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Applied Optics

Applied Optics


  • Vol. 37, Iss. 27 — Sep. 20, 1998
  • pp: 6449–6455

Dye photodestruction in a solid-state dye laser with a polymeric gain medium

Sergei Popov  »View Author Affiliations

Applied Optics, Vol. 37, Issue 27, pp. 6449-6455 (1998)

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The process of dye photodestruction in a solid-state dye laser is studied, and implemented is a polymeric gain medium doped with a strongly concentrated dye. The behavior of the conversion efficiency in the polymeric gain medium pumped with different laser-pulse repetition rates and the process of dye photobleaching are analyzed. The contribution of the heating of the host material into the dye molecules’ deactivation is discussed. The negative effect of high dye concentration on the dye stability under a high pump repetition rate is reported and analyzed for the first time to my knowledge. A comparison of the present results with recently published data demonstrates the major role of photodestruction, rather than direct thermodestruction, in the dye stability of the solid-state gain medium. The role of additives with low molecular weights in the polymeric matrix, for increasing the stability of the gain material, is discussed.

© 1998 Optical Society of America

OCIS Codes
(140.2050) Lasers and laser optics : Dye lasers
(140.3600) Lasers and laser optics : Lasers, tunable
(160.3380) Materials : Laser materials
(160.4760) Materials : Optical properties
(160.4890) Materials : Organic materials
(260.5130) Physical optics : Photochemistry

Original Manuscript: February 20, 1998
Revised Manuscript: May 5, 1998
Published: September 20, 1998

Sergei Popov, "Dye photodestruction in a solid-state dye laser with a polymeric gain medium," Appl. Opt. 37, 6449-6455 (1998)

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  1. B. H. Soffer, B. B. McFarland, “Continuously tunable, narrow-band organic dye laser,” Appl. Phys. Lett. 10, 266–267 (1967). [CrossRef]
  2. O. G. Peterson, B. B. Snavely, “Stimulated emission from flashlamp-excited organic dyes in polymethyl methacrylate,” Appl. Phys. Lett. 12, 238–240 (1968). [CrossRef]
  3. F. J. Duarte, J. J. Ehrlich, W. E. Davenport, T. S. Taylor, J. C. McDonald, “A new tunable dye laser oscillator: preliminary report,” in Proceedings of the International Conference on Lasers ’92, C. P. Wang, ed. (STS, McLean, Va., 1993), pp. 293–296.
  4. F. J. Duarte, A. Costela, I. Garsia-Moreno, R. Sastre, J. J. Erlich, T