We report spectrally-integrated, visible-pump, mid-infrared probe studies of the CO ligand in myoglobin. Supported by density functional calculations, we find that the CO oscillator strength and frequency changes occur on disparate timescales following dissociation.
© 2004 Optical Society of America
J. P. Ogilvie, T. Polack, S. Franzen, M. H. Vos, M. Joffre, J. L. Martin, and A. Alexandrou, "The CO oscillator as a probe of ligand dissociation dynamics in myoglobin," in 14th International Conference on Ultrafast Phenomena, Technical Digest (CD) (Optical Society of America, 2004), paper ThD29.
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