OSA's Digital Library

Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 29, Iss. 33 — Nov. 20, 1990
  • pp: 4981–4986

Chemical ionization Fourier transform mass spectrometry of chemical warfare agent simulants using laser-produced metal ions

Chih-Cong Chou and S. Randolph Long  »View Author Affiliations


Applied Optics, Vol. 29, Issue 33, pp. 4981-4986 (1990)
http://dx.doi.org/10.1364/AO.29.004981


View Full Text Article

Enhanced HTML    Acrobat PDF (704 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations

Abstract

In an initial investigation of the potential utility of chemical ionization (CI) mass spectrometry of selected of chemical warfare agents using metal ions, the reactions of manganese ions with chloroalkyl sulfides analogs organophosphonates have been followed in a Fourier transform mass spectrometer. Mn+ ions, produced and by UV laser radiation focused on a stainless steel target, react rapidly with each molecule studied to provide mass spectra. The manganese ion CI mass spectra are compared to mass spectra obtained via characteristic electron impact (EI) and methane CI.

© 1990 Optical Society of America

History
Original Manuscript: March 27, 1990
Published: November 20, 1990

Citation
Chih-Cong Chou and S. Randolph Long, "Chemical ionization Fourier transform mass spectrometry of chemical warfare agent simulants using laser-produced metal ions," Appl. Opt. 29, 4981-4986 (1990)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-29-33-4981


Sort:  Author  |  Year  |  Journal  |  Reset  

References

  1. A. G. Harrison, Chemical Ionization Mass Spectrometry (CRC Press, Boca Raton, FL, 1983).
  2. A. Harrison, Chemical Ionization (Wiley-Interscience, New York, 1984).
  3. R. C. Burnier, G. D. Byrd, B. S. Freiser, “Gas Phase Reactions of Fe+ with Ketones and Ethers,” J. Am. Chem. Soc. 103, 4360 (1981). [CrossRef]
  4. J. S. Uppal, R. H. Staley, “Relative Binding Energies of Organic Molecules to Mn+ in the Gas Phase,” J. Am. Chem. Soc. 104, 1238 (1982); “Relative Binding Energies of Organic Molecules to Al+ in the Gas Phase,” J. Am. Chem. Soc. 104, 1235 (1982). [CrossRef]
  5. G. D. Byrd, R. C. Burnier, B. S. Freiser, “Gas-Phase Ion-Molecule Reactions of Fe+ and Ti+ with Alkanes,” J. Am. Chem. Soc. 104, 3565 (1982). [CrossRef]
  6. G. D. Byrd, B. S. Freiser, “Gas-Phase Reactions of Rh+ with Alkanes,” J. Am. Chem. Soc. 104, 5944 (1982). [CrossRef]
  7. L. F. Halle, R. Houriet, M. M. Kappes, R. H. Staley, J. L. Beauchamp, “Nickel Ions Effect a Highly Specific 1,4-Dehydrogenation of Hydrocarbons in the Gas Phase: Metallocycles Are Not Involved,” J. Am. Chem. Soc. 104, 6293 (1982). [CrossRef]
  8. M. A. Tolbert, J. L. Beauchamp, “Activation of Carbon–Hydrogen and Carbon–Carbon Bonds by Transition Metal Ions in the Gas Phase. Exhibition of Unique Reactivity by Scandium Ions,” J. Am. Chem. Soc. 106, 8117 (1984). [CrossRef]
  9. D. A. Weil, C. L. Wilkins, “A Comparison of the Ion-Molecule Reactions of Group 11 Metal Ions with Alcohols,” J. Am. Chem. Soc. 107, 7316 (1985). [CrossRef]
  10. L. Operti, E. C. Tews, B. S. Freiser, “Determination of Gas-Phase Ligand Binding Energies to Mg+ by FTMS Techniques,” J. Am. Chem. Soc. 110, 3847 (1988). [CrossRef]
  11. R. C. Burnier, G. D. Byrd, B. S. Freiser, “Copper(I) Chemical Ionization-Mass Spectrometric Analysis of Esters and Ketones,” Anal. Chem. 52, 1641 (1980). [CrossRef]
  12. D. A. Peaks, M. L. Gross, “Iron(I) Chemical Ionization and Tandem Mass Spectrometry for Locating Double Bonds,” Anal. Chem. 57, 115 (1985). [CrossRef]
  13. R. A. Forbes, E. C. Tews, B. S. Freiser, M. B. Wise, S. P. Perone, “Application of Pattern Recognition to Metal Ion Chemical Ionization Mass Spectra,” Anal. Chem. 58, 684 (1986). [CrossRef]
  14. R. A. Forbes, E. C. Tews, Y. Huang, B. S. Freiser, S. P. Perone, “Evaluation of Laser Desorbed Transition-Metal Ions as Analytical Chemical Ionization Reagents by Pattern Recognition,” Anal. Chem. 59, 1937 (1987). [CrossRef]
  15. R. B. Cody, R. C. Burnier, W. D. Reents, T. J. Carlin, D. A. McCrery, R. K. Lengel, B. S. Freiser, “Laser Ionization Source for Ion Cyclotron Resonance Spectroscopy. Application to Atomic Metal Ion Chemistry,” Int. J. Mass Spectrom. Ion Phys. 33, 37 (1980). [CrossRef]
  16. Y. Huang, B. S. Freiser, “Gas-Phase Study of Fe+-Benzyne with Alkanes,” J. Am. Chem. Soc. 111, 2387 (1989). [CrossRef]
  17. C. C. Chou, Int. J. Mass Spectrom. Ion Phys.

Cited By

Alert me when this paper is cited

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.


« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited