Relaxation Mechanisms and Lifetime of the OH Stretching Vibration in Aqueous Hydrates

Jasper C. Werhahn; Sotiris S. Xantheas; Hristo Iglev

doi:10.1364/HILAS.2012.JT2A.45

Research in Optical Sciences
OSA Technical Digest (Optica Publishing Group, 2012),
paper JT2A.45
•https://doi.org/10.1364/HILAS.2012.JT2A.45

Relaxation Mechanisms and Lifetime of the OH Stretching Vibration in Aqueous Hydrates

Jasper C. Werhahn, Sotiris S. Xantheas, and Hristo Iglev

International Conference on Ultrafast Structural Dynamics 2012

Berlin Germany
19–21 March 2012
ISBN: 978-1-55752-939-8

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J. C. Werhahn, S. S. Xantheas, and H. Iglev, "Relaxation Mechanisms and Lifetime of the OH Stretching Vibration in Aqueous Hydrates," in Research in Optical Sciences, OSA Technical Digest (Optica Publishing Group, 2012), paper JT2A.45.

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Abstract

Nonlinear infrared spectroscopy gives evidence for intermolecular energy transfer as primary channel for the relaxation of the OH stretching vibration of HDO. Properties of bifurcated hydrogen bonds are unambiguously compared to strong and weak ones.

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