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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 19, Iss. 11 — Jun. 1, 1980
  • pp: 1833–1837

Deconvolution of infrared spectra beyond the Doppler limit

J. Plíva, A. S. Pine, and P. D. Willson  »View Author Affiliations


Applied Optics, Vol. 19, Issue 11, pp. 1833-1837 (1980)
http://dx.doi.org/10.1364/AO.19.001833


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Abstract

It is shown that the deconvolution method of Van Cittert can be used reliably to enhance the effective spectral resolution by a factor of ∼3 with data that exhibit a high SNR (∼103) and in which base line variations have been eliminated. Deconvolution of a Doppler-limited spectrum of C6H6 measured on a difference-frequency laser system yielded linewidths of ∼1.2 × 10−3 cm−1 (compared with the Doppler width of 3.6 × 10−3 cm−1 at 203 K). Extensive reliability tests of the deconvolution technique have been performed.

© 1980 Optical Society of America

History
Original Manuscript: January 21, 1980
Published: June 1, 1980

Citation
J. Plíva, A. S. Pine, and P. D. Willson, "Deconvolution of infrared spectra beyond the Doppler limit," Appl. Opt. 19, 1833-1837 (1980)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-19-11-1833


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References

  1. P. H. Van Cittert, Phys Z. 69, 298 (1931). [CrossRef]
  2. H. C. Burger, P. H. Van Cittert, Phys Z. 79, 722 (1932);Phys Z. 81, 428 (1933). [CrossRef]
  3. P. A. Jansson, J. Opt. Soc. Am. 60, 184 (1970). [CrossRef]
  4. P. A. Jansson, R. H. Hunt, E. K. Plyler, J. Opt. Soc. Am. 60, 596 (1970). [CrossRef]
  5. P. D. Willson, J. R. Hanratty, T. H. Edwards, presented at 1972 Symposium on Molecular Spectroscopy, Columbus, Ohio.
  6. P. D. Willson, Ph.D. Dissertation, Michigan State U. (1973).
  7. G. Halsey, W. E. Blass, Appl. Opt. 16, 286 (1977). [CrossRef] [PubMed]
  8. A. S. Pine, J. Opt. Soc. Am. 64, 1683 (1974);J. Opt. Soc. Am. 66, 97 (1976). [CrossRef]
  9. S. R. Polo, P. D. Willson, to be published.

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