Calibration lines of HCN in the 1.5-μm region

Hiroyuki Sasada; Kohji Yamada

doi:10.1364/AO.29.003535

Applied Optics
Vol. 29,
Issue 24,
pp. 3535-3547
(1990)
•https://doi.org/10.1364/AO.29.003535

Calibration lines of HCN in the 1.5-μm region

Hiroyuki Sasada and Kohji Yamada

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Hiroyuki Sasada and Kohji Yamada, "Calibration lines of HCN in the 1.5-μm region," Appl. Opt. 29, 3535-3547 (1990)

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Abstract

Near-IR distributed feedback semiconductor laser spectroscopy of HCN in natural abundance and in an H¹³CN-enriched sample has been performed from 6380 to 6410 cm⁻¹. Absolute accuracy of wavenumber measurement was 0.0005 cm⁻¹ using the 3–0 band of CO as a reference. New sets of molecular constants for the (2 0⁰ 0)–(0 0⁰ 0) and (2 1¹ 0)-(0 1¹ 0) bands of H¹²C¹⁴N and H¹³C¹⁴N have been determined by combining the present results together with the existing data. Two tables of the calculated wavenumbers are given for calibration standards in the 1.5-μm region.

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assignment			wavenumber
CO	3–0	R(7)	6377.40675
H^{1 3} CN	c	P(10)	6377.5990
H^{1 3} CN	a	P(30)	6380.2100
CO	3–0	R(8)	6380.30141
H^{1 3} CN	b	P(20) f	6380.6761
H^{1 3} CN	c	P(9)	6380.8244
H^{1 3} CN	b	P(20) e	6380.8796
H^{1 2} CN	b	P(28) f	6382.2901
H^{1 2} CN	b	P(28) e	6382.5525
CO	3–0	R(9)	6383.08973
H^{1 3} CN	c	P(8)	6384.0137
H^{1 3} CN	a	P(29)	6384.1903
H^{1 3} CN	b	P(19) f	6384.2802
H^{1 3} CN	b	P(19) e	6384.4782
H^{1 2} CN	d	P(17) f	6385.5389
H^{1 2} CN	d	P(17) e	6385.5861
CO	3–0	R(10)	6385.77158
H^{1 2} CN	c	P(17)	6386.1687
H^{1 2} CN	b	P(27) f	6386.3431
H^{1 2} CN	b	P(27) e	6386.6015
H^{1 2} CN	a	P(36)	6387.1525
H^{1 3} CN	c	P(7)	6387.1670
H^{1 3} CN	b	P(18) f	6387.8475
H^{1 3} CN	b	P(18) e	6388.0388
H^{1 3} CN	a	P(28)	6388.1347
CO	3–0	R(11)	6388.34681
H^{1 2} CN	d	P(16) f	6389.1562
H^{1 2} CN	d	P(16) e	6389.1944
H^{1 2} CN	c	P(16)	6389.7745
H^{1 2} CN	b	P(26) f	6390.3589
H^{1 2} CN	b	P(26) e	6390.6132
CO	3–0	R(12)	6390.81527
H^{1 3} CN	b	P(17) f	6391.3782
H^{1 2} CN	a	P(35)	6391.5365
H^{1 3} CN	b	P(17) e	6391.5624
H^{1 3} CN	a	P(27)	6392.0415
H^{1 2} CN	d	P(15) f	6392.7304
H^{1 2} CN	d	P(15) e	6392.7651
CO	3–0	R(13)	6393.17681
H^{1 2} CN	c	P(15)	6393.3392
H^{1 3} CN	c	P(5)	6393.3628
H^{1 2} CN	b	P(25) f	6394.3356
H^{1 2} CN	b	P(25) e	6394.5849
H^{1 3} CN	b	P(16) f	6394.8718
H^{1 3} CN	b	P(16) e	6395.0489
CO	3–0	R(14)	6395.43128
H^{1 2} CN	a	P(34)	6395.8815
H^{1 3} CN	a	P(26)	6395.9108
H^{1 2} CN	d	P(14) f	6396.2658
H^{1 2} CN	d	P(14) e	6396.2949
H^{1 3} CN	c	P(4)	6396.4035
H^{1 2} CN	c	P(14)	6396.8648
CO	3–0	R(15)	6397.57855
H^{1 2} CN	b	P(24) f	6398.2721
H^{1 3} CN	b	P(15) f	6398.3281
H^{1 3} CN	b	P(15) e	6398.4975
H^{1 2} CN	b	P(24) e	6398.5168
H^{1 3} CN	c	P(3)	6399.4101
CO	3–0	R(16)	6399.61847
H^{1 3} CN	a	P(25)	6399.7441
H^{1 2} CN	d	P(13) e	6399.7863
H^{1 2} CN	a	P(33)	6400.1880
H^{1 2} CN	c	P(13)	6400.3543
CO	3–0	R(17)	6401.55087
H^{1 3} CN	b	P(14) f	6401.7473
H^{1 3} CN	b	P(14) e	6401.9084
H^{1 2} CN	b	P(23) f	6402.1712
H^{1 3} CN	c	P(2)	6402.3770
H^{1 2} CN	b	P(23) e	6402.4101
CO	3–0	R(18)	6403.37564
H^{1 3} CN	a	P(24)	6403.5396
H^{1 2} CN	c	P(12)	6403.8018
H^{1 2} CN	a	P(32)	6404.4549
CO	3–0	R(19)	6405.09261
H^{1 3} CN	b	P(13) f	6405.1304
H^{1 3} CN	b	P(13) e	6405.2824
H^{1 2} CN	b	P(22) f	6406.0292
H^{1 2} CN	b	P(22) e	6406.2621
CO	3–0	R(20)	6406.70164
H^{1 2} CN	c	P(11)	6407.2097
H^{1 3} CN	a	P(23)	6407.2977
CO	3–0	R(21)	6408.20259
H^{1 3} CN	b	P(12) f	6408.4756
H^{1 3} CN	b	P(12) e	6408.6186
H^{1 2} CN	a	P(31)	6408.6821
CO	3–0	R(22)	6409.59530

