In an initial investigation of the potential utility of chemical ionization (CI) mass spectrometry of selected of chemical warfare agents using metal ions, the reactions of manganese ions with chloroalkyl sulfides analogs organophosphonates have been followed in a Fourier transform mass spectrometer. Mn+ ions, produced and by UV laser radiation focused on a stainless steel target, react rapidly with each molecule studied to provide mass spectra. The manganese ion CI mass spectra are compared to mass spectra obtained via characteristic electron impact (EI) and methane CI.
© 1990 Optical Society of America
Original Manuscript: March 27, 1990
Published: November 20, 1990
Chih-Cong Chou and S. Randolph Long, "Chemical ionization Fourier transform mass spectrometry of chemical warfare agent simulants using laser-produced metal ions," Appl. Opt. 29, 4981-4986 (1990)