Absolute intensities and self-, N2-, and air-broadened Lorentz halfwidths for selected lines in the ν3 and of 12CH3D from measurements with atunable diode laser spectrometer
Applied Optics, Vol. 25, Issue 11, pp. 1848-1853 (1986)
http://dx.doi.org/10.1364/AO.25.001848
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Abstract
Absolute intensities were measured at room temperature for thirty-nine lines in the qQ, qP, and qR branches of the ν3 (A1) parallel-type band of 12CH3D between 1250 and 1340 cm-1 using a tunable diode laser spectrometer. Although the line intensities were determined to a precision ≈3%, the square of the vibrational transitiondipole moment matrix element derived from each mean line intensity varied by ≈20%, indicating intensity perturbations possibly caused by Coriolis interaction with the nearby ν6 fundamental. Room temperature air- and N2-broadened halfwidths have also been determined for seventeen of these lines and the measured halfwidth values varied from 0.023 cm-1 atm-1 for high J,K transitions to ∼0.067 cm-1 atm-1 for low J,K transitions. The average of the ratios of N2- to air-broadened halfwidths was 1.01, with a standard deviation of 0.01, indicating almost equal broadening efficiencies for N2 and air. Room temperature self-broadened halfwidths were also determined for three transitions with a mean value of 0.0803 ± 0.0010 cm-1 atm-1.
Citation
V. Malathy Devi, Curtis P. Rinsland, D. Chris Benner, Mary Ann H. Smith, and K. B. Thakur, "Absolute intensities and self-, N2-, and air-broadened Lorentz halfwidths for selected lines in the ν3 and of 12CH3D from measurements with atunable diode laser spectrometer," Appl. Opt. 25, 1848-1853 (1986)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-25-11-1848
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