Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group

Reaction Rate of Vibrationally Excited Hydroxyl with Ozone

Not Accessible

Your library or personal account may give you access

Abstract

The reaction of vibrationally excited hydroxyl with ozone was studied in a fast-flow system by observing the effect of ozone concentration on the intensity of hydroxyl emission bands in the 1.4-μ to 2.2-μ wavelength region. Fourier transform spectroscopy was used to obtain spectra of the faint emissions from the excited hydroxyl. Rate constants for the ozone-hydroxyl reaction were calculated for vibrational levels v = 2 to v = 9. The rate constants increased with vibrational level in a regular manner up to v = 5. An abrupt increase occurred for v = 6 relative to v = 5, which may suggest a change in mechanism beginning at v = 6.

© 1971 Optical Society of America

Full Article  |  PDF Article
More Like This
Formation of Vibrationally Excited OH by the Reaction H + O3

P. E. Charters, R. G. Macdonald, and J. C. Polanyi
Appl. Opt. 10(8) 1747-1754 (1971)

Vibrationally excited hydroxyl tagging velocimetry

Nathan Grady and Robert W. Pitz
Appl. Opt. 53(31) 7182-7188 (2014)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Figures (2)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (1)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (7)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved