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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 35, Iss. 21 — Jul. 20, 1996
  • pp: 4086–4095

Rational design of fiber-optic probes for visible and pulsed-ultraviolet resonance Raman spectroscopy

L. Shane Greek, H. Georg Schulze, Charles A. Haynes, Michael W. Blades, and Robin F. B. Turner  »View Author Affiliations


Applied Optics, Vol. 35, Issue 21, pp. 4086-4095 (1996)
http://dx.doi.org/10.1364/AO.35.004086


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Abstract

We investigated the performance of fiber-optic resonance Raman probes with a series of experiments to determine the working curves of such probes using model analytes and to investigate the effects of absorbing media. A computer model designed to simulate these experiments is presented, and numerical results are found to be in agreement with the experimental data. Design considerations resulting from these studies are discussed, and novel designs for overcoming problems of coupling efficiency, damage threshold, and sensitivity in absorbing samples are presented. These findings are applied to the design of fiber-optic probes for ultraviolet resonance Raman spectroscopy involving nanosecond pulsed-ultraviolet excitation (225 and 266 nm). These probes have been used to collect what is, to our knowledge, the first reported fiber-optic-linked ultraviolet resonance Raman spectra of tryptophan and DNA.

© 1996 Optical Society of America

History
Original Manuscript: October 13, 1995
Revised Manuscript: March 14, 1996
Published: July 20, 1996

Citation
L. Shane Greek, H. Georg Schulze, Charles A. Haynes, Michael W. Blades, and Robin F. B. Turner, "Rational design of fiber-optic probes for visible and pulsed-ultraviolet resonance Raman spectroscopy," Appl. Opt. 35, 4086-4095 (1996)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-35-21-4086


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