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Applied Optics

Applied Optics


  • Vol. 19, Iss. 16 — Aug. 15, 1980
  • pp: 2726–2734

Carbon dioxide laser absorption spectra and low ppb photoacoustic detection of hydrazine fuels

G. L. Loper, A. R. Calloway, M. A. Stamps, and J. A. Gelbwachs  »View Author Affiliations

Applied Optics, Vol. 19, Issue 16, pp. 2726-2734 (1980)

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Absorption cross-section data are reported for the toxic rocket fuels hydrazine, monomethylhydrazine, and unsymmetrical dimethylhydrazine (UDMH), as well as for their selected air oxidation products dimethylamine, trimethylamine, and methanol at up to seventy-eight CO2 laser wavelengths each. These data are important for the assessment of the capability of CO2 laser-based spectroscopic techniques for monitoring low levels of hydrazine-fuel vapors in the ambient air. Interference-free detection sensitivities of <30 ppb have been demonstrated for UDMH using a laboratory photoacoustic detection system.

© 1980 Optical Society of America

Original Manuscript: March 3, 1980
Published: August 15, 1980

G. L. Loper, A. R. Calloway, M. A. Stamps, and J. A. Gelbwachs, "Carbon dioxide laser absorption spectra and low ppb photoacoustic detection of hydrazine fuels," Appl. Opt. 19, 2726-2734 (1980)

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  1. Department of Health, Education, and Welfare, NIOSH Registry of Toxic Effects of Chemical Substances, Vol. 2, (U.S. GPO,Washington, D.C., 1977).
  2. “NIOSH Recommendations for a Hydrazines Standard,” Occup. Safety Health Reporter, 8, 672 (19Oct.1978).
  3. G. L. Loper, “Gas Phase Kinetic Study of Air Oxidation of UDMH,” in Proceedings, Conference on Environmental Chemistry of Hydrazine Fuels, Tyndall AFB, 13 Sept. 1977, CEEDO-TR-78-14, pp. 129–159.
  4. G. L. Loper, A. R. Calloway, M. A. Stamps, J. A. Gelbwachs, “Expected Detectabilities of Hydrazine-Based Rocket Fuels and their Selected Oxidation Products by 12C16O2 Laser Spectroscopic Techniques,” Aerospace Corp. Report, TR-0079(4970-50)-2 (1979).
  5. G. L. Loper, A. R. Calloway, M. A. Stamps, J. A. Gelbwachs, “CO2 Laser Photoacoustic Detection of the Hydrazine-Based Rocket Fuels,” Aerospace Corp. Report, TR-0080 (5970-09)-2 (1980).
  6. C. K. N. Patel, Science 202, 157 (1978). [CrossRef] [PubMed]
  7. E. L. Kerr, J. G. Atwood, Appl. Opt. 7, 915 (1968);L. B. Kreuzer, N. D. Kenyon, C. K. N. Patel, Science 177, 347 (1972);L. B. Kreuzer, Anal. Chem. 46, 239A (1974). [CrossRef] [PubMed]
  8. R. J. Brewer, C. W. Bruce, Appl. Opt. 17, 3746 (1978). [CrossRef] [PubMed]
  9. B. D. Green, J. I. Steinfeld, Environ. Sci. Technol. 10, 1134 (1976). [CrossRef] [PubMed]
  10. E. R. Murray, R. D. Hake, J. E. van der Lann, J. G. Hawley, Appl. Phys. Lett. 28, 542 (1976);R. T. Menzies, M. S. Shumate, J. Geophys. Res. 83, C8, 4039 (1978);E. R. Murray, Opt. Eng. 17, 30 (1978);E. R. Murray, J. E. van der Laan, Opt. Eng. 17, 815 (1978). [CrossRef]
  11. R. Beck, W. Englisch, K. Gürs, Table of Laser Lines in Gases and Vapors, Springer Series in Optical Sciences, Vol. 2 (Springer, Berlin, 1978).
  12. T. F. Deaton, D. A. Depatie, T. W. Walker, Appl. Phys. Lett. 26, 300 (1975). [CrossRef]
  13. M. S. Shumate, U.S. Patent4,067,653 (10Jan.1978).
  14. R. S. Eng, K. W. Nill, in Digest of Topical Meeting on Applications of Laser Spectroscopy, (Optical Society of America, Washington, D.C., 1975).
  15. J. R. Durig, S. F. Bash, E. E. Mercer, J. Chem. Phys. 44, 4238 (1966). [CrossRef] [PubMed]
  16. J. R. Durig, W. C. Harris, D. W. Wertz, J. Chem. Phys. 50, 1449 (1969). [CrossRef]
  17. J. R. Durig, W. C. Harris, J. Chem. Phys. 51, 4457 (1969). [CrossRef]
  18. R. Gerlach, N. M. Amer, Appl. Phys. Lett. 32, 228 (1978);L. J. Thomas, M. J. Kelly, N. M. Amer, Appl. Phys. Lett. 32, 736 (1978);D. R. Wake, N. M. Amer, Appl. Phys. Lett. 34, 379 (1979). [CrossRef]
  19. S. Shtrikman, M. Slatkine, Appl. Phys. Lett. 31, 830 (1977);E. Kritchman, S. Shtrikman, M. Slatkine, J. Opt. Soc. Am. 68, 1257 (1978). [CrossRef]
  20. C. K. N. Patel, R. J. Kerl, Appl. Phys. Lett. 30, 578 (1977). [CrossRef]
  21. C. F. Dewey, R. D. Kamm, C. E. Hackett, Appl. Phys. Lett. 23, 633 (1973);C. W. Bruce, B. Z. Sojka, B. G. Hurd, W. R. Watkins, K. O. White, Z. Derzko, Appl. Opt. 15, 2970 (1976). [CrossRef] [PubMed]
  22. M. S. Shumate, R. T. Menzies, J. S. Margolis, L.-G. Rosengren, Appl. Opt. 15, 2480 (1976). [CrossRef] [PubMed]
  23. The use of measurements that are carefully ratioed to the sharp water peaks should allow the absorption profiles of these species to be recognizable for absorption signals that are 10% of the water background. Improvements in this 10−7-cm−1 detection sensitivity assumed above may be possible using Stark modulation or frequency modulation spectroscopy to discriminate against water vapor continuum absorption.
  24. R. A. Crane, Appl. Opt. 17, 2097 (1978). [CrossRef] [PubMed]
  25. R. R. Patty, G. M. Russwurm, W. A. McClenny, D. R. Morgan, Appl. Opt. 13, 2850 (1974). [CrossRef] [PubMed]
  26. A. Mayer, J. Comera, H. Charpentier, C. Jaussaud, Appl. Opt. 17, 391 (1978). [CrossRef] [PubMed]
  27. U.S. Department Health of Education, and Welfare, Air Quality Criteria for Hydrocarbons, National Air Pollution Control Administration Publication AP-64 (U.S. GPO, Washington, D.C., 1970).
  28. Sadtler Standard Spectra, Gases and Vapors, Vol. 1 (Sadtler Research Laboratories, Philadelphia, 1972).
  29. H. B. Singh, L. J. Salas, L. A. Cavanagh, Air Pollut. Control Assoc. 27, 332 (1977);D. R. Cronn, R. A. Rasmussen, E. Robinson, D. A. Harsch, J. Geophys. Res. 82, 5935 (1977). [CrossRef]

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