An interferometric method of measuring small differences between weak optical absorptions of solutions has been developed using the thermooptic effect. To record the small changes in optical path length ∼λ/200 due to heating, it was necessary to stabilize the fringe pattern with respect to slow thermal drift using a galvanometer-driven compensator plate controlled by a closed feedback loop. Fringe shifts from background absorptions were nulled out to better than 1 part in 400, permitting the measurement of differences in absorptions between two solutions that were 1/100th of background. Using laser powers of 100 mW, absorptions ∼5 × 10−6 cm−1 (base e) could be measured with CCl4 solutions.
© 1982 Optical Society of America
Original Manuscript: September 21, 1981
Published: May 1, 1982
David A. Cremers and Richard A. Keller, "Thermooptic-based differential measurements of weak solute absorptions with an interferometer," Appl. Opt. 21, 1654-1662 (1982)