Abstract
The reaction of vibrationally excited hydroxyl with ozone was studied in a fast-flow system by observing the effect of ozone concentration on the intensity of hydroxyl emission bands in the 1.4-μ to 2.2-μ wavelength region. Fourier transform spectroscopy was used to obtain spectra of the faint emissions from the excited hydroxyl. Rate constants for the ozone-hydroxyl reaction were calculated for vibrational levels v = 2 to v = 9. The rate constants increased with vibrational level in a regular manner up to v = 5. An abrupt increase occurred for v = 6 relative to v = 5, which may suggest a change in mechanism beginning at v = 6.
© 1971 Optical Society of America
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