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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: Joseph N. Mait
  • Vol. 50, Iss. 24 — Aug. 20, 2011
  • pp: 4805–4816

Improved multiple-pass Raman spectrometer

Utsav KC, Joel A. Silver, David C. Hovde, and Philip L. Varghese  »View Author Affiliations


Applied Optics, Vol. 50, Issue 24, pp. 4805-4816 (2011)
http://dx.doi.org/10.1364/AO.50.004805


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Abstract

An improved Raman gain spectrometer for flame measurements of gas temperature and species concentrations is described. This instrument uses a multiple-pass optical cell to enhance the incident light intensity in the measurement volume. The Raman signal is 83 times larger than from a single pass, and the Raman signal-to-noise ratio (SNR) in room-temperature air of 153 is an improvement over that from a single-pass cell by a factor of 9.3 when the cell is operated with 100 passes and the signal is integrated over 20 laser shots. The SNR improvement with the multipass cell is even higher for flame measurements at atmospheric pressure, because detector readout noise is more significant for single-pass measurements when the gas density is lower. Raman scattering is collected and dispersed in a spectrograph with a transmission grating and recorded with a fast gated CCD array detector to help eliminate flame interferences. The instrument is used to record spontaneous Raman spectra from N2, CO2, O2, and CO in a methane–air flame. Curve fits of the recorded Raman spectra to detailed simulations of nitrogen spectra are used to determine the flame temperature from the shapes of the spectral signatures and from the ratio of the total intensities of the Stokes and anti-Stokes signals. The temperatures measured are in good agreement with radiation-corrected thermocouple measurements for a range of equivalence ratios.

© 2011 Optical Society of America

OCIS Codes
(120.1740) Instrumentation, measurement, and metrology : Combustion diagnostics
(300.6190) Spectroscopy : Spectrometers
(300.6450) Spectroscopy : Spectroscopy, Raman

ToC Category:
Spectroscopy

History
Original Manuscript: May 3, 2011
Manuscript Accepted: June 11, 2011
Published: August 16, 2011

Citation
Utsav KC, Joel A. Silver, David C. Hovde, and Philip L. Varghese, "Improved multiple-pass Raman spectrometer," Appl. Opt. 50, 4805-4816 (2011)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-50-24-4805


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