.201	70	106 814.6
940.408	400	106 336.8	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
941.612	150	106 200.9	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
943.480	80	105 990.5
944.187	70	105 911.3
944.828	150	105 839.4	$4 d {¹ F}_{3}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
945.396	50p	105 775.8	$4 d {¹ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
949.705	200	105 295.8	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
960.626	150	104 098.8	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
974.361	30	102 631.4
978.062	200	102 243.0	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
978.257	70	102 222.6
980.704	200	101 967.6	$4 s 4 p^{6} 4 d {³ D}_{1} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
982.518	40	101 779.3	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
984.176	200	101 607.8	$4 d {¹ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
986.080	40	101 411.6
986.832	80	101 334.3	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
990.369	150	100 972.5	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
990.842	40	100 924.3	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
995.590	300	100 443.0	$5 p 3 / 2 {[1 / 2]}_{1} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
997.073	150	100 293.6	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
998.801	30	100 120.0	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1001.765	150	99 823.77	$4 s 4 p^{6} 4 d {³ D}_{3} - 5 g 3 / 2 {[7 / 2]}_{4}^{°}$
1002.484	400	99 752.22	$4 d {¹ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
1005.633	30	99 439.86	$5 p 3 / 2 {[1 / 2]}_{0} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1009.560	15	99 053.11	$4 s 4 p^{6} 4 d {³ D}_{3} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1028.380	100	97 240.30	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
1038.690	400	96 275.08	$5 p 3 / 2 {[5 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1044.407	200	95 748.10	$5 p 1 / 2 {[3 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{0}^{°}$
1045.779	30	95 622.50	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1045.779	30	95 622.50	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1047.774	300	95 440.41	$5 p 3 / 2 {[5 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1048.970	20	95 331.57	$4 f 3 / 2 {[7 / 2]}_{3} - 5 g 1 / 2 {[9 / 2]}_{4}^{°}$
1051.329	60	95 117.74	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1058.619	5	94 462.71	$4 f 3 / 2 {[7 / 2]}_{4} - 5 g 1 / 2 {[9 / 2]}_{5}^{°}$
1066.486	50	93 765.86	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1068.551	400	93 584.69	$5 p 3 / 2 {[5 / 2]}_{3} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1069.220	30	93 526.16
1072.247	300	93 262.10	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1081.142	60	92 494.76
1081.412	60	92 471.73
1083.452	300	92 297.60	$5 p 1 / 2 {[3 / 2]}_{2} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1085.458	20p	92 126.96	$4 f 3 / 2 {[5 / 2]}_{3} - 5 g 1 / 2 {[7 / 2]}_{4}^{°}$
1087.047	200	91 992.36	$5 p 1 / 2 {[1 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1093.100	90	91 482.97	$5 p 3 / 2 {[3 / 2]}_{1} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1093.537	200	91 446.39	$5 p 1 / 2 {[1 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{0}^{°}$
1101.502	30	90 785.14
1105.566	40	90 451.42	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1108.794	200	90 188.06	$5 p 3 / 2 {[3 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1114.688	60	89 711.22
1115.533	90	89 643.27
1116.878	20	89 535.32	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1118.693	70	89 390.02
1123.205	50	89 030.95	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1130.152	70	88 483.71
1131.914	70	88 345.94
1132.230	5	88 321.28	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1132.377	60	88 309.78
1134.612	15	88 135.87
1141.223	100	87 625.30	$5 p 3 / 2 {[1 / 2]}_{0} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1142.552	50	87 523.40
1144.089	150	87 405.76	$4 s 4 p^{6} 4 d {¹ D}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
1144.583	15	87 368.05
1145.447	20	87 302.18
1154.761	100	86 598.04	$4 s 4 p^{6} 4 d {¹ D}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1166.603	100	85 718.97	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
1168.163	150	85 604.47	$5 p 1 / 2 {[1 / 2]}_{0} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1183.734	80	84 478.45	$5 p 1 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1185.965	5	84 319.49	$5 p 3 / 2 {[1 / 2]}_{0} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1188.556	5	84 135.72	$4 f 3 / 2 {[9 / 2]}_{5} - 5 g 3 / 2 {[9 / 2]}_{5}^{°}$
1194.240	300	83 735.24	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1200.761	300	83 280.55	$4 f 3 / 2 {[9 / 2]}_{5} - 5 g 3 / 2 {[11 / 2]}_{6}^{°}$
1200.938	60	83 268.27	$4 f 3 / 2 {[9 / 2]}_{4} - 5 g 3 / 2 {[9 / 2]}_{4}^{°}$
1212.935	100p	82 444.67	$4 f 3 / 2 {[9 / 2]}_{4} - 5 g 3 / 2 {[11 / 2]}_{5}^{°}$
1217.957	90	82 104.71	$4 f 1 / 2 {[7 / 2]}_{3} - 5 g 1 / 2 {[9 / 2]}_{4}^{°}$
1227.720	100p	81 451.78	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
1232.557	100	81 132.13	$4 f 1 / 2 {[7 / 2]}_{4} - 5 g 1 / 2 {[9 / 2]}_{5}^{°}$
1233.911	200	81 043.13	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{0}^{°}$
1238.927	300	80 715.01	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
1245.952	150	80 259.91	$4 f 3 / 2 {[7 / 2]}_{3} - 5 g 3 / 2 {[9 / 2]}_{4}^{°}$
1247.248	30	80 176.50	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1253.607	300	79 769.80	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[5 / 2]}_{3}^{°}$
1259.696	200	79 384.23	$4 f 3 / 2 {[7 / 2]}_{4} - 5 g 3 / 2 {[9 / 2]}_{5}^{°}$
1260.914	400	79 307.54	$5 p 1 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1262.962	100	79 179.07	$4 f 1 / 2 {[5 / 2]}_{3} - 5 g 1 / 2 {[7 / 2]}_{4}^{°}$
1265.380	500	79 027.64	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[7 / 2]}_{3}^{°}$
1270.119	80	787 32.79	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1295.809	300	77 171.88	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[7 / 2]}_{3}^{°}$
1298.576	90	77 007.44	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1300.770	150	76 877.55	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1301.321	70	76 844.99	$4 f 3 / 2 {[5 / 2]}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
1302.027	80	76 803.32	$4 f 1 / 2 {[5 / 2]}_{2} - 5 g 1 / 2 {[7 / 2]}_{3}^{°}$
1302.804	400	76 757.51	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
1303.195	100p	76 734.49	$4 f 3 / 2 {[5 / 2]}_{3} - 5 g 3 / 2 {[7 / 2]}_{4}^{°}$
1303.933	500	76 691.03	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[7 / 2]}_{4}^{°}$
1306.764	400	76 524.89	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1312.247	60	76 205.17	$4 f 3 / 2 {[3 / 2]}_{1} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
1315.142	200	76 037.42	$5 p 1 / 2 {[1 / 2]}_{1} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1315.142	200	76 037.42	$4 f 3 / 2 {[5 / 2]}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1315.442	100	76 020.08	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1315.997	10	75 988.02	$4 f 3 / 2 {[5 / 2]}_{2} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
1316.414	6	75 963.94	$4 f 3 / 2 {[5 / 2]}_{3} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1320.745	400	75 714.86	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1323.813	500p	75 539.38	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[5 / 2]}_{3}^{°}$
1327.822	150	75 311.32	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1332.063	300	75 071.55	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 d 1 / 2 {[1 / 2]}_{0}$
1337.338	300	747 75.39	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1340.423	30	746 03.29
1342.525	30	74 486.53
1352.053	50	73 961.57
1355.214	300	73 789.09	$5 p 1 / 2 {[1 / 2]}_{0} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1355.975	500	73 747.67	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
1360.104	70	73 523.80	$4 f 3 / 2 {[3 / 2]}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
1361.387	300	73 454.48	$5 p 3 / 2 {[1 / 2]}_{0} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
1370.986	2	72 940.18	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[7 / 2]}_{3}^{°}$
1373.344	90	72 814.96
1375.212	80	72 716.06	$4 f 3 / 2 {[3 / 2]}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1376.542	500	72 645.80	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1384.389	20	72 236.11
1387.286	30	72 083.21	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{0}^{°}$
1396.791	200	71 592.66
1400.335	50	71 411.50
1401.838	90	71 334.91
1408.844	90	70 980.18	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1409.836	80	70 930.23
1410.032	300	70 920.38	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1411.328	30	70 855.23
1413.400	200	70 751.37
1419.918	60	70 426.58
1430.156	30	69 922.42
1437.120	60	69 583.59
1447.487	60	69 087.26
1451.948	90	68 872.98
1460.046	300	68 491.00
1462.478	80	68 377.10	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1484.570	60	67 359.56	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
1486.903	300	67 253.87
1491.328	300	67 054.33	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1506.187	100	66 392.81
1509.420	60	66 250.62
1517.616	90	65 892.83
1520.471	200	65 769.07
1533.218	50	65 222.30	$4 f 1 / 2 {[7 / 2]}_{4} - 5 g 3 / 2 {[11 / 2]}_{5}^{°}$
1534.723	150	65 158.33
1537.219	30	65 052.55	$5 p 3 / 2 {[1 / 2]}_{0} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1547.389	70	64 624.99
1550.124	200	64 510.95
1551.994	40	64 433.26
1559.284	70	64 131.98
1575.631	40	63 466.65
1585.853	90	63 057.55	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
1591.801	100	62 821.93
1603.774	60	62 352.94
1633.026	500	61 236.03	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
1645.336	40	60 777.86
1654.458	500	60 442.76	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
1676.842	20	59 635.90	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1682.255	50	59 444.03
1725.015	700	57 970.52	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
1735.947	8	57 605.45	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1750.433	20	57 406.93
1765.578	5	56 638.68	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{0}^{°}$
1767.791	30	56 567.78
1772.084	40	56 430.73
1786.197	500	55 984.87	$5 s 1 / 2 {[1 / 2]}_{0}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
1790.812	200p	55 840.59	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
1806.091	500	55 368.19	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
1860.483	500	53 749.48	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1860.864	600	53 738.47	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
1874.386	50	53 350.79
1878.333	500	53 238.70	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
1926.236	400	51 914.72	$4 d {¹ P}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
1927.427	500	51 882.63	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
1934.876	400	51 682.90	$5 s 1 / 2 {[1 / 2]}_{0}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
2009.941	500	49 752.70	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
2029.193	600	49 280.67	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
2085.204	100	47 956.95	$4 d {¹ P}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
2133.094	600	46 880.25	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
2145.587	30	46 607.29	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
2150.860	200	46 493.02
2221.867	80	45 007.17
2234.739	20	44 747.95
2337.660	200	42 777.81
2420.689	80	41 310.55
2429.285	80	41 164.38
2451.216	35	40 796.09
2454.626	60	40 739.41	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
2473.925	30	40 421.60
2617.542	30	38 203.79
2646.243	30	37 789.43
2675.190	10	37 380.52

Energy levels of Zr v.

