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Optica Publishing Group
  • The Thirteenth International Conference on Ultrafast Phenomena
  • 2002 OSA Technical Digest Series (Optica Publishing Group, 2002),
  • paper WD21
  • https://doi.org/10.1364/UP.2002.WD21

Ultrafast Pump-Probe and Resonance Raman Spectroscopic Study of Excited State Electronic Coupling in Two Related Hexanuclear Charge Transfer Compounds

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Abstract

Photoinduced multi-electron transfer is reported in two hexanuclear intervalant charge transfer complexes of Pt(IV) and Fe(III). Femtosecond pump-probe spectroscopy, resonance Raman and electrochemical data suggest the degree of excited state electronic coupling is tunable by changing the electronic nature of the bridging ligand.

© 2002 Optical Society of America

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