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Ultrafast intersystem crossing in a transition metal complex

Eric A. Juban and James K. McCusker

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Abstract

Intersystem crossing is an important aspect of virtually all photophysical and photochemical processes involving transition metals. One of the most extensively studied transition metal ions is chromium(III)[1,2]. A diagram of this ion’s electronic structure, depicting d-electrons under octahedral symmetry, is illustrated in Figure 1.

© 2002 Optical Society of America

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