Iso	Band	Reference	Precision (cm⁻¹)	Range of J	Number	rms (cm⁻¹)
H^{1 2} CN	2 0⁰ 0 – 0 0⁰ 0	present	0.0005	P(31)–P(36)	6	0.00031
	2 0⁰ 0 – 0 0⁰ 0	present, 1	0.0033	P(37)–R(29)	66	0.0036
	2 0⁰ 0 – 0 0⁰ 0	13	0.0010	P(27)–R(28)	54	0.00039
	2 0⁰ 0 – 0 0⁰ 0	14	0.0009	R(16)	1	0.00008
	0 0⁰ 0 – 0 0⁰ 0	17,18,26,27	3.3 × 10⁻⁸	R(0)–R(4)	5	3.7 × 10⁻⁷
	0 0⁰ 0 – 0 0⁰ 0	17,18,26,27	~5 0 × 10⁻⁶	R(0)–R(4)	5	3.7 × 10⁻⁷
	2 0⁰ 0 – 0 0⁰ 0	21, 26,27	1.0 × 10⁻⁶	R(0)–R(3)	4	6.6 × 10⁻⁶
	2 0⁰ 0 – 0 0⁰ 0	21, 26,27	~5.0 × 10⁻⁶	R(0)–R(3)	4	6.6 × 10⁻⁶
H^{1 3} CN	2 0⁰ 0 – 0 0⁰ 0	present	0.0005	P(23)–P(30)	8	0.00040
	2 0⁰ 0 – 0 0⁰ 0	present, 1	0.0033	P(29)–R(39)	69	0.0039
	2 0⁰ 0 – 0 0⁰ 0	13	0.0010	P(21)–R(20)	32	0.00125
	0 0⁰ 0 – 0 0⁰ 0	19,26,27	8.3 × 10⁻⁷	R(0)–R(5)	6	5.0 × 10⁻⁶
	0 0⁰ 0 – 0 0⁰ 0	19,26,27	~5.0 × 10⁻⁶	R(0)–R(5)	6	5.0 × 10⁻⁶
	2 0⁰ 0 – 0 0⁰ 0	26,27	5.0 × 10⁻⁶	R(0)–R(3)	3	4.7 × 10⁻⁶
H^{1 2} CN	2 1¹ 0 – 0 1¹ 0	present	0.0005	P(22)–P(28)	14	0.00050
	2 1¹ 0 – 0 1¹ 0	present, 1	0.0033	P(28)–R(33)	152	0.0037
	2 1¹ 0 – 0 1¹ 0	13	0. 0010	P(18)–R(22)	73	0.00096
	0 1¹ 0 – 0 1¹ 0	22,23,24	2.0 × 10⁻⁷	Q(1)–Q(20)	18	6.8 × 10⁻⁷
	0 1¹ 0 – 0 1¹ 0	22,23,24	~1.7× 10⁻⁶	Q(1)–Q(20)	18	6.8 × 10⁻⁷
	0 1¹ 0 – 0 1¹ 0	20, 21,27	1.0 × 10⁻⁶	R(1)–R(4)	8	2.9 × 10⁻⁶
	0 1¹ 0 – 0 1¹ 0	20, 21,27	~5.0 × 10⁻⁶	R(1)–R(4)	8	2.9 × 10⁻⁶
H^{1 3} CN	2 1¹ 0 – 0 1¹ 0	present	0.0005	P(12)–P(20)	18	0.00048
	2 1¹ 0 – 0 1¹ 0	present, 1	0.0033	P(20)–R(30)	126	0.0038
	0 1¹ 0 – 0 1¹ 0	25	3.0 × 10⁻⁷	Q(6)–Q(15)	10	2.4 × 10⁻⁷
	0 1¹ 0 – 0 1¹ 0	27	5.0 × 10⁻⁸	R(2)–R(5)	8	9.4 × 10⁻⁷

