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Applied Optics

Applied Optics


  • Vol. 37, Iss. 24 — Aug. 20, 1998
  • pp: 5640–5646

Bubble Chamber as a Trace Chemical Detector

Xin Luo, Edward Iain McCreary, Jerry H. Atencio, Andy W. McCown, and Robert K. Sander  »View Author Affiliations

Applied Optics, Vol. 37, Issue 24, pp. 5640-5646 (1998)

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A novel concept for trace chemical analysis in liquids has been demonstrated. The technique utilizes light absorption in a superheated liquid. Although a superheated liquid is thermodynamically unstable, a high degree of superheating can be dynamically achieved for a short period of time. During this time the superheated liquid is extremely sensitive to boiling at nucleation sites produced by energy deposition. Observation of bubbles in the superheated liquid in some sense provides amplification of the initial energy deposition. Bubble chambers containing superheated liquids have been used to detect energetic particles; now a bubble chamber is used to detect a trace chemical in superheated liquid propane by observing bubble formation initiated by optical absorption. Crystal violet is used as a test case and can be detected at the subpart-per-1012 level by using a Nd:YAG laser. The mechanism for bubble formation and ideas for further improvement are discussed.

© 1998 Optical Society of America

OCIS Codes
(120.0120) Instrumentation, measurement, and metrology : Instrumentation, measurement, and metrology
(120.1880) Instrumentation, measurement, and metrology : Detection
(120.3940) Instrumentation, measurement, and metrology : Metrology
(120.6810) Instrumentation, measurement, and metrology : Thermal effects
(170.1580) Medical optics and biotechnology : Chemometrics

Xin Luo, Edward Iain McCreary, Jerry H. Atencio, Andy W. McCown, and Robert K. Sander, "Bubble Chamber as a Trace Chemical Detector," Appl. Opt. 37, 5640-5646 (1998)

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  1. G. G. Harigel, D. C. Colley, and D. C. Cundy, eds., Bubbles 40: Proceedings of the Conference on the Bubble Chamber and Its Contributions to Particle Physics (North-Holland, Amsterdam, 1994) [also published as Nucl. Phys. B Proc. Suppl. 36, (1994)].
  2. R. P. Shutt, ed., Bubble and Spark Chambers (Academic, New York, 1967), Vol. 1.
  3. R. C. Reid, “Superheated liquids,” Am. Sci. 64, 146–156 (1976).
  4. F. Seitz, “On the theory of the bubble chamber,” Phys. Fluids 1, 2–13 (1958).
  5. J. Harper and J. C. Rich, “Radiation-induced nucleation in superheated liquid droplet neutron detectors,” Nucl. Instrum. Methods Phys. Res. A 336, 220–225 (1993).
  6. N. E. Shafer and R. N. Zare, “Through a beer glass darkly,” Phys. Today 44, 48–52 (October 1991).
  7. A. C. Tam, “Applications of photoacoustic sensing techniques,” Rev. Mod. Phys. 58, 381–431 (1986).
  8. S. E. Bialkowski, Photothermal Spectroscopy Methods for Chemical Analysis (Wiley, New York, 1996), Chap. 7.
  9. R. A. Leach and J. M. Harris, “Supercritical fluids as spectroscopic solvents for thermooptical absorption measurements,” Anal. Chem. 56, 1481–1487 (1984).
  10. R. A. Leach and J. M. Harris, “Thermal lens absorption measurements by flow injection into supercritical fluid solvents,” Anal. Chem. 56, 2801–2805 (1984).
  11. G. J. Diebold and J. S. Hayden, “Opto-acoustic detection of chain reactions,” Chem. Phys. 49, 429–437 (1980).
  12. D. Magde and M. W. Windsor, “Picosecond internal conversion in crystal violet,” Chem. Phys. Lett. 24, 144–148 (1974).
  13. D. A. Cremers and M. W. Windsor, “A study of the viscosity-dependent electronic relaxation of some triphenylmethane dyes using picosecond flash photolysis,” Chem. Phys. Lett. 71, 27–32 (1980).
  14. F. J. Green, The Sigma-Aldrich Handbook of Stains, Dyes and Indicators (Aldrich Chemical Co., Milwaukee, Wis., 1990).
  15. I. Carmichael and G. L. Hug, “Triplet–triplet absorption spectra of organic molecules in condensed phases,” J. Phys. Chem. Ref. Data 15, 1–250 (1986).
  16. L. Manring and K. Peters, “Photodissociation of triarylmethanes,” in Ultrafast Phenomena IV, D. H. Auston and K. B. Eisenthal, ed. (Springer-Verlag, New York, 1984) pp. 304–307.
  17. R. C. Stamberg and D. E. Gillespie, “Laser-stimulated nucleation in a bubble chamber,” J. Appl. Phys. 37, 459–461 (1966).
  18. G. Harigel, H. J. Hilke, G. Linser, and F. Schenk, “On the formation of narrow bubble tracks by a laser beam in argon, nitrogen, and hydrogen bubble chambers,” Nucl. Instrum. Methods 188, 517–520 (1981).
  19. D. A. Glaser and D. C. Rahm, “Characteristics of bubble chambers,” Phys. Rev. 97, 474–479 (1955).
  20. C. T. Avedisian, “The homogeneous nucleation limits of liquids,” J. Phys. Chem. Ref. Data 14, 695–729 (1985).
  21. Ya. M. Kimelfeld, “Infrared spectroscopy of solutions in liquified simple gases,” in Vibrational Spectra and Structure J. R. Durig, ed. (Elsevier, New York, 1991), Vol. 19, pp. 315–367.

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