Laser-induced fragmentation fluorescence from C2(d3πg→a3πu) provides a detection strategy for vinyl and acetylene. The efficiency of C2(d3πg) production via multi-photon photodissociation depends on the H-atom loss mechanism and the internal energy of the precursor molecule.
© 2006 Optical Society of America
(120.0120) Instrumentation, measurement, and metrology : Instrumentation, measurement, and metrology
(120.1740) Instrumentation, measurement, and metrology : Combustion diagnostics
(300.0300) Spectroscopy : Spectroscopy
(300.2530) Spectroscopy : Fluorescence, laser-induced
J. H. Frank, D. L. Osborn, and N. Hansen, "Laser-Induced Fragmentation Fluorescence of Vinyl and Acetylene," in Laser Applilcations to Chemical, Security and Environmental Analysis, Technical Digest (Optical Society of America, 2006), paper MB3.
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