	H^{1 2} C^{1 4}N					H^{1 3} C^{1 4}N

χ² (d.f.)	96.7 (131)					162.4 (113)
ΔT	6519.61043(14)					6483.28267(18)
B′	1.45707522(14)					1.42045300(46)
D′	2.86217(246) × 10⁻⁶					2.70387(260) × 10⁻⁶
B″	1.478221832(16)					1.44000020(22)
D″	2.90969(216) × 10⁻⁶					2.75250(256) × 10⁻⁶

ΔT	100					100
B′	−8	100				−37	100
D′	19	34	100			−12	5	100
B″	11	20	67	100		7	2	41	100
D″	15	30	99	68	100	−14	−10	97	47	100
	ΔT	B′	D′	B″	D″	ΔT	B′	D′	B″	D″

	H^{1 2} C^{1 4}N								H^{1 3} C^{1 4}N

χ ²(d.f.)	293.8 (255)								192.0 (152)
ΔT	6480.78514(18)								6445.69509(40)
B′	1.4610460(12)								1.4239840(26)
D′	2.91617(293) × 10⁻⁶								2.78560(597) × 10⁻⁶
q₀′	7.6928(15) × 10⁻³								7.3802(17) × 10⁻³
q_j′	−9.773(235) × 10⁻⁸								−8.889(383) × 10⁻⁸
B″	1.48177870(13)								1.44316314(49)
D″	2.96680(254) × 10⁻⁶								2.83376(815) × 10⁻⁶
q₀″	7.4877317(90) × 10⁻³								7.1662164(60) × 10⁻³
q_j″	−8.86730(683) × 10⁻⁸								−8.12376(772) × 10⁻⁸
q_{j j}″	1.1790(1199) × 10^{−1 2}								1.4050(2315) × 10^{−1 2}