Configuration	Term	J	E(cm⁻¹)	Unc. (cm⁻¹)
4p⁶	¹S	0	0.0	1.9
4p⁵ 4d	³P°	0	241 381.3	0.6
	³P°	1	243 560.8	0.4
	³P°	2	247 962.3	0.3
	³F°	4	251 283.3	0.7
	³F°	3	253 753.4	0.4
	³F°	2	257 361.3	0.3
	³D°	3	265 845.5	0.4
	¹D°	2	270 560.8	0.2
	³D°	1	271 601.6	0.2
	³D°	2	274 654.6	0.2
	¹F°	3	277 145.5	0.3
	¹P°	1	328 940.75	0.09
4p⁵ 5s	3/2[3/2]°	2	325 014.87	0.10
	3/2[3/2]°	1	327 616.99	0.12
	1/2[1/2]°	0	340 315.49	0.13
	1/2[1/2]°	1	342 245.65	0.07
4p⁵ 5p	3/2[1/2]	1	371 895.16	0.12
	3/2[5/2]	2	376 897.68	0.09
	3/2[5/2]	3	378 753.36	0.12
	3/2[3/2]	1	380 855.53	0.11
	3/2[3/2]	2	382 985.08	0.08
	3/2[1/2]	0	388 852.95	0.10
	1/2[3/2]	1	391 998.41	0.10
	1/2[3/2]	2	395 994.98	0.13
	1/2[1/2]	1	396 300.35	0.11
	1/2[1/2]	0	402 688.40	0.14
4s4p⁶ 4d	³D	1	434 714.6	0.5
	³D	2	435 759.1	0.3
	³D	3	437 678.1	0.3
	¹D	2	450 133.7	0.3
4p⁵ 4f	3/2[9/2]	5	453 680.8	0.7
	3/2[9/2]	4	454 538.8	0.4
	3/2[7/2]	3	457 546.7	0.4
	3/2[7/2]	4	458 432.2	0.3
	3/2[3/2]	1	460 476.9	0.4
	3/2[5/2]	2	460 694.1	0.2
	3/2[5/2]	3	460 767.5	0.3
	3/2[3/2]	2	464 015.4	0.2
	1/2[7/2]	3	470 773.5	0.5
	1/2[7/2]	4	471 762.4	0.5
	1/2[5/2]	3	473 715.4	0.6
	1/2[5/2]	2	476 130.2	0.4
4p⁵ 5d	3/2[1/2]°	0	452 938.91	0.19
	3/2[1/2]°	1	453 905.60	0.16
	3/2[7/2]°	4	455 444.4	0.3
	3/2[3/2]°	2	455 630.8	0.14
	3/2[7/2]°	3	455 925.27	0.18
	3/2[5/2]°	2	457 613.1	0.3
	3/2[5/2]°	3	458 523.7	0.6
	3/2[3/2]°	1	462 307.4	0.3
	1/2[5/2]°	2	471 306.3	0.2
	1/2[3/2]°	2	472 015.28	0.19
	1/2[5/2]°	3	472 520.0	0.3
	1/2[3/2]°	1	476 477.4	0.3
4p⁵ 6s	3/2[3/2]°	2	472 338.0	0.2
	3/2[3/2]°	1	473 172.7	0.3
	1/2[1/2]°	0	487 746.6	0.3
	1/2[1/2]°	1	488 292.7	0.2
4p⁵ 6d	3/2[1/2]°	1	528 422.8	1.0
	3/2[7/2]°	4	529 161.6	1.1
	3/2[3/2]°	2	529 283.3	1.0
	3/2[7/2]°	3	529 299.6	1.1
	3/2[5/2]°	2	530 119.7	0.8
	3/2[5/2]°	3	530 465.5	0.8
	3/2[3/2]°	1	531 839.0	1.1
	1/2[3/2]°	1	546 323	15
4p⁵ 7s	3/2[3/2]°	2	536 763.9	0.7
	3/2[3/2]°	1	537 213.4	0.6
	1/2[1/2]°	0	552 258.2	1.2
	1/2[1/2]°	1	552 521.1	0.9
4p⁵ 5g	3/2[5/2]°	2	536 682.2	0.3
	3/2[5/2]°	3	536 731.5	0.2
	3/2[11/2]°	6	536 961.4	0.8
	3/2[11/2]°	5	536 983.9	0.8
	3/2[7/2]°	4	537 501.9	0.5
	3/2[7/2]°	3	537 539.2	0.2
	3/2[9/2]°	4	537 806.7	0.4
	3/2[9/2]°	5	537 816.5	0.4
	1/2[9/2]°	4	552 878.2	0.5
	1/2[7/2]°	4	552 894.5	0.5
	1/2[9/2]°	5	552 894.7	0.4
	1/2[7/2]°	3	552 933.5	0.5
4p⁵ 6g	3/2[5/2]°	2	570 779.3	1.0
	3/2[5/2]°	3	570 828.2	0.5
	3/2[11/2]°	6	570 946.5	1.0
	3/2[11/2]°	5	570 967.6	0.5
	3/2[7/2]°	4	571 271.7	0.4
	3/2[7/2]°	3	571 306.3	0.6
	3/2[9/2]°	4	571 443.6	0.6
	3/2[9/2]°	5	571 452.2	0.7
	1/2[9/2]°	4	586 704.9	0.8
	1/2[7/2]°	4	586 718.2	0.8
	1/2[9/2]°	5	586 734.5	0.8
4p⁵ 7d	3/2[3/2]°	1	568 040	16
	1/2[3/2]°	1	583 420	17
4p⁵ 8s	3/2[3/2]°	1	571 376	16
	1/2[1/2]°	1	586 882	17
4s4p⁶ 5p	¹P°	1	573 776	17
4p⁵ 9s	3/2[3/2]°	1	591 916	18
4p⁵ 10s	3/2[3/2]°	1	605 118	18

Calculated energy level values in cm⁻¹ and percentage compositions for the 4p⁵(4d + 5s) configurations of Zr v. States of 4p⁵ 5s are denoted by an asterisk. Negative eigenvector components are preceded by a minus sign.

J	E(obs.)	E(calc.)	obs.-calc.	% J₁l	Percentage composition—LS
0	241 381	241 499	−118	100% 3/2[1/2]	−100% ³P
	340 315	340 315	0	100% 1/2[1/2]*	100% ³P*
1	243 561	243 637	−76	67% 3/2 [1/2]	−98% ³P − 2% ³D
	271 602	271 353	249	49% 1/2[3/2]	97% ³D − 2% ³P − 1% ¹P
	327 617	327 616	1	84% 3/2[3/2]*	−45% ¹P* + 41% ³P* + 14% ¹P
	328 941	328 944	−3	37% 1/2[3/2]	85% ¹P − 8% ³P* + 6% ¹P* + 1% ³D
	342 246	342 247	−1	97% 1/2[1/2]*	−51% ³P* − 49% ¹P*
2	247 962	247 983	−21	78% 3/2[3/2]	92% ³P + 6% ³D + 2% ¹D
	257 361	257 315	46	73% 3/2[5/2]	−74% ³P + 15% ¹D − 11% ³D
	270 561	270 805	−244	73% 1/2[5/2]	47% ¹D − 27% ³D + 26% ³F
	274 655	274 738	−83	78% 1/2[3/2]	−56% ³D − 36% ¹D + 8% ³P
	325 015	325 016	−1	100% 3/2[3/2]*	−100% ³P*
3	253 753	253 551	202	68% 3/2[7/2]	87% ³F − 8% ¹F + 5% ³D
	265 846	266 079	−233	79% 3/2[5/2]	66% ³D + 34% ¹F
	277 146	277 036	110	87% 1/2[5/2]	−58% ¹F + 29% ³D − 13% ³F
4	251 283	251 114	169	100% 3/2[7/2]	100% ³F

Energy parameters in cm⁻¹ and mean errors Δ of least-squares fits for Zr v.

Configuration	Parameter	HF	Fitted	Fitted/HF
4p⁵ 4d	E_av	258 435	264 395 ± 69
	F²(4p4d)	65 714	55 869 ± 615	0.850
	G¹(4p4d)	81 768	60 622 ± 363	0.741
	G³(4p4d)	50 422	43 933 ± 1144	0.87
	ζ₄_p	9 007	9 633 ± 179	1.07
	ζ₄_d	620	652 ± 75	1.05
4p⁵ 5s	E_av	330 839	331 289 ± 171
	G¹(4p5s)	7 500(0.40) ^a	7 066 ± 895	0.94
	ζ₄_p	9 302	10 200 ± 205	1.10
Configuration	R²(4p4d,4p5s)	−7 023 (−0.22)	−2 039 ± 2001	0.29
Interaction	R¹(4p4d,5s4p)	190 (0.005)	55^b
	Δ		218
4p⁵ 5p	E_av	380 074	384 586 ± 24
	F²(4p5p)	22 151	21 060 ± 198	0.951
	G⁰(4p5p)	4 481 (0.20)	4 121 ± 20	0.920
	G²(4p5p)	6 098 (0.60)	5 910 ± 326	0.97
	ζ₄_p	9 363	10 219 ± 38	1.091
	ζ₅_p	1 674	2 242 ± 45	1.34
	Δ		72
4p⁵ 5d	E_av	453 723	462 027 ± 12
	F²(4p5p)	15 901	13 835 ± 146	0.870
	G¹(4p5d)	9 462 (0.75)	9 293 ± 58	0.982
	G³(4p5d)	6 790 (0.90)	6 110 ± 241	0.90
	ζ₄_p	9 356	10 256 ± 19	1.096
	ζ₅_d	154	207 ± 13	1.34
4p⁵ 6s	E_av	470 595	477 815 ± 23
	G¹(4p6s)	2 357 (0.36)	2 103 ± 142	0.89
	ζ₄_p	9 380	10 301 ± 30	1.098
Configuration	R²(4p5d,4p6s)	518 (0.06)	295^c
Interaction	R¹(4p5d,6s4p)	1 373 (0.16)	782 ± 447	0.57
	Δ		41
4p⁵ 4f	E_av	458 854	461 077 ± 63
	F²(4p4f)	25 338	24 265 ± 840	0.96
	G²(4p4f)	15 451	14 266 ± 808	0.92
	G⁴(4p4f)	10 215	8 315 ± 1112	0.81
	ζ₄_p	9 345	10 143 ± 75	1.085
	ζ₄_f	4	36^d
4s4p⁶ 4d	E_av	463 830	447 232 ± 190
	G²(4s4d)	60 448	23 028 ± 1432	0.38
	ζ₄_p	636	566 ± 111	0.89
Configuration	R²(4p4d,4f4s)	29 125	9 446 ± 710	0.32
Interaction	R¹(4p4d,4s4f)	47 899	27 962 ± 199	0.584
	Δ		139
4p⁵ 5g	E_av	531 679	542 489 ± 2
	F²(4p5g)	4 758	4 277 ± 28	0.899
	G³(4p5g)	392	286 ± 33	.73
	G⁵(4p5g)	276	108 ± 56	.39
	ζ₄_p	9 421	10 385 ± 3	1.1023
	ζ₅_g	0.3	0^e
	Δ		8
4p⁵ 6d	E_av	542 640	534 855 ± 15
	F²(4p6d)	6 941	6 195 ± 142	0.89
	G¹(4p6d)	3 679	3 402 ± 45	0.925
	G³(4p6d)	2 769	2 476 ± 241	0.89
	ζ₄_p	9 393	10 325^f
	ζ₆_d	74	115 ± 13	1.55
4p⁵ 7s	E_av	532 684	542 098 ± 17
	G¹(4p7s)	1 095 (0.34)	1 014 ± 94	0.93
	ζ₄_p	9 402	10 335 ± 19	1.098
Configuration	R²(4p6d,4p7s)	768	768^g
Interaction	R¹(4p6d,7s4p)	715	715^g
	Δ		33
4p⁵ 6g	E_av	564 519	576 338 ± 2
	F²(4p6g)	2 786	2 513 ± 23	0.902
	G³(4p6g)	372	286 ± 34	0.77
	G⁵(4p6g)	263	167 ± 49	0.63
	ζ₄_p	9 421	103 83 ± 3	1.1021
	ζ₆_g	0.2	0^e
	Δ		7

a Values in parentheses are the ratio of the calculated parameter to a value calculated by using the absolute value of each wave function.
b Fixed at HF ratio to R²(4p4d,4p5s).
c Fixed at HF ratio to R¹(4p5d,6s4p).
d Fixed at value of ζ₄_f in Nb v.
e Fixed at zero.
f Fixed at HF ratio to ζ₄_p(4p⁵7s).
g Fixed at HF value.

Calculated energy level values and percentage compositions for the 4p⁵ 5p configuration of Zr v. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
0	388 853	388 812	41	78% 3/2[1/2]	79% ³P − 21% ¹S
	402 688	402 699	−11	78% 1/2[1/2]	79% ¹S + 21% ³P
1	371 895	371 929	−34	91% 3/2[1/2]	85% ³S + 14% ³P
	380 856	380 949	−93	94% 3/2[3/2]	46% ¹P − 31% ³D − 20% ³P + 3% ³S
	391 998	391 978	20	92% 1/2[3/2]	64% ³D + 33% ¹P − 2% ³P
	396 300	396 300	0	89% 1/2[1/2]	−64% ³P − 20% ¹P + 12% ³S + 4% ³D
2	376 898	376 857	41	87% 3/2[5/2]	58% ³D − 34% ¹D + 8% ³P
	382 985	383 012	−27	87% 3/2[3/2]	68% ³P + 31% ¹D + 1% ³D
	395 995	396 010	−15	99% 1/2[3/2]	−40% ³D − 35% ¹D + 25% ³P
3	378 753	378 674	79	100% 3/2[5/2]	100% ³D

Calculated energy level values in cm⁻¹ and percentage compositions for the 4p⁵(5d + 6s) configurations of Zr v. States of 4p⁵ 6s are denoted by an asterisk. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
0	452 939	452 940	−1	100% 3/2[1/2]	100% ³P
	487 747	487 766	−19	100% 1/2[1/2]*	100% ³P*
1	453 906	453 898	8	67% 3/2[1/2]	−90% ³P − 10% ³D
	462 307	462 273	34	66% 3/2[3/2]	57% ³D − 39% ¹P − 4% ³P
	473 173	473 184	−11	98% 3/2[3/2]*	−62% ¹P* + 37% ³P* + 1% ³D
	476 477	476 500	−23	91% 1/2[3/2]	60% ¹P + 33% ³D − 6% ³P − 1% ³P*
	488 293	488 273	20	100% 1/2[1/2]*	−62% ³P* − 38% ¹P*
2	455 631	455 643	−12	96% 3/2[3/2]	66% ³P + 24% ³D + 9% ¹D
	457 613	457 621	−8	98% 3/2[5/2]	45% ¹D − 31% ³F − 23% ³D
	471 306	471 262	44	97% 1/2[5/2]	−67% ³F − 25% ¹D + 8% ³D
	472 015	472 071	−56	92% 1/2[3/2]	−43% ³D + 31% ³P − 21% ¹D + 4% ³P*
	472 338	472 324	14	96% 3/2[3/2]*	96% ³P* + 2% ³D − 1% ³P + 1% ¹D
3	455 925	455 956	−31	91% 3/2[7/2]	61% ³F − 34% ¹F + 5% ³D
	458 524	458 523	1	91% 3/2[5/2]	66% ³D + 31% ¹F + 3% ³F
	472 520	472 492	28	99% 1/2[5/2]	−35% ¹F − 36% ³F + 29% ³D
4	455 444	455 434	10	100% 3/2[7/2]	100% ³F

Calculated energy level values in cm⁻¹ and percentage compositions for the 4s4p⁶ 4d + 4p⁵ 4f configurations of Zr v. States of 4s4p⁶ 4d are denoted by an asterisk. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
1	434 715	434 629	86		64% ³D* + 36% ³D
	460 477	460 626	−149	64% 3/2[3/2]	64% ³D − 36% ³D*
2	435 759	435 813	−54		66% ³D* + 33% ³D + 1% ³F
	450 134	450 134	0		−76% ¹D* − 21% ¹D + 2% ³F − 1% ³D
	460 694	460 566	128	55% 3/2[5/2]	−41% ³D − 33% ³F + 25% ³D* + 1% ¹D
	464 015	464 016	−1	42% 3/2[3/2]	31% ¹D − 29% ³F − 19% ¹D* + 14% ³D − 7% ³D*
	476 130	476 131	−1	90% 1/2[5/2]	47% ¹D + 35% ³F − 11% ³D − 5% ¹D* + 2% ³D*
3	437 678	437 706	−28		−71% ³D* − 27% ³D − 1% ³F − 1% ¹F
	457 547	457 680	−133	95% 3/2[7/2]	−46% ³G + 30% ¹F − 24% ³F
	460 768	460 682	86	79% 3/2[5/2]	−31% ³D − 27% ³F + 21% ³D* − 21% ¹F
	470 774	470 898	−124	95% 1/2[7/2]	−54% ³G − 26% ¹F + 19% ³F
	473 715	473 648	67	91% 1/2[5/2]	41% ³D − 29% ³F − 21% ¹F − 8% ³D*
4	454 539	454 584	−45	95% 3/2[9/2]	61% ³G − 37% ¹G + 2% ³F
	458 432	458 449	−17	93% 3/2[7/2]	57% ³F + 33% ¹G + 10% ³G
	471 762	471 690	72	97% 1/2[7/2]	41% ³F − 30% ¹G − 28% ³G
5	453 681	453 566	115	100% 3/2[9/2]	100% ³G

Calculated energy level values in cm⁻¹ and percentage compositions for the 4p⁵ 5g configuration of Zr v. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
2	536 682	536 674	8	100% 3/2[5/2]	100% ³F
3	536 732	536 731	1	100% 3/2[5/2]	61% ³F + 39% ¹F
	537 539	537 535	4	99% 3/2[7/2]	54% ³G − 30% ¹F + 16% ³F
	552 934	552 939	−5	100% 1/2[7/2]	46% ³G + 31% ¹F − 22% ³F
4	537 502	537 495	7	100% 3/2[7/2]	−46% ³F − 30% ³G − 24% ¹G
	537 807	537 811	−4	100% 3/2[9/2]	39% ¹G − 31% ³G − 30% ³H
	552 878	552 880	−2	100% 1/2[9/2]	70% ³H + 17% ¹G − 13% ³G
	552 894	552 896	−2	100% 1/2[7/2]	54% ³F − 26% ³G − 20% ¹G
5	536 984	536 988	−4	100% 3/2[11/2]	−54% ¹H + 46% ³H
	537 816	537 815	1	100% 3/2[9/2]	70% ³G + 16% ³H + 14% ¹H
	552 895	552 888	7	100% 1/2[9/2]	−38% ³H − 32% ¹H + 30% ³G
6	536 961	536 973	−12	100%3/2[11/2]	100% ³H

TABLE I

Observed spectral lines of Zr v. All wavelengths are in vacuum. Except for the 4p⁶, 4s4p⁶ 4d, and 4s4p⁶ 5p configurations, the levels given for the line classifications are all based on the 4p^{5 2}P core. The 4p⁶, 4p⁵ 4d, 4s4p⁶ 4d, and 4s4p⁶ 5p configurations are designated in LS coupling, all others in J₁l. Symbols: p, perturbed by close line; u, unresolved from close line.

Wavelength (Å)	Intensity	Wave number (cm⁻¹)	Classification
165.257	1	605 118	$4 p^{6} {¹ S}_{0} - 10 s 3 / 2 {[3 / 2]}_{1}^{°}$
168.943	1	591 916	$4 p^{6} {¹ S}_{0} - 9 s 3 / 2 {[3 / 2]}_{1}^{°}$
170.392	2	586 882	$4 p^{6} {¹ S}_{0} - 8 s 1 / 2 {[1 / 2]}_{1}^{°}$
171.403	1	583 420	$4 p^{6} {¹ S}_{0} - 7 d 1 / 2 {[3 / 2]}_{1}^{°}$
174.286	3	573 770	$4 p^{6} {¹ S}_{0} - 4 s 4 p^{6} 5 p {¹ P}_{1}^{°}$
175.016	2	571 377	$4 p^{6} {¹ S}_{0} - 8 s 3 / 2 {[3 / 2]}_{1}^{°}$
176.043	2	568 042	$4 p^{6} {¹ S}_{0} - 7 d 3 / 2 {[3 / 2]}_{1}^{°}$
180.988	7	552 522	$4 p^{6} {¹ S}_{0} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
183.042	20	546 323	$4 p^{6} {¹ S}_{0} - 6 d 1 / 2 {[3 / 2]}_{1}^{°}$
186.146	30	537 213	$4 p^{6} {¹ S}_{0} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
188.027	50	531 839	$4 p^{6} {¹ S}_{0} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
189.248	25p	528 406	$4 p^{6} {¹ S}_{0} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
204.798	80	488 286	$4 p^{6} {¹ S}_{0} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
209.872	100	476 480	$4 p^{6} {¹ S}_{0} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
211.339	100	473 173	$4 p^{6} {¹ S}_{0} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
216.307	125	462 306	$4 p^{6} {¹ S}_{0} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
220.310	30	453 906	$4 p^{6} {¹ S}_{0} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
280.779	40	356 152
284.333	20p	351 700
292.187	300	342 246	$4 p^{6} {¹ S}_{0} - 5 s 1 / 2 {[1 / 2]}_{1}^{°}$
294.570	30	339 478
294.938	40	339 054
295.159	70	338 800
297.480	60p	336 158
297.779	30p	335 797
298.190	70	335 357
298.316	50	335 215
298.427	70	335 090
298.533	80	334 971
298.813	70p	334 658
298.946	30	334 509
298.979	30	334 472
299.399	30	334 002
299.663	30	333 708
299.890	50	333 456
300.391	60p	332 884.5
300.673	30p	332 587.5
300.748	40p	332 504.5
301.587	20p	331 579.7
301.634	50p	331 527.5
301.958	80p	331 171.8
302.150	20	330 961.0
302.505	50	330 572.8
303.380	20p	329 619.9
303.752	20	329 215.5
303.831	30p	329 130.1
304.008	500	328 938.7	$4 p^{6} {¹ S}_{0} - 4 d {¹ P}_{1}^{°}$
304.076	60	328 864.6
304.142	80p	328 794.2
304.380	30	328 536.6
304.414	20	328 499.7
304.527	80p	328 377.8
305.236	300	327 615.4	$4 p^{6} {¹ S}_{0} - 5 s 3 / 2 {[3 / 2]}_{1}^{°}$
305.425	30	327 412.8
305.459	70	327 676.1
306.698	30	326 028.5
306.904	60p	325 834.4
307.236	30	325 482.8
307.753	60p	524 936.2
308.321	50p	324 337.1
308.489	80	324 161.1
308.621	60	324 021.9
308.857	20	323 744.8
309.421	30	323 184.7
309.728	15p	322 863.7
310.326	30	322 242.0
310.508	10	322 053.3
310.928	90	321 618.3
311.252	60	321 283.4
312.100	20	320 409.7
313.050	30	319 437.3
313.954	80	318 518.3
314.488	90	317 976.7
314.628	50	317 835.7
315.308	70	317 149.9
315.440	20p	317 017.5
317.280	40	315 179.0
317.298	40	315 161.1
319.842	60	312 654.4
321.845.	10	310 708.7
322.954	10	309 670.4
322.999	30	309 598.9
324.785	70p	307 896.4
325.030	70	307 663.9
325.213	50	307 490.7
325.410	30p	307 304.8
326.087	80	306 666.3
327.536	30p	305 309.7
329.271	30p	303 701.3
329.752	20	303 258.6
330.217	20	302 831.2
330.528	30	302 546.3
330.851	60	302 256.6
331.789	10	301 396.5
332.316	30p	300 918.1
333.007	30	300 294.1
333.232	60	300 091.0
333.945	60p	299 450.2
334.863	3	298 629.4
335.233	10	298 299.5
337.670	40	296 147.2
337.932	20	295 917.6
341.002	30	293 253.5
346.419	20	288 668.2
356.429	40	280 560.7
356.528	20	280 483.0
362.226	30	276 070.4
368.184	400p	271 603.3	$4 p^{6} {¹ S}_{0} - 4 d {³ D}_{1}^{°}$
368.441	30p	271 413.9
372.724	10p	268 295.0
373.218	20	267 939.6
376.582	10	265 546.4
377.293	10	265 046.6
378.680	10p	264 075.2
378.935	30	263 897.4
383.917	40	260 473.0
386.214	30	258 924.0
386.866	15	258 487.7
388.330	80	257 512.9
389.971	20	256 429.3
390.740	40	255 924.7
391.804	15	255 299.7
392.248	20	254 940.5
392.926	30	254 500.8
394.546	40	253 455.9
397.024	10	251 873.9
399.107	10	250 559.4
410.425	25	243 471.6
410.572	100p	243 562.6	$4 p^{6} {¹ S}_{0} - 4 d {³ P}_{1}^{°}$
411.291	40	243 136.9
429.983	7	232 567.3	$4 d {³ P}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
442.963	80	225 752.3	$4 d {³ P}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{3}$
453.610	30	220 453.9	$4 d {³ P}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
456.425	80	219 094.1	$4 d {³ P}_{0}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
458.698	40	218 008.6	$4 d {³ F}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{4}$
460.549	90	217 132.0	$4 d {³ P}_{1}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
461.009	80	216 915.5	$4 d {³ P}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
462.852	15	216 052.0	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
468.577	50	213 412.2	$4 d {³ F}_{2}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
469.917	90	212 803.6	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
470.078	70	212 730.8	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
470.558	6	212 513.7	$4 d {³ P}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
477.364	50	209 483.7	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
482.745	70	207 148.6	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
483.060	50	207 013.7	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
483.231	60	206 940.5	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
483.902	60	206 653.4	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
485.632	50p	205 917.2	$4 d {³ D}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{4}$
486.454	40	205 569.3	$4 d {¹ D}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
488.571	70	204 678.5	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
488.929	90	204 528.5	$4 d {³ D}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
490.694	90	203 793.0	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{3}$
491.628	3	203 405.7	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
491.804	60	203 333.0	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
491.993	70	203 255.0	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
492.331	20	203 115.4	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
494.077	150	202 397.4	$4 d {³ F}_{4}^{°} - 4 f 3 / 2 {[9 / 2]}_{5}$
494.629	15	202 171.7	$4 d {³ P}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
496.338	20	201 475.7	$4 d {³ D}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
498.046	150	200 784.7	$4 d {³ F}_{3}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
499.471	125	200 211.8	$4 d {¹ D}_{2}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
499.535	125	200 186.1	$4 d {³ F}_{2}^{°} - 4 f 3 / 2 {[7 / 2]}_{3}$
502.361	125	199 060.0	$4 d {³ D}_{2}^{°} - 4 f 1 / 2 {[5 / 2]}_{3}$
508.727	70	196 569.2	$4 d {¹ F}_{3}^{°} - 4 f 1 / 2 {[5 / 2]}_{3}$
509.218	6	196 379.6	$4 d {³ F}_{3}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
509.896	8	196 118.6	$4 d {³ D}_{2}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
513.027	125	194 921.5	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
513.220	30	194 848.2	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
513.830	150	194 617.0	$4 d {¹ F}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{4}$
516.455	60	193 627.6	$4 d {¹ F}_{3}^{°} - 4 f 1 / 2 {[7 / 2]}_{3}$
517.244	90	193 332.4	$4 d {³ P}_{0}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
518.746	150	192 772.6	$4 d {³ F}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
519.248	200	192 586.3	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
519.715	150	192 413.1	$4 d {³ D}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
520.170	60	192 244.9
520.296	125	192 198.1	$4 d {³ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
523.141	90	191 153.0	$4 d {³ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
525.943	50	190 134.8	$4 d {¹ D}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
527.106	125	189 715.1	$4 d {³ P}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
528.843	40	189 092.2	$4 d {³ D}_{1}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
529.452	70	188 874.4	$4 d {³ D}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
529.963	90	188 692.4	$4 d {³ D}_{3}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
532.495	80	187 795.3	$4 d {³ P}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
534.802	90	186 985.2	$4 d {¹ D}_{2}^{°} - 4 f 3 / 2 {[7 / 2]}_{3}$
535.133	40	186 869.3	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
536.498	200	186 394.0	$4 d {³ F}_{4}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
537.310	100	186 112.4	$4 d {³ D}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
537.521	100	186 039.4	$4 d {³ D}_{2}^{°} - 4 f 3 / 2 {[5 / 2]}_{2}$
538.087	30	185 843.4
538.153	80	185 820.8	$4 d {³ D}_{2}^{°} - 4 f 3 / 2 {[3 / 2]}_{1}$
542.629	70	184 288.1	$4 d {³ D}_{3}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
543.704	90	183 923.5	$4 d {³ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
544.598	20	183 621.7	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[5 / 2]}_{3}$
549.432	150	182 006.3	$4 d {³ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
551.609	60	181 287.8	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[7 / 2]}_{4}$
556.873	100	179 574.3	$4 d {¹ D}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
560.121	100	178 533.0	$4 d {³ D}_{1}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
560.543	60	178 398.5	$4 d {³ F}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
563.717	100	177 394.0	$4 d {¹ F}_{3}^{°} - 4 f 3 / 2 {[9 / 2]}_{4}$
563.844	100	177 354.0	$4 d {³ F}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
569.864	90	175 4 80.5	$4 d {³ D}_{2}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
574.280	150	174 131.1
578.069	100	172 989.8	$4 d {¹ F}_{3}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
581.952	2p	171 835.5	$4 d {³ D}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
583.380	50	171 414.9
589.559	50	169 618.2
591.914	40	168 929.3
592.379	30	168 810.9
592.946	60	168 649.4
595.426	60	167 949.0
599.343	60	166 849.3
601.229	80	166 325.9
604.893	1	165 318.5	$5 p 3 / 2 {[1 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
605.336	100	165 197.4	$4 d {¹ D}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
606.536	20p	164 870.8	$5 p 3 / 2 {[1 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
609.187	100	164 153.2	$4 d {¹ D}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
613.074	40	163 112.5	$4 d {³ D}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
613.411	100	163 022.9	$4 d {³ D}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
621.862	40	160 807.4
622.929	90	160 531.9	$4 d {¹ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
623.769	30	160 315.8	$5 p 3 / 2 {[5 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
623.988	5	1602 59.6	$5 p 1 / 2 {[3 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{0}^{°}$
625.525	20	159 865.8	$5 p 3 / 2 {[5 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
628.428	90	159 127.2	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
630.463	80	158 613.6	$4 d {¹ F}_{3}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
632.869	80	158 010.5	$5 p 3 / 2 {[5 / 2]}_{3} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
635.368	15	157 389.1	$5 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
638.867	50	156 527.1	$5 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
638.867	50	156 527.1	$5 p 1 / 2 {[3 / 2]}_{2} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
639.560	30	156 357.6	$5 p 3 / 2 {[3 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
639.606	10p	156 346.1
639.688	15	156 326.3
640.122	4	156 220.3	$5 p 1 / 2 {[1 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
641.196	9	155 958.6	$5 p 1 / 2 {[1 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{0}^{°}$
645.500	90	154 918.7	$4 d {³ P}_{0}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
648.389	15	154 228.5	$5 p 3 / 2 {[3 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
649.574	50	153 946.9
650.066	30	153 830.5
650.283	40	153 779.1	$5 p 3 / 2 {[3 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
650.427	15	153 745.2
650.821	10	153 652.1
652.177	60	153 332.7
652.647	15	153 222.3	$5 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
654.513	15	152 785.5
654.710	90	152 739.4	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
656.020	15	152 434.4	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
656.159	60	152 402.0	$5 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
657.387	60	152 117.4
659.143	20	151 712.1	$5 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
661.055	10	151 273.4
661.702	40	151 125.4
662.324	10	150 983.5	$5 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
664.250	3	150 545.7	$5 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
664.635	10	150 458.6
664.857	60	150 408.2	$5 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[7 / 2]}_{4}^{°}$
666.467	30	150 044.9
667.409	2	149 833.1	$5 p 1 / 2 {[1 / 2]}_{0} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
669.703	30	149 319.9
669.954	25	149 264.0	$5 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
673.340	60	148 513.4	$5 p 3 / 2 {[3 / 2]}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
673.686	100	148 437.1	$4 d {³ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
674.034	5	148 360.5	$5 p 3 / 2 {[1 / 2]}_{0} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
674.134	200p	148 338.5	$4 d {³ P}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
675.342	30	148 073.0
675.526	200	148 032.8	$4 d {³ P}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
675.865	15	147 958.6
677.663	15	147 566.0	$5 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
678.056	50	147 480.4	$5 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
679.394	300	147 190.0	$4 d {¹ P}_{1}^{°} - 6 f 1 / 2 {[5 / 2]}_{2}$
683.536	5	146 298.0	$5 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
687.576	40	145 438.4	$5 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
688.268	200	145 292.2	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
690.520	100	144 818.4
703.026	200p	142 242.3	$4 d {³ F}_{3}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
712.488	40	140 353.2
712.855	50	140 281.1
713.053	40	140 242.1
716.978	150	139 474.3	$4 d {³ P}_{0}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
717.236	300	139 424.2	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
719.739	100	138 939.2	$4 d {³ F}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
721.323	150	138 634.1	$4 d {³ F}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
724.454	60	137 792.2
728.741	40	137 222.9
730.188	40	136 951.0
730.430	10	136 905.7
733.148	60	136 398.1	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
733.413	30	136 348.9
734.941	60	136 065.3	$4 s 4 p^{6} 4 d {³ D}_{1} - 6 g 3 / 2 {[5 / 2]}_{2}^{°}$
740.331	200	135 074.7	$4 d {¹ P}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
740.613	2000	135 023.3	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
742.181	25	134 738.0
742.736	500	134 637.3	$4 d {³ F}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
744.018	50	134 437.4
744.753	60	134 272.8
746.913	30	133 884.4	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 4 f 1 / 2 {[5 / 2]}_{2}$
748.538	40	133 593.8	$4 s 4 p^{6} 4 d {³ D}_{3} - 6 g 3 / 2 {[7 / 2]}_{4}^{°}$
749.810	30	133 367.1
749.977	90	133337.4	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
752.020	40	132 975.2
752.484	300	132 893.1	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
753.160	30	132 773.9
754.582	20	132 523.8
756.107	70	132 256.4
762.852	70	131 087.1	$4 d {³ D}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
764.578	300	130 791.2	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
766.200	500	130 514.3	$4 d {³ P}_{0}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
766.388	20	130 482.1
769.567	15	129 943.2
771.180	20	129 671.4
773.804	200	129 231.6	$4 d {³ F}_{3}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
775.582	200	128 935.4	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
779.210	200	128 335.1	$4 d {³ P}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
783.520	30	127 629.1
784.496	400	127 470.4	$4 d {³ F}_{4}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
785.350	80	127 331.8
785.481	40	137 310.5
795.295	100	125 739.5	$4 d {¹ D}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
796.029	100	125 623.6	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
797.227	400	125 434.7	$4 d {¹ D}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
797.780	50	125 347.8
800.001	10 000	124 999.8	$4 d {³ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
800.301	50	124 953.0
801.929	70	124 699.3	$4 d {³ D}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
803.902	60	124 393.2
806.887	10 000	123 933.2	$4 d {³ P}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
808.810	80	123 638.5
809.419	20	123 545.4
809.754	200	123 494.3	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
812.052	10 000	123 144.8	$4 d {³ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
812.398	40	123 092.3
812.577	30	123 064.3
813.074	20	122 990.0
816.209	100	122 517.6	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
821.221	60	121 769.9	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 4 f 3 / 2 {[3 / 2]}_{2}$
822.055	500	121 646.4	$4 d {³ D}_{2}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
822.415	60	121 593.1
823.461	300p	121 438.7	$4 d {¹ D}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
823.779	200	121 391.8	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
825.129	200	121 193.2	$4 d {¹ P}_{1}^{°} - 4 s 4 p^{6} 4 d {¹ D}_{2}$
825.263	40p	121 173.5	$4 s 4 p^{6} 4 d {¹ D}_{2} - 6 g 3 / 2 {[7 / 2]}_{3}^{°}$
828.531	10u	120 695.5	$4 s 4 p^{6} 4 d {¹ D}_{2} - 6 g 3 / 2 {[5 / 2]}_{3}^{°}$
830.586	200	120 396.9	$4 d {³ D}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
836.566	400	119 536.3	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
841.399	3 000	118 849.7	$4 d {¹ F}_{3}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
849.110	30u	117 770.3	$4 f 3 / 2 {[9 / 2]}_{5} - 6 g 3 / 2 {[9 / 2]}_{5}^{°}$
851.390	70	117 455.0
852.764	90	117 265.7	$4 f 3 / 2 {[9 / 2]}_{5} - 6 g 3 / 2 {[11 / 2]}_{6}^{0}$
852.868	300p	117 251.4	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
853.429	60	117 174.3	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 1 / 2 {[7 / 2]}_{3}^{°}$
853.684	700	117 139.4	$4 d {³ D}_{3}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
855.399	20	116 904.5	$4 f 3 / 2 {[9 / 2]}_{4} - 6 g 3 / 2 {[9 / 2]}_{4}^{°}$
858.892	100	116 429.0	$4 f 3 / 2 {[9 / 2]}_{4} - 6 g 3 / 2 {[11 / 2]}_{5}^{°}$
859.126	15	116 397.3	$5 p 3 / 2 {[1 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
862.480	90	115 944.7	$4 f 1 / 2 {[7 / 2]}_{3} - 6 g 1 / 2 {[9 / 2]}_{4}^{°}$
862.674	20	115 918.6
863.561	60	115 799.6
867.930	40	115 216.6	$4 s 4 p^{6} 4 d {³ D}_{3} - 5 g 1 / 2 {[7 / 2]}_{4}^{°}$
869.776	100	114 972.1	$4 f 1 / 2 {[7 / 2]}_{4} - 6 g 1 / 2 {[9 / 2]}_{5}^{°}$
873.106	200	114 533.6	$4 d {³ F}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
873.400	30	114 495.1
877.985	100	113 897.2	$4 f 3 / 2 {[7 / 2]}_{3} - 6 g 3 / 2 {[9 / 2]}_{4}^{°}$
884.799	100	113 020.1	$4 f 3 / 2 {[7 / 2]}_{4} - 6 g 3 / 2 {[9 / 2]}_{5}^{°}$
885.038	80	112 989.5	$4 f 1 / 2 {[5 / 2]}_{3} - 6 g 1 / 2 {[7 / 2]}_{4}^{°}$
885.481	30	112 933.0
885.679	300	112 907.7	$4 d {³ D}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
886.216	30	112 839.3	$4 f 3 / 2 {[7 / 2]}_{4} - 6 g 3 / 2 {[7 / 2]}_{4}^{°}$
887.596	10	112 663.9	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 4 s 4 p^{6} 4 d {³ D}_{3}$
888.610	3	112 535.3	$4 f 3 / 2 {[7 / 2]}_{4} - 6 g 3 / 2 {[11 / 2]}_{5}^{°}$
889.492	80	112 423.7	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
890.414	30	112 307.3
895.605	60	111 656.4
897.801	80	111 383.3	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
900.476	300	111 052.4	$4 d {³ D}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
904.941	100	110 504.4	$4 f 3 / 2 {[5 / 2]}_{3} - 6 g 3 / 2 {[7 / 2]}_{4}^{°}$
905.989	50	110 388.8
906.606	90p	110 301.4	$4 f 3 / 2 {[3 / 2]}_{1} - 6 g 3 / 2 {[5 / 2]}_{2}^{°}$
906.663	500	110 294.6	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
907.984	60	110 134.1	$4 f 3 / 2 {[5 / 2]}_{2} - 6 g 3 / 2 {[5 / 2]}_{3}^{°}$
908.590	15	110 060.6	$4 f 3 / 2 {[5 / 2]}_{3} - 6 g 3 / 2 {[5 / 2]}_{3}^{°}$
915.123	60	109 274.9
915.300	500	109 253.8	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
915.829	60	109 190.7
923.100	400	108 330.6	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
924.276	100	108 192.8	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
924.710	10	108 142.0	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
932.046	80	107 290.8	$4 f 3 / 2 {[3 / 2]}_{2} - 6 g 3 / 2 {[7 / 2]}_{3}^{°}$
932.793	80	107 204.9
933.763	30	107 093.5
936.170	100	106 818.2	$4 d {¹ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{2}$
936.201	70	106 814.6
940.408	400	106 336.8	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
941.612	150	106 200.9	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
943.480	80	105 990.5
944.187	70	105 911.3
944.828	150	105 839.4	$4 d {¹ F}_{3}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
945.396	50p	105 775.8	$4 d {¹ P}_{1}^{°} - 4 s 4 p^{6} 4 d {³ D}_{1}$
949.705	200	105 295.8	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
960.626	150	104 098.8	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
974.361	30	102 631.4
978.062	200	102 243.0	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
978.257	70	102 222.6
980.704	200	101 967.6	$4 s 4 p^{6} 4 d {³ D}_{1} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
982.518	40	101 779.3	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
984.176	200	101 607.8	$4 d {¹ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
986.080	40	101 411.6
986.832	80	101 334.3	$4 d {¹ D}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
990.369	150	100 972.5	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
990.842	40	100 924.3	$4 s 4 p^{6} 4 d {³ D}_{2} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
995.590	300	100 443.0	$5 p 3 / 2 {[1 / 2]}_{1} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
997.073	150	100 293.6	$4 d {³ D}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
998.801	30	100 120.0	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1001.765	150	99 823.77	$4 s 4 p^{6} 4 d {³ D}_{3} - 5 g 3 / 2 {[7 / 2]}_{4}^{°}$
1002.484	400	99 752.22	$4 d {¹ F}_{3}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
1005.633	30	99 439.86	$5 p 3 / 2 {[1 / 2]}_{0} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1009.560	15	99 053.11	$4 s 4 p^{6} 4 d {³ D}_{3} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1028.380	100	97 240.30	$4 d {³ D}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
1038.690	400	96 275.08	$5 p 3 / 2 {[5 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1044.407	200	95 748.10	$5 p 1 / 2 {[3 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{0}^{°}$
1045.779	30	95 622.50	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1045.779	30	95 622.50	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1047.774	300	95 440.41	$5 p 3 / 2 {[5 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1048.970	20	95 331.57	$4 f 3 / 2 {[7 / 2]}_{3} - 5 g 1 / 2 {[9 / 2]}_{4}^{°}$
1051.329	60	95 117.74	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1058.619	5	94 462.71	$4 f 3 / 2 {[7 / 2]}_{4} - 5 g 1 / 2 {[9 / 2]}_{5}^{°}$
1066.486	50	93 765.86	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1068.551	400	93 584.69	$5 p 3 / 2 {[5 / 2]}_{3} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1069.220	30	93 526.16
1072.247	300	93 262.10	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1081.142	60	92 494.76
1081.412	60	92 471.73
1083.452	300	92 297.60	$5 p 1 / 2 {[3 / 2]}_{2} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1085.458	20p	92 126.96	$4 f 3 / 2 {[5 / 2]}_{3} - 5 g 1 / 2 {[7 / 2]}_{4}^{°}$
1087.047	200	91 992.36	$5 p 1 / 2 {[1 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1093.100	90	91 482.97	$5 p 3 / 2 {[3 / 2]}_{1} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1093.537	200	91 446.39	$5 p 1 / 2 {[1 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{0}^{°}$
1101.502	30	90 785.14
1105.566	40	90 451.42	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1108.794	200	90 188.06	$5 p 3 / 2 {[3 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1114.688	60	89 711.22
1115.533	90	89 643.27
1116.878	20	89 535.32	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1118.693	70	89 390.02
1123.205	50	89 030.95	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1130.152	70	88 483.71
1131.914	70	88 345.94
1132.230	5	88 321.28	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1132.377	60	88 309.78
1134.612	15	88 135.87
1141.223	100	87 625.30	$5 p 3 / 2 {[1 / 2]}_{0} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1142.552	50	87 523.40
1144.089	150	87 405.76	$4 s 4 p^{6} 4 d {¹ D}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
1144.583	15	87 368.05
1145.447	20	87 302.18
1154.761	100	86 598.04	$4 s 4 p^{6} 4 d {¹ D}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1166.603	100	85 718.97	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
1168.163	150	85 604.47	$5 p 1 / 2 {[1 / 2]}_{0} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1183.734	80	84 478.45	$5 p 1 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1185.965	5	84 319.49	$5 p 3 / 2 {[1 / 2]}_{0} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1188.556	5	84 135.72	$4 f 3 / 2 {[9 / 2]}_{5} - 5 g 3 / 2 {[9 / 2]}_{5}^{°}$
1194.240	300	83 735.24	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1200.761	300	83 280.55	$4 f 3 / 2 {[9 / 2]}_{5} - 5 g 3 / 2 {[11 / 2]}_{6}^{°}$
1200.938	60	83 268.27	$4 f 3 / 2 {[9 / 2]}_{4} - 5 g 3 / 2 {[9 / 2]}_{4}^{°}$
1212.935	100p	82 444.67	$4 f 3 / 2 {[9 / 2]}_{4} - 5 g 3 / 2 {[11 / 2]}_{5}^{°}$
1217.957	90	82 104.71	$4 f 1 / 2 {[7 / 2]}_{3} - 5 g 1 / 2 {[9 / 2]}_{4}^{°}$
1227.720	100p	81 451.78	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
1232.557	100	81 132.13	$4 f 1 / 2 {[7 / 2]}_{4} - 5 g 1 / 2 {[9 / 2]}_{5}^{°}$
1233.911	200	81 043.13	$5 p 3 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{0}^{°}$
1238.927	300	80 715.01	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
1245.952	150	80 259.91	$4 f 3 / 2 {[7 / 2]}_{3} - 5 g 3 / 2 {[9 / 2]}_{4}^{°}$
1247.248	30	80 176.50	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1253.607	300	79 769.80	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[5 / 2]}_{3}^{°}$
1259.696	200	79 384.23	$4 f 3 / 2 {[7 / 2]}_{4} - 5 g 3 / 2 {[9 / 2]}_{5}^{°}$
1260.914	400	79 307.54	$5 p 1 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1262.962	100	79 179.07	$4 f 1 / 2 {[5 / 2]}_{3} - 5 g 1 / 2 {[7 / 2]}_{4}^{°}$
1265.380	500	79 027.64	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[7 / 2]}_{3}^{°}$
1270.119	80	787 32.79	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1295.809	300	77 171.88	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[7 / 2]}_{3}^{°}$
1298.576	90	77 007.44	$5 p 3 / 2 {[5 / 2]}_{2} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1300.770	150	76 877.55	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1301.321	70	76 844.99	$4 f 3 / 2 {[5 / 2]}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
1302.027	80	76 803.32	$4 f 1 / 2 {[5 / 2]}_{2} - 5 g 1 / 2 {[7 / 2]}_{3}^{°}$
1302.804	400	76 757.51	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
1303.195	100p	76 734.49	$4 f 3 / 2 {[5 / 2]}_{3} - 5 g 3 / 2 {[7 / 2]}_{4}^{°}$
1303.933	500	76 691.03	$5 p 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[7 / 2]}_{4}^{°}$
1306.764	400	76 524.89	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
1312.247	60	76 205.17	$4 f 3 / 2 {[3 / 2]}_{1} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
1315.142	200	76 037.42	$5 p 1 / 2 {[1 / 2]}_{1} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1315.142	200	76 037.42	$4 f 3 / 2 {[5 / 2]}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1315.442	100	76 020.08	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1315.997	10	75 988.02	$4 f 3 / 2 {[5 / 2]}_{2} - 5 g 3 / 2 {[5 / 2]}_{2}^{°}$
1316.414	6	75 963.94	$4 f 3 / 2 {[5 / 2]}_{3} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1320.745	400	75 714.86	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
1323.813	500p	75 539.38	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[5 / 2]}_{3}^{°}$
1327.822	150	75 311.32	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
1332.063	300	75 071.55	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 d 1 / 2 {[1 / 2]}_{0}$
1337.338	300	747 75.39	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1340.423	30	746 03.29
1342.525	30	74 486.53
1352.053	50	73 961.57
1355.214	300	73 789.09	$5 p 1 / 2 {[1 / 2]}_{0} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1355.975	500	73 747.67	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
1360.104	70	73 523.80	$4 f 3 / 2 {[3 / 2]}_{2} - 5 g 3 / 2 {[7 / 2]}_{3}^{°}$
1361.387	300	73 454.48	$5 p 3 / 2 {[1 / 2]}_{0} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
1370.986	2	72 940.18	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[7 / 2]}_{3}^{°}$
1373.344	90	72 814.96
1375.212	80	72 716.06	$4 f 3 / 2 {[3 / 2]}_{2} - 5 g 3 / 2 {[5 / 2]}_{3}^{°}$
1376.542	500	72 645.80	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1384.389	20	72 236.11
1387.286	30	72 083.21	$5 p 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{0}^{°}$
1396.791	200	71 592.66
1400.335	50	71 411.50
1401.838	90	71 334.91
1408.844	90	70 980.18	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1409.836	80	70 930.23
1410.032	300	70 920.38	$5 p 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1411.328	30	70 855.23
1413.400	200	70 751.37
1419.918	60	70 426.58
1430.156	30	69 922.42
1437.120	60	69 583.59
1447.487	60	69 087.26
1451.948	90	68 872.98
1460.046	300	68 491.00
1462.478	80	68 377.10	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1484.570	60	67 359.56	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
1486.903	300	67 253.87
1491.328	300	67 054.33	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1506.187	100	66 392.81
1509.420	60	66 250.62
1517.616	90	65 892.83
1520.471	200	65 769.07
1533.218	50	65 222.30	$4 f 1 / 2 {[7 / 2]}_{4} - 5 g 3 / 2 {[11 / 2]}_{5}^{°}$
1534.723	150	65 158.33
1537.219	30	65 052.55	$5 p 3 / 2 {[1 / 2]}_{0} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1547.389	70	64 624.99
1550.124	200	64 510.95
1551.994	40	64 433.26
1559.284	70	64 131.98
1575.631	40	63 466.65
1585.853	90	63 057.55	$4 d {¹ P}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
1591.801	100	62 821.93
1603.774	60	62 352.94
1633.026	500	61 236.03	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
1645.336	40	60 777.86
1654.458	500	60 442.76	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 1 / 2 {[1 / 2]}_{0}$
1676.842	20	59 635.90	$5 p 1 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[3 / 2]}_{2}^{°}$
1682.255	50	59 444.03
1725.015	700	57 970.52	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
1735.947	8	57 605.45	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
1750.433	20	57 406.93
1765.578	5	56 638.68	$5 p 1 / 2 {[1 / 2]}_{1} - 5 d 3 / 2 {[1 / 2]}_{0}^{°}$
1767.791	30	56 567.78
1772.084	40	56 430.73
1786.197	500	55 984.87	$5 s 1 / 2 {[1 / 2]}_{0}^{°} - 5 p 1 / 2 {[1 / 2]}_{1}$
1790.812	200p	55 840.59	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
1806.091	500	55 368.19	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
1860.483	500	53 749.48	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{2}$
1860.864	600	53 738.47	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{3}$
1874.386	50	53 350.79
1878.333	500	53 238.70	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
1926.236	400	51 914.72	$4 d {¹ P}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{1}$
1927.427	500	51 882.63	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
1934.876	400	51 682.90	$5 s 1 / 2 {[1 / 2]}_{0}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
2009.941	500	49 752.70	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 1 / 2 {[3 / 2]}_{1}$
2029.193	600	49 280.67	$5 s 3 / 2 {[3 / 2]}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
2085.204	100	47 956.95	$4 d {¹ P}_{1}^{°} - 5 p 3 / 2 {[5 / 2]}_{2}$
2133.094	600	46 880.25	$5 s 3 / 2 {[3 / 2]}_{2}^{°} - 5 p 3 / 2 {[1 / 2]}_{1}$
2145.587	30	46 607.29	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 3 / 2 {[1 / 2]}_{0}$
2150.860	200	46 493.02
2221.867	80	45 007.17
2234.739	20	44 747.95
2337.660	200	42 777.81
2420.689	80	41 310.55
2429.285	80	41 164.38
2451.216	35	40 796.09
2454.626	60	40 739.41	$5 s 1 / 2 {[1 / 2]}_{1}^{°} - 5 p 3 / 2 {[3 / 2]}_{2}$
2473.925	30	40 421.60
2617.542	30	38 203.79
2646.243	30	37 789.43
2675.190	10	37 380.52

TABLE II

Energy levels of Zr v.

Configuration	Term	J	E(cm⁻¹)	Unc. (cm⁻¹)
4p⁶	¹S	0	0.0	1.9
4p⁵ 4d	³P°	0	241 381.3	0.6
	³P°	1	243 560.8	0.4
	³P°	2	247 962.3	0.3
	³F°	4	251 283.3	0.7
	³F°	3	253 753.4	0.4
	³F°	2	257 361.3	0.3
	³D°	3	265 845.5	0.4
	¹D°	2	270 560.8	0.2
	³D°	1	271 601.6	0.2
	³D°	2	274 654.6	0.2
	¹F°	3	277 145.5	0.3
	¹P°	1	328 940.75	0.09
4p⁵ 5s	3/2[3/2]°	2	325 014.87	0.10
	3/2[3/2]°	1	327 616.99	0.12
	1/2[1/2]°	0	340 315.49	0.13
	1/2[1/2]°	1	342 245.65	0.07
4p⁵ 5p	3/2[1/2]	1	371 895.16	0.12
	3/2[5/2]	2	376 897.68	0.09
	3/2[5/2]	3	378 753.36	0.12
	3/2[3/2]	1	380 855.53	0.11
	3/2[3/2]	2	382 985.08	0.08
	3/2[1/2]	0	388 852.95	0.10
	1/2[3/2]	1	391 998.41	0.10
	1/2[3/2]	2	395 994.98	0.13
	1/2[1/2]	1	396 300.35	0.11
	1/2[1/2]	0	402 688.40	0.14
4s4p⁶ 4d	³D	1	434 714.6	0.5
	³D	2	435 759.1	0.3
	³D	3	437 678.1	0.3
	¹D	2	450 133.7	0.3
4p⁵ 4f	3/2[9/2]	5	453 680.8	0.7
	3/2[9/2]	4	454 538.8	0.4
	3/2[7/2]	3	457 546.7	0.4
	3/2[7/2]	4	458 432.2	0.3
	3/2[3/2]	1	460 476.9	0.4
	3/2[5/2]	2	460 694.1	0.2
	3/2[5/2]	3	460 767.5	0.3
	3/2[3/2]	2	464 015.4	0.2
	1/2[7/2]	3	470 773.5	0.5
	1/2[7/2]	4	471 762.4	0.5
	1/2[5/2]	3	473 715.4	0.6
	1/2[5/2]	2	476 130.2	0.4
4p⁵ 5d	3/2[1/2]°	0	452 938.91	0.19
	3/2[1/2]°	1	453 905.60	0.16
	3/2[7/2]°	4	455 444.4	0.3
	3/2[3/2]°	2	455 630.8	0.14
	3/2[7/2]°	3	455 925.27	0.18
	3/2[5/2]°	2	457 613.1	0.3
	3/2[5/2]°	3	458 523.7	0.6
	3/2[3/2]°	1	462 307.4	0.3
	1/2[5/2]°	2	471 306.3	0.2
	1/2[3/2]°	2	472 015.28	0.19
	1/2[5/2]°	3	472 520.0	0.3
	1/2[3/2]°	1	476 477.4	0.3
4p⁵ 6s	3/2[3/2]°	2	472 338.0	0.2
	3/2[3/2]°	1	473 172.7	0.3
	1/2[1/2]°	0	487 746.6	0.3
	1/2[1/2]°	1	488 292.7	0.2
4p⁵ 6d	3/2[1/2]°	1	528 422.8	1.0
	3/2[7/2]°	4	529 161.6	1.1
	3/2[3/2]°	2	529 283.3	1.0
	3/2[7/2]°	3	529 299.6	1.1
	3/2[5/2]°	2	530 119.7	0.8
	3/2[5/2]°	3	530 465.5	0.8
	3/2[3/2]°	1	531 839.0	1.1
	1/2[3/2]°	1	546 323	15
4p⁵ 7s	3/2[3/2]°	2	536 763.9	0.7
	3/2[3/2]°	1	537 213.4	0.6
	1/2[1/2]°	0	552 258.2	1.2
	1/2[1/2]°	1	552 521.1	0.9
4p⁵ 5g	3/2[5/2]°	2	536 682.2	0.3
	3/2[5/2]°	3	536 731.5	0.2
	3/2[11/2]°	6	536 961.4	0.8
	3/2[11/2]°	5	536 983.9	0.8
	3/2[7/2]°	4	537 501.9	0.5
	3/2[7/2]°	3	537 539.2	0.2
	3/2[9/2]°	4	537 806.7	0.4
	3/2[9/2]°	5	537 816.5	0.4
	1/2[9/2]°	4	552 878.2	0.5
	1/2[7/2]°	4	552 894.5	0.5
	1/2[9/2]°	5	552 894.7	0.4
	1/2[7/2]°	3	552 933.5	0.5
4p⁵ 6g	3/2[5/2]°	2	570 779.3	1.0
	3/2[5/2]°	3	570 828.2	0.5
	3/2[11/2]°	6	570 946.5	1.0
	3/2[11/2]°	5	570 967.6	0.5
	3/2[7/2]°	4	571 271.7	0.4
	3/2[7/2]°	3	571 306.3	0.6
	3/2[9/2]°	4	571 443.6	0.6
	3/2[9/2]°	5	571 452.2	0.7
	1/2[9/2]°	4	586 704.9	0.8
	1/2[7/2]°	4	586 718.2	0.8
	1/2[9/2]°	5	586 734.5	0.8
4p⁵ 7d	3/2[3/2]°	1	568 040	16
	1/2[3/2]°	1	583 420	17
4p⁵ 8s	3/2[3/2]°	1	571 376	16
	1/2[1/2]°	1	586 882	17
4s4p⁶ 5p	¹P°	1	573 776	17
4p⁵ 9s	3/2[3/2]°	1	591 916	18
4p⁵ 10s	3/2[3/2]°	1	605 118	18

TABLE III

Calculated energy level values in cm⁻¹ and percentage compositions for the 4p⁵(4d + 5s) configurations of Zr v. States of 4p⁵ 5s are denoted by an asterisk. Negative eigenvector components are preceded by a minus sign.

J	E(obs.)	E(calc.)	obs.-calc.	% J₁l	Percentage composition—LS
0	241 381	241 499	−118	100% 3/2[1/2]	−100% ³P
	340 315	340 315	0	100% 1/2[1/2]*	100% ³P*
1	243 561	243 637	−76	67% 3/2 [1/2]	−98% ³P − 2% ³D
	271 602	271 353	249	49% 1/2[3/2]	97% ³D − 2% ³P − 1% ¹P
	327 617	327 616	1	84% 3/2[3/2]*	−45% ¹P* + 41% ³P* + 14% ¹P
	328 941	328 944	−3	37% 1/2[3/2]	85% ¹P − 8% ³P* + 6% ¹P* + 1% ³D
	342 246	342 247	−1	97% 1/2[1/2]*	−51% ³P* − 49% ¹P*
2	247 962	247 983	−21	78% 3/2[3/2]	92% ³P + 6% ³D + 2% ¹D
	257 361	257 315	46	73% 3/2[5/2]	−74% ³P + 15% ¹D − 11% ³D
	270 561	270 805	−244	73% 1/2[5/2]	47% ¹D − 27% ³D + 26% ³F
	274 655	274 738	−83	78% 1/2[3/2]	−56% ³D − 36% ¹D + 8% ³P
	325 015	325 016	−1	100% 3/2[3/2]*	−100% ³P*
3	253 753	253 551	202	68% 3/2[7/2]	87% ³F − 8% ¹F + 5% ³D
	265 846	266 079	−233	79% 3/2[5/2]	66% ³D + 34% ¹F
	277 146	277 036	110	87% 1/2[5/2]	−58% ¹F + 29% ³D − 13% ³F
4	251 283	251 114	169	100% 3/2[7/2]	100% ³F

TABLE IV

Energy parameters in cm⁻¹ and mean errors Δ of least-squares fits for Zr v.

