Rotational Line Strengths and Self-Pressure-Broadening Coefficients for the 1.27-µm, a1Δg–X3Σg-, v = 0–0 Band of O2
Applied Optics, Vol. 37, Issue 12, pp. 2264-2270 (1998)
http://dx.doi.org/10.1364/AO.37.002264
Acrobat PDF (222 KB)
Abstract
We measured at 296 K the rotational line strengths and pressure-broadening coefficients for the 1.27-μm, a1Δg–X3Σg−, v = 0–0 band of O2 with a Fourier transform infrared spectrometer using an optical path length of 84 m, a spectral resolution of 0.01 cm−1, and sample pressures between 13 and 104 kPa. The integrated band strength is 7.79(17) × 10−6 m−2 Pa−1 [7.89(17) × 10−5 cm−2 atm−1], and the Einstein Acoefficient for spontaneous emission is 2.237(51) × 10−4 s−1, which corresponds to an upper-state1/e lifetime of 1.24(3) h. The pressure-broadening coefficients decrease with increasing N and range from 19 to 38 MHz/kPa (FWHM). The mean value for the transitions studied is 30.3(21) MHz/kPa [0.1024(71) cm−1/atm] (FWHM). The Einstein A coefficient determined here is in good agreement with the widely accepted value of 2.58 × 10−4 s−1 initially obtained by Badgeret al. [J. Chem. Phys. 43, 4345 (1965)] more than 30 years ago. The standard uncertainties given above are one standard deviation.
© 1998 Optical Society of America
[Optical Society of America ]
OCIS Codes
(010.0010) Atmospheric and oceanic optics : Atmospheric and oceanic optics
(010.1320) Atmospheric and oceanic optics : Atmospheric transmittance
(010.4950) Atmospheric and oceanic optics : Ozone
(020.3690) Atomic and molecular physics : Line shapes and shifts
(300.1030) Spectroscopy : Absorption
(300.6300) Spectroscopy : Spectroscopy, Fourier transforms
Citation
Walter J. Lafferty, Alexander M. Solodov, Catherine L. Lugez, and Gerald T. Fraser, "Rotational Line Strengths and Self-Pressure-Broadening Coefficients for the 1.27-µm, a1Δg–X3Σg-, v = 0–0 Band of O2," Appl. Opt. 37, 2264-2270 (1998)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-37-12-2264
You do not have subscription access to this journal. Citation lists with outbound citation links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Log in to access OSA Member Subscription
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Log in to access OSA Member Subscription
You do not have subscription access to this journal. Article level metrics are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Log in to access OSA Member Subscription
Related Journal Articles 
- Doppler-free spectroscopy and collisional studies with tunable diode lasers of lithium isotopes in a heat-pipe oven (JOSAB)
- Collisional-dephasing and Doppler-broadening effects on quantum interference in a Vee atomic system (JOSAB)
- Estimation of the Amount of Tropospheric Ozone in a Cloudy Sky by Ground-Based Fourier-Transform Infrared Emission Spectroscopy (AO)
- A moderate-spectral-resolution transmittance model based on fitting the line-by-line calculation (OE)
- Update of line parameters of ozone in the 2550-2900 cm−1 region (AO)
Related Conference Papers
- Application of cavity ring-down spectroscopy to sputter erosion measurements
- Advances in the Performance Assessment of a Tunable Diode Laser Absorption Spectrometer for Airborne Measurements of CH2O
- Direct measurement of resonant frequencies for H2O in the range of 0.2-4.2 THz by frequency-tuning monochromatic THz source
- Airborne Lidar Applications to Global Investigations of Ozone, Water Vapor, Aerosols and Clouds
- Spectroscopic Archives and Transmission Codes for the Atmosphere and Their Application to Laser Sensing
« Previous Article | Next Article »
OSA is a member of 