				ΔT	B′	D′	q₀′	q_j′	B″	D″	q₀″	q_j″	q_{j j}″
ΔT	100			100	−91	−3	0	0	31	34	0	0	0	ΔT
B′	−77	100			100	−9	0	0	−45	−53	0	0	0	B′
D′	−18	34	100			100	0	0	80	87	0	0	0	D′
q₀′	−1	2	7	100			100	−87	0	0	−1	1	−2	q₀′
q_j′	1	−3	−8	−96	100			100	0	0	3	−3	3	q_j′
B″	5	3	36	2	−2	100			100	91	0	0	0	B″
D″	14	−15	86	5	−6	42	100			100	0	0	0	D″
q₀″	0	0	0	−1	2	0	0	100			100	−96	91	q₀″
q_j″	0	0	0	1	−3	0	0	−95	100			100	−98	q_j″
q_{j j}″	0	0	0	−1	3	0	0	88	−98	100			100	q_{j j}″
	ΔT	B′	D′	q₀′	q_j′	B″	D″	q₀″	q_j″	q_{j j}″

	(0 1¹ 0)		(2 1¹ 0)
	obs.	obs.–cal.	obs.	obs.–cal.
H^{1 2} C^{1 4}N
R(1) e	5.9120477(10)	0.0000019
f	5.9419940(10)	0.0000001
R(2) e	8.8678909(20)	−0.0000025	8.7431498(50)	0.0002615
f	8.9128116(20)	0.0000014	8.7888746(50)	−0.0001598
R(3) e	11.8235239(30)	−0.0000066	11.6572187(50)	0.0003555
f	11.8834114(30)	0.0000017	11.7181614(50)	−0.0002190
R(4) e	14.7788860(50)	−0.0000011
f	14.8537167(50)	−0.0000034

H^{1 3} C^{1 4}N
R(2) e	8.6371785(50)	−0.0000000	8.5217938(50)	0.0003263
f	8.6801658(50)	−0.0000012	8.5652953(50)	−0.0004436
R(3) e	11.5159243(50)	−0.0000009	11.3620395(50)	0.0003898
f	11.5732328(50)	−0.0000014	11.4201066(50)	−0.0005617
R(4) e	14.3944031(50)	−0.0000007
f	14.4660249(50)	−0.0000004
R(5) e	17.2725485(50)	0.0000014
f	17.3584721(50)	0.0000005

	H^{1 2} C^{1 4}N		H^{1 3} C^{1 4}N
J	P–branch	R–branch	P–branch	R–branch
0		6522.5246(5)		6486.1236(5)
1	6516.6540(5)	6525.3964(5)	6480.4027(5)	6488.9253(5)
2	6513.6553(5)	6528.2257(5)	6477.4837(5)	6491.6878(5)
3	6510.6145(5)	6531.0126(5)	6474.5257(5)	6494.4110(5)
4	6507.5317(5)	6533.7568(5)	6471.5288(5)	6497.0949(5)
5	6504.4068(5)	6536.4585(5)	6468.4931(5)	6499.7394(5)
6	6501.2399(5)	6539.1175(5)	6465.4187(5)	6502.3444(5)
7	6498.0312(5)	6541.7337(5)	6462.3055(5)	6504.9099(5)
8	6494.7808(5)	6544.3071(5)	6459.1538(5)	6507.4358(5)
9	6491.4886(5)	6546.8377(5)	6455.9635(5)	6509.9221(5)
10	6488.1548(5)	6549.3253(5)	6452.7348(5)	6512.3686(5)
11	6484.7795(5)	6551.7699(5)	6449.4677(5)	6514.7755(5)
12	6481.3627(5)	6554.1715(5)	6446.1623(5)	6517.1425(5)
13	6477.9045(5)	6556.5300(5)	6442.8187(5)	6519.4697(5)
14	6474.4050(5)	6558.8454(5)	6439.4369(5)	6521.7570(5)
15	6470.8644(5)	6561.1175(5)	6436.0171(5)	6524.0043(5)
16	6467.2826(5)	6563.3464(5)	6432.5592(5)	6526.2117(5)
17	6463.6597(5)	6565.5320(5)	6429.0635(5)	6528.3790(5)
18	6459.9959(5)	6567.6742(5)	6425.5300(5)	6530.5062(5)
19	6456.2913(5)	6569.7730(5)	6421.9587(5)	6532.5934(5)
20	6452.5458(5)	6571.8284(5)	6418.3498(5)	6534.6403(5)
21	6448.7597(5)	6573.8402(5)	6414.7034(5)	6536.6470(5)
22	6444.9330(5)	6575.8086(5)	6411.0195(5)	6538.6135(5)
23	6441.0658(5)	6577.7333(5)	6407.2982(5)	6540.5397(5)
24	6437.1582(5)	6579.6144(5)	6403.5396(5)	6542.4255(5)
25	6433.2103(5)	6581.4519(5)	6399.7439(5)	6544.2710(5)
26	6429.2222(5)	6583.2456(5)	6395.9110(5)	6546.0761(5)
27	6425.1940(5)	6584.9956(6)	6392.0412(5)	6547.8407(6)
28	6421.1258(5)	6586.7019(6)	6388.1345(5)	6549.5649(6)
29	6417.0177(5)	6588.3642(6)	6384.1909(5)	6551.2486(6)
30	6412.8698(5)	6589.9828(7)	6380.2107(5)	6552.8917(7)
31	6408.6822(5)	6591.5574(7)	6376.1938(5)	6554.4943(7)
32	6404.4549(5)	6593.0881(8)	6372.1405(6)	6556.0563(8)
33	6400.1882(5)	6594.5749(8)	6368.0507(6)	6557.5776(8)
34	6395.8821(5)	6596.0177(9)	6363.9247(6)	6559.0584(9)
35	6391.5367(5)	6597.4164(10)	6359.7624(7)	6560.4984(10)
36	6387.1522(5)	6598.7711(11)	6355.5641(8)	6561.8978(11)
37	6382.7286(5)	6600.0817(12)	6351.3298(8)	6563.2564(12)
38	6378.2660(6)	6601.3483(13)	6347.0596(9)	6564.5743(13)
39	6373.7646(6)	6602.5706(14)	6342.7536(10)	6565.8514(14)
40	6369.2245(6)	6603.7489(15)	6338.4120(11)	6567.0878(15)

		H^{1 2} C^{1 4}N
J	P–branch	Q–branch	R–branch
1 e		6480.7589(5)	6486.5722(5)
f		6480.7285(5)	6486.6034(5)
2 e	6474.8314(5)	6480.7063(5)	6489.4030(5)
f	6474.8019(5)	6480.6152(5)	6489.4504(5)
3 e	6471.7922(5)	6480.6274(5)	6492.1920(5)
f	6471.7486(5)	6480.4453(5)	6492.2560(5)
4 e	6468.7116(5)	6480.5223(5)	6494.9390(5)
f	6468.6542(5)	6480.2187(5)	6495.0200(5)
5 e	6465.5896(5)	6480.3908(5)	6497.6441(5)
f	6465.5188(5)	6479.9356(5)	6497.7424(5)
6 e	6462.4262(5)	6480.2331(5)	6500.3070(5)
f	6462.3426(5)	6479.5958(5)	6500.4232(5)
7 e	6459.2217(5)	6480.0490(5)	6502.9279(5)
f	6459.1256(5)	6479.1995(5)	6503.0622(5)
8 e	6455.9760(5)	6479.8387(5)	6505.5065(5)
f	6455.8678(5)	6478.7466(5)	6505.6594(5)
9 e	6452.6892(5)	6479.6020(5)	6508.0429(5)
f	6452.5694(5)	6478.2372(5)	6508.2148(5)
10 e	6449.3614(5)	6479.3390(5)	6510.5371(5)
f	6449.2304(5)	6477.6714(5)	6510.7282(5)
11 e	6445.9927(5)	6479.0496(5)	6512.9888(5)
f	6445.8509(5)	6477.0490(5)	6513.1997(5)
12 e	6442.5832(5)	6478.7339(5)	6515.3982(5)
f	6442.4310(5)	6476.3703(5)	6515.6291(5)
13 e	6439.1330(5)	6478.3918(5)	6517.7651(5)
f	6438.9708(5)	6475.6351(5)	6518.0164(5)
14 e	6435.6421(5)	6478.0234(5)	6520.0895(5)
f	6435.4704(5)	6474.8437(5)	6520.3616(5)
15 e	6432.1106(5)	6477.6285(5)	6522.3713(5)
f	6431.9298(5)	6473.9959(5)	6522.6645(5)
16 e	6428.5387(5)	6477.2073(5)	6524.6105(5)
f	6428.3492(5)	6473.0919(5)	6524.9252(5)
17 e	6424.9263(5)	6476.7596(5)	6526.8071(5)
f	6424.7285(5)	6472.1318(5)	6527.1436(5)
18 e	6421.2737(5)	6476.2855(5)	6528.9609(5)
f	6421.0680(5)	6471.1155(5)	6529.3196(5)
19 e	6417.5809(5)	6475.7849(5)	6531.0720(5)
f	6417.3678(5)	6470.0432(5)	6531.4531(5)
20 e	6413.8479(5)	6475.2579(5)	6533.1403(5)
f	6413.6278(5)	6468.9148(5)	6533.5442(5)
21 e	6410.0750(5)	6474.7043(5)	6535.1658(5)
f	6409.8482(5)	6467.7306(5)	6535.5928(5)
22 e	6406.2621(5)	6474.1243(5)	6537.1484(5)
f	6406.0290(5)	6466.4905(5)	6537.5988(5)
23 e	6402.4094(5)	6473.5177(5)	6539.0881(5)
f	6402.1705(5)	6465.1946(5)	6539.5621(5)
24 e	6398.5170(5)	6472.8845(5)	6540.9848(5)
f	6398.2726(5)	6463.8430(5)	6541.4828(5)
25 e	6394.5850(5)	6472.2248(5)	6542.8385(6)
f	6394.3356(5)	6462.4359(5)	6543.3608(6)
26 e	6390.6134(5)	6471.5384(5)	6544.6493(6)
f	6390.3593(5)	6460.9731(5)	6545.1960(6)
27 e	6386.6025(5)	6470.8254(5)	6546.4169(7)
f	6386.3441(5)	6459.4550(5)	6546.9885(7)
28 e	6382.5522(5)	6470.0858(5)	6548.1415(7)
f	6382.2899(5)	6457.8815(5)	6548.7381(8)
29 e	6378.4628(6)	6469.3194(5)	6549.8230(8)
f	6378.1969(6)	6456.2527(5)	6550.4447(9)
30 e	6374.3343(6)	6468.5264(5)	6551.4613(9)
f	6374.0652(6)	6454.5688(5)	6552.1085(10)

		H^{1 3} C^{1 4}N
J	P–branch	Q–branch	R–branch

1 e		6445.6713(6)	6451.3376(6)
f		6445.6422(6)	6451.3676(6)
2 e	6439.8983(6)	6445.6237(6)	6454.1008(6)
f	6439.8701(6)	6445.5364(6)	6454.1464(6)
3 e	6436.9422(6)	6445.5522(6)	6456.8253(6)
f	6436.9005(6)	6445.3777(6)	6456.8869(6)
4 e	6433.9477(6)	6445.4570(6)	6459.5110(6)
f	6433.8930(6)	6445.1661(6)	6459.5890(5)
5 e	6430.9150(6)	6445.3379(5)	6462.1577(5)
f	6430.8476(6)	6444.9016(5)	6462.2526(5)
6 e	6427.8440(6)	6445.1950(5)	6464.7655(5)
f	6427.7645(6)	6444.5843(5)	6464.8777(5)
7 e	6424.7349(5)	6445.0282(5)	6467.3343(5)
f	6424.6436(5)	6444.2142(5)	6467.4642(5)
8 e	6421.5877(5)	6444.8377(5)	6469.8641(5)
f	6421.4851(5)	6443.7912(5)	6470.0120(5)
9 e	6418.4025(5)	6444.6233(5)	6472.3547(5)
f	6418.2891(5)	6443.3155(5)	6472.5211(5)
10 e	6415.1793(5)	6444.3850(5)	6474.8061(5)
f	6415.0555(5)	6442.7869(5)	6474.9915(5)
11 e	6411.9184(5)	6444.1229(5)	6477.2183(5)
f	6411.7846(5)	6442.2057(5)	6477.4230(5)
12 e	6408.6196(5)	6443.8369(5)	6479.5913(5)
f	6408.4763(5)	6441.5718(5)	6479.8156(5)
13 e	6405.2832(5)	6443.5270(5)	6481.9249(5)
f	6405.1308(5)	6440.8852(5)	6482.1692(5)
14 e	6401.9092(5)	6443.1932(5)	6484.2191(5)
f	6401.7481(5)	6440.1460(5)	6484.4839(5)
15 e	6398.4976(5)	6442.8355(5)	6486.4739(5)
f	6398.3283(5)	6439.3542(5)	6486.7595(5)
16 e	6395.0486(5)	6442.4540(5)	6488.6893(6)
f	6394.8715(5)	6438.5099(5)	6488.9960(6)
17 e	6391.5623(5)	6442.0484(5)	6490.8651(6)
f	6391.3778(5)	6437.6131(5)	6491.1934(6)
18 e	6388.0387(5)	6441.6190(5)	6493.0013(6)
f	6387.8473(5)	6436.6639(5)	6493.3515(6)
19 e	6384.4780(5)	6441.1655(5)	6495.0980(6)
f	6384.2801(5)	6435.6624(5)	6495.4704(6)
20 e	6380.8801(5)	6440.6881(5)	6497.1549(6)
f	6380.6762(5)	6434.6086(5)	6497.5500(6)
21 e	6377.2453(5)	6440.1867(5)	6499.1723(7)
f	6377.0357(5)	6433.5025(5)	6499.5903(7)
22 e	6373.5735(6)	6439.6613(6)	6501.1498(7)
f	6373.3587(6)	6432.3442(6)	6501.5911(7)
23 e	6369.8650(6)	6439.1119(6)	6503.0877(7)
f	6369.6454(6)	6431.1339(6)	6503.5525(7)
24 e	6366.1198(7)	6438.5384(7)	6504.9857(8)
f	6365.8957(7)	6429.8715(7)	6505.4744(8)
25 e	6362.3379(9)	6437.9408(8)	6506.8438(9)
f	6362.1099(9)	6428.5572(8)	6507.3568(9)
26 e	6358.5195(10)	6437.3192(9)	6508.6622(10)
f	6358.2880(10)	6427.1910(9)	6509.1996(10)
27 e	6354.6648(12)	6436.6734(10)	6510.4406(11)
f	6354.4300(12)	6425.7730(10)	6511.0028(11)
28 e	6350.7737(14)	6436.0035(13)	6512.1791(13)
f	6350.5361(14)	6424.3033(13)	6512.7664(13)
29 e	6346.8464(17)	6435.3095(15)	6513.8776(15)
f	6346.6064(17)	6422.7819(15)	6514.4902(15)
30 e	6342.8830(21)	6434.5912(18)	6515.5361(18)
f	6342.6410(21)	6421.2091(18)	6516.1743(18)

	H^{1 2} C^{1 5}N	H^{1 3} C^{1 5}N

χ² (d.f.)	37.9 (51)	58.0 (47)
ΔT	6516.51112(60)	6480.58641(60)
B′	1.41494255(59)	1.37770492(74)
D′	2.6967(115) × 10⁻⁶	2.5770(107) × 10⁻⁶
B″	1.43524782(29)	1.39643101(30)
D″	2.7408(101) × 10⁻⁶	2.6215(100) × 10⁻⁶

χ² (d.f.) 129.7 (120)
T_∑′–T_∑″	6442.09996(88)	T_Δ′–T_Δ″	6441.53840(75)
B_∑′	1.4655043(69)	B_Δ′	1.4647501(51)
D∑′	2.9800(119) × 10⁻⁶	D_Δ′	3.0401(115) × 10⁻⁶
		q₀′	7.738(16) × 10⁻³
		T_Δ″–T_∑″	15.142(61)
B_∑″	1.48582847(24)	B_Δ″	1.48502185(42)
D_∑″	3.06391(969) × 10⁻⁶	D_Δ″	3.0343(115) × 10⁻⁶
		q₀″	7.592(15) × 10⁻³
		q_j″	−9.3184(190) × 10⁻⁸

Abstract

Cited By

Figures (2)

Tables (9)

Equations (8)

Applied Optics