Configuration	Parameter	HF	Fitted	Fitted/HF
4p⁵ 4d	E_av	258 435	264 395 ± 69
	F²(4p4d)	65 714	55 869 ± 615	0.850
	G¹(4p4d)	81 768	60 622 ± 363	0.741
	G³(4p4d)	50 422	43 933 ± 1144	0.87
	ζ₄_p	9 007	9 633 ± 179	1.07
	ζ₄_d	620	652 ± 75	1.05
4p⁵ 5s	E_av	330 839	331 289 ± 171
	G¹(4p5s)	7 500(0.40) ^a	7 066 ± 895	0.94
	ζ₄_p	9 302	10 200 ± 205	1.10
Configuration	R²(4p4d,4p5s)	−7 023 (−0.22)	−2 039 ± 2001	0.29
Interaction	R¹(4p4d,5s4p)	190 (0.005)	55^b
	Δ		218
4p⁵ 5p	E_av	380 074	384 586 ± 24
	F²(4p5p)	22 151	21 060 ± 198	0.951
	G⁰(4p5p)	4 481 (0.20)	4 121 ± 20	0.920
	G²(4p5p)	6 098 (0.60)	5 910 ± 326	0.97
	ζ₄_p	9 363	10 219 ± 38	1.091
	ζ₅_p	1 674	2 242 ± 45	1.34
	Δ		72
4p⁵ 5d	E_av	453 723	462 027 ± 12
	F²(4p5p)	15 901	13 835 ± 146	0.870
	G¹(4p5d)	9 462 (0.75)	9 293 ± 58	0.982
	G³(4p5d)	6 790 (0.90)	6 110 ± 241	0.90
	ζ₄_p	9 356	10 256 ± 19	1.096
	ζ₅_d	154	207 ± 13	1.34
4p⁵ 6s	E_av	470 595	477 815 ± 23
	G¹(4p6s)	2 357 (0.36)	2 103 ± 142	0.89
	ζ₄_p	9 380	10 301 ± 30	1.098
Configuration	R²(4p5d,4p6s)	518 (0.06)	295^c
Interaction	R¹(4p5d,6s4p)	1 373 (0.16)	782 ± 447	0.57
	Δ		41
4p⁵ 4f	E_av	458 854	461 077 ± 63
	F²(4p4f)	25 338	24 265 ± 840	0.96
	G²(4p4f)	15 451	14 266 ± 808	0.92
	G⁴(4p4f)	10 215	8 315 ± 1112	0.81
	ζ₄_p	9 345	10 143 ± 75	1.085
	ζ₄_f	4	36^d
4s4p⁶ 4d	E_av	463 830	447 232 ± 190
	G²(4s4d)	60 448	23 028 ± 1432	0.38
	ζ₄_p	636	566 ± 111	0.89
Configuration	R²(4p4d,4f4s)	29 125	9 446 ± 710	0.32
Interaction	R¹(4p4d,4s4f)	47 899	27 962 ± 199	0.584
	Δ		139
4p⁵ 5g	E_av	531 679	542 489 ± 2
	F²(4p5g)	4 758	4 277 ± 28	0.899
	G³(4p5g)	392	286 ± 33	.73
	G⁵(4p5g)	276	108 ± 56	.39
	ζ₄_p	9 421	10 385 ± 3	1.1023
	ζ₅_g	0.3	0^e
	Δ		8
4p⁵ 6d	E_av	542 640	534 855 ± 15
	F²(4p6d)	6 941	6 195 ± 142	0.89
	G¹(4p6d)	3 679	3 402 ± 45	0.925
	G³(4p6d)	2 769	2 476 ± 241	0.89
	ζ₄_p	9 393	10 325^f
	ζ₆_d	74	115 ± 13	1.55
4p⁵ 7s	E_av	532 684	542 098 ± 17
	G¹(4p7s)	1 095 (0.34)	1 014 ± 94	0.93
	ζ₄_p	9 402	10 335 ± 19	1.098
Configuration	R²(4p6d,4p7s)	768	768^g
Interaction	R¹(4p6d,7s4p)	715	715^g
	Δ		33
4p⁵ 6g	E_av	564 519	576 338 ± 2
	F²(4p6g)	2 786	2 513 ± 23	0.902
	G³(4p6g)	372	286 ± 34	0.77
	G⁵(4p6g)	263	167 ± 49	0.63
	ζ₄_p	9 421	103 83 ± 3	1.1021
	ζ₆_g	0.2	0^e
	Δ		7

TABLE V

Calculated energy level values and percentage compositions for the 4p⁵ 5p configuration of Zr v. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
0	388 853	388 812	41	78% 3/2[1/2]	79% ³P − 21% ¹S
	402 688	402 699	−11	78% 1/2[1/2]	79% ¹S + 21% ³P
1	371 895	371 929	−34	91% 3/2[1/2]	85% ³S + 14% ³P
	380 856	380 949	−93	94% 3/2[3/2]	46% ¹P − 31% ³D − 20% ³P + 3% ³S
	391 998	391 978	20	92% 1/2[3/2]	64% ³D + 33% ¹P − 2% ³P
	396 300	396 300	0	89% 1/2[1/2]	−64% ³P − 20% ¹P + 12% ³S + 4% ³D
2	376 898	376 857	41	87% 3/2[5/2]	58% ³D − 34% ¹D + 8% ³P
	382 985	383 012	−27	87% 3/2[3/2]	68% ³P + 31% ¹D + 1% ³D
	395 995	396 010	−15	99% 1/2[3/2]	−40% ³D − 35% ¹D + 25% ³P
3	378 753	378 674	79	100% 3/2[5/2]	100% ³D

TABLE VI

Calculated energy level values in cm⁻¹ and percentage compositions for the 4p⁵(5d + 6s) configurations of Zr v. States of 4p⁵ 6s are denoted by an asterisk. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
0	452 939	452 940	−1	100% 3/2[1/2]	100% ³P
	487 747	487 766	−19	100% 1/2[1/2]*	100% ³P*
1	453 906	453 898	8	67% 3/2[1/2]	−90% ³P − 10% ³D
	462 307	462 273	34	66% 3/2[3/2]	57% ³D − 39% ¹P − 4% ³P
	473 173	473 184	−11	98% 3/2[3/2]*	−62% ¹P* + 37% ³P* + 1% ³D
	476 477	476 500	−23	91% 1/2[3/2]	60% ¹P + 33% ³D − 6% ³P − 1% ³P*
	488 293	488 273	20	100% 1/2[1/2]*	−62% ³P* − 38% ¹P*
2	455 631	455 643	−12	96% 3/2[3/2]	66% ³P + 24% ³D + 9% ¹D
	457 613	457 621	−8	98% 3/2[5/2]	45% ¹D − 31% ³F − 23% ³D
	471 306	471 262	44	97% 1/2[5/2]	−67% ³F − 25% ¹D + 8% ³D
	472 015	472 071	−56	92% 1/2[3/2]	−43% ³D + 31% ³P − 21% ¹D + 4% ³P*
	472 338	472 324	14	96% 3/2[3/2]*	96% ³P* + 2% ³D − 1% ³P + 1% ¹D
3	455 925	455 956	−31	91% 3/2[7/2]	61% ³F − 34% ¹F + 5% ³D
	458 524	458 523	1	91% 3/2[5/2]	66% ³D + 31% ¹F + 3% ³F
	472 520	472 492	28	99% 1/2[5/2]	−35% ¹F − 36% ³F + 29% ³D
4	455 444	455 434	10	100% 3/2[7/2]	100% ³F

TABLE VII

Calculated energy level values in cm⁻¹ and percentage compositions for the 4s4p⁶ 4d + 4p⁵ 4f configurations of Zr v. States of 4s4p⁶ 4d are denoted by an asterisk. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
1	434 715	434 629	86		64% ³D* + 36% ³D
	460 477	460 626	−149	64% 3/2[3/2]	64% ³D − 36% ³D*
2	435 759	435 813	−54		66% ³D* + 33% ³D + 1% ³F
	450 134	450 134	0		−76% ¹D* − 21% ¹D + 2% ³F − 1% ³D
	460 694	460 566	128	55% 3/2[5/2]	−41% ³D − 33% ³F + 25% ³D* + 1% ¹D
	464 015	464 016	−1	42% 3/2[3/2]	31% ¹D − 29% ³F − 19% ¹D* + 14% ³D − 7% ³D*
	476 130	476 131	−1	90% 1/2[5/2]	47% ¹D + 35% ³F − 11% ³D − 5% ¹D* + 2% ³D*
3	437 678	437 706	−28		−71% ³D* − 27% ³D − 1% ³F − 1% ¹F
	457 547	457 680	−133	95% 3/2[7/2]	−46% ³G + 30% ¹F − 24% ³F
	460 768	460 682	86	79% 3/2[5/2]	−31% ³D − 27% ³F + 21% ³D* − 21% ¹F
	470 774	470 898	−124	95% 1/2[7/2]	−54% ³G − 26% ¹F + 19% ³F
	473 715	473 648	67	91% 1/2[5/2]	41% ³D − 29% ³F − 21% ¹F − 8% ³D*
4	454 539	454 584	−45	95% 3/2[9/2]	61% ³G − 37% ¹G + 2% ³F
	458 432	458 449	−17	93% 3/2[7/2]	57% ³F + 33% ¹G + 10% ³G
	471 762	471 690	72	97% 1/2[7/2]	41% ³F − 30% ¹G − 28% ³G
5	453 681	453 566	115	100% 3/2[9/2]	100% ³G

TABLE VIII

Calculated energy level values in cm⁻¹ and percentage compositions for the 4p⁵ 5g configuration of Zr v. Negative eigenvector components are preceded by a minus sign.

J	E (obs.)	E (calc.)	obs.-calc.	% J₁l	Percentage composition—LS
2	536 682	536 674	8	100% 3/2[5/2]	100% ³F
3	536 732	536 731	1	100% 3/2[5/2]	61% ³F + 39% ¹F
	537 539	537 535	4	99% 3/2[7/2]	54% ³G − 30% ¹F + 16% ³F
	552 934	552 939	−5	100% 1/2[7/2]	46% ³G + 31% ¹F − 22% ³F
4	537 502	537 495	7	100% 3/2[7/2]	−46% ³F − 30% ³G − 24% ¹G
	537 807	537 811	−4	100% 3/2[9/2]	39% ¹G − 31% ³G − 30% ³H
	552 878	552 880	−2	100% 1/2[9/2]	70% ³H + 17% ¹G − 13% ³G
	552 894	552 896	−2	100% 1/2[7/2]	54% ³F − 26% ³G − 20% ¹G
5	536 984	536 988	−4	100% 3/2[11/2]	−54% ¹H + 46% ³H
	537 816	537 815	1	100% 3/2[9/2]	70% ³G + 16% ³H + 14% ¹H
	552 895	552 888	7	100% 1/2[9/2]	−38% ³H − 32% ¹H + 30% ³G
6	536 961	536 973	−12	100%3/2[11/2]	100% ³H

Top

Information for
Authors
Reviewers
Librarians

Abstract

Cited By

Figures (7)

Tables (8)

Equations (333)

Journal of the Optical Society of America