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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: Joseph N. Mait
  • Vol. 48, Iss. 22 — Aug. 1, 2009
  • pp: 4424–4429

Improved sensitivity gas detection by spontaneous Raman scattering

Michael P. Buric, Kevin P. Chen, Joel Falk, and Steven D. Woodruff  »View Author Affiliations


Applied Optics, Vol. 48, Issue 22, pp. 4424-4429 (2009)
http://dx.doi.org/10.1364/AO.48.004424


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Abstract

Accurate, real-time measurement of the dilute constituents of a gaseous mixture poses a significant challenge usually relegated to mass spectrometry. Here, spontaneous Raman backscattering is used to detect low pressure molecular gases. Rapid detection of gases in the 100 parts in 10 6 ( ppm ) range is described. Improved sensitivity is brought about by use of a hollow-core, photonic bandgap fiber gas cell in the backscattering configuration to increase collection efficiency and an image-plane aperture to greatly reduce silica-Raman background noise. Spatial and spectral properties of the silica noise were examined with a two-dimensional CCD detector array.

© 2009 Optical Society of America

OCIS Codes
(300.6450) Spectroscopy : Spectroscopy, Raman
(060.5295) Fiber optics and optical communications : Photonic crystal fibers

ToC Category:
Spectroscopy

History
Original Manuscript: April 30, 2009
Revised Manuscript: July 1, 2009
Manuscript Accepted: July 6, 2009
Published: July 24, 2009

Citation
Michael P. Buric, Kevin P. Chen, Joel Falk, and Steven D. Woodruff, "Improved sensitivity gas detection by spontaneous Raman scattering," Appl. Opt. 48, 4424-4429 (2009)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-48-22-4424


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References

  1. T. Ritari, J. Tuominen, H. Ludvigsen, J. C. Petersen, T. Sørensen, T. P. Hansen, and H. R. Simonsen, “Gas sensing using air-guiding photonic bandgap fibers,” Opt. Express 12, 4080-4087 (2004). [CrossRef] [PubMed]
  2. M. P. Buric, K. P. Chen, J. Falk, and S. D. Woodruff, “Enhanced spontaneous Raman scattering and gas composition analysis using a photonic bandgap fiber,” Appl. Opt. 47, 4255-4261(2008). [CrossRef] [PubMed]
  3. X. Cao and C. N. Hefwitt, “Detection methods for the analysis of biogenic non-methane hydrocarbons in air,” J. Chromatogr. A 710, 39-50 (1995). [CrossRef]
  4. M. R. Beychok, “Coal gasification and the Phenosolvan process,” presented at the 168th National Meeting of the American Chemical Society, Atlantic City, 8-13 September 1974 (American Chemical Society, 1974); FUEL 33.
  5. J. Kiefer, T. Seeger, S. Steuer, S. Schorsch, M. C. Weikl, and A. Leipertz, “Design and characterization of a Raman scattering--based sensor system for temporally resolved gas analysis and its application in a gas turbine power plant,” Meas. Sci. Technol. 19, 085408 (2008), [CrossRef]
  6. B. E. A. Saleh and M. C. Teich, Fundamentals of Photonics, 2nd ed. (Wiley-Interscience, 2007). p. 554.
  7. N. V. Wilding, P. S. Light, F. Couny, and F. Benabid, “Experimental comparison of electromagnetic induced transparency in acetylene-filled kagomé and triangular lattice hollow core photonic crystal fiber,” in Conference on Lasers and Electro-Optics (Optical Society of America, 2008), paper JFA3. [CrossRef]
  8. S. Afshar V., Y. Ruan, S. C. Warren-Smith, and T. M. Monro, “Enhanced fluorescence sensing using microstructured optical fibers: a comparison of forward and backward collection modes,” Opt. Lett. 33, 1473-1475 (2008). [CrossRef] [PubMed]
  9. HC-580 HC-PBF data sheet retrieved 3 September 2008 from http://www.i-waveco.com/category/pdf/5131-HC58001.pdf.
  10. HC-800-01 HC-PBF data sheet retrieved 3 November 2008 from http://www.crystal-fibre.com/datasheets/HC-800-01.pdf,
  11. Semrock beam splitter data sheet. Downloaded 23 July 2008 from http://www.semrock.com/Catalog/RamanEdgeDichroic.htm.
  12. D. Pristinski and H. Du, “Solid-core photonic crystal fiber as a Raman spectroscopy platform with a silica core as an internal reference,” Opt. Lett. 31, 3246-3248 (2006). [CrossRef] [PubMed]
  13. The 14 mm lens focusing into the pinhole plane exhibited significant chromatic aberration so that the oxygen Raman signal shown in Fig. was reduced by approximately 43% with the addition of the pinhole. Later experiments utilizing an achromatic-doublet lens resulted in little attenuation at both wavelengths with the addition of the aperture.
  14. R. W. Boyd, Radiometry and the Detection of Optical Radiation (Wiley, 1983), pp. 132-136.
  15. J. Henningsen and J. Hald, “Dynamics of gas flow in hollow core photonic bandgap fibers,” Appl. Opt. 47, 2790-2797(2008). [CrossRef] [PubMed]
  16. W. Fenner, H. A. Hyatt, J. M. Kellam, and S. P. S. Porto, “Raman cross section of some simple gases,” J. Opt. Soc. Am. 63, 73-77 (1973). [CrossRef]
  17. J. J. Barrett and N. I. Adams III, “Laser-excited rotation-vibration Raman scattering in ultra-small gas samples,” J. Opt. Soc. Am. 58, 311-318 (1968). [CrossRef]

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