Fluoroform-d optically pumped submillimeter-wave laser

M. S. Tobin; R. D. Felock

doi:10.1364/OL.5.000430

Optics Letters
Vol. 5,
Issue 10,
pp. 430-432
(1980)
•https://doi.org/10.1364/OL.5.000430

Fluoroform-d optically pumped submillimeter-wave laser

M. S. Tobin and R. D. Felock

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M. S. Tobin and R. D. Felock, "Fluoroform-d optically pumped submillimeter-wave laser," Opt. Lett. 5, 430-432 (1980)

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Abstract

Submillimeter-wave laser action in deuterated fluoroform is reported for the first time to our knowledge. A total of 27 lines was observed when CDF₃ was pumped by various CO₂ lines in the 9- and 10-μm regions. Near-milliwatt-level cw power on 10 lines was observed in a nonoptimized hole-coupled metallic-waveguide resonator. Tentative spectroscopic assignments are made for the strongest lines.

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CO₂ Pump Line	Pump Mode^a	λ_SMMW^(MEAS)		Relative Signal Strength^b	Relative Polarization^c	Tentative Assignments^d

						IR	SMMW	λ_SMMW^(CALC) (cm⁻¹)

		(μm)	(cm⁻¹)
10P(24)	CW	361.3	27.68	M	║	ν₅,^RP(43,10)	^QR(41,11)	27.68
10P(20)	CW	433.2	23.08	S	║	ν₅, ^RP(36,12)	^QR(34,13)	23.09
10P(14)	CW	266.0	37.59	M	┴	ν₅,^RQ(57,44)	^QR(56,45)	37.56
10P(12)	CW	658.4	15.19	S	║	ν₅,^RP(24,14)	^QR(22,15)	15.20
10P(6)	CW	658.0	15.20	S	║	ν₅,^RP(24,5)	^QR(22,6)	15.19
10R(4)	CW	286.8	34.87	M	–	–	^QR(22,K)	34.85^e
10R(8)	CW	329.9	30.31	S	┴	ν₅^RQ(46, 12)	^QR (45,13)	30.30
10R(10)	CW	688.7	14.52	M	–	ν₅,^PP(24, 18)	^QR(21,17)	14.54
	CW	658.5	15.19	VS	║	ν₅^PP(24,18)	^QR (22,17)	15.20
	CW	286.8	34.87	M	┴	ν₅^RQ(53,19)	^QR (52,10)	34.86
10R(12)	CW	1008.0	9.921	S	║	ν₅,^PP(16, 11)	^QR (14,10)	9.916
10R(16)	CW	1261.0	7.930	M	–	–	^QR(11,K)	7.933^e
10R(20)	CW	316.6	31.59	M	┴	ν₅^PQ(48,3)	^QR(47,2)	31.60
10R(24)	C	521.4	19.18	W	–	–	^QR(28,K)	19.14^e
10R(26)	CW	420.0	23.81	M	–	–	^QR(35,K)	23.74^e
10R(28)	CW	582.4	17.17	M	║	ν₅,^RR(25,20)	^QR (25,21)	17.18
10R(32)	C	388.0	25.77	W	–	–	^QR(38,K)	25.71^e
10R(36)	CW	540.5	18.50	S	┴	ν₅,^PQ(28,19)	^QR (27,18)	18.50
10R(38)	CW	488.2	20.45	VS	┴	ν₅,^PQ(31,21)	^QR (30,20)	20.47
10R(40)	CW	560.8	17.83	S	║	ν₅^RR(26,9)	^QR (26,10)	17.83
10R(42)	CW	388.6	25.73	S	┴	ν₅,^PQ(39,25)	^QR (38,24)	25.73
10R(44)	C	421.1	23.75	M	–	–	^QR(35,K)	23.74^e
10R(48)	CW	286.3	34.93	W	–	–	^QR(52,K)	34.85^e
9P(44)	C	266.9	37.47	W	–	–	^QR(56,K)	37.45^e
9R(14)^f	CW	–	–	W	–	–	–	–
97R(22)	c	345.8	28.92	W	║	ν₂,^QP(45,K)	^QR(43,K)	28.85^e
97R(24)	CW	362.5	27.59	W	║	ν₂^QP(43,K)	^QR(41,K)	27.55^e

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