UV Femtosecond fluorescence and transient-absorption studies of ferric and ferrous cytochrome-C are presented. We characterize their photocycles which are described in terms of a model based on electron metal-to-heme back-donation from occupied metal d orbitals.
© 2010 OSA
A. Cannizzo, O. Bräm, C. Consani, F. van Mourik, and M. Chergui, "Femtosecond UV Studies of Relaxation Processes in Cytochrome C," in International Conference on Ultrafast Phenomena, OSA Technical Digest (CD) (Optical Society of America, 2010), paper ME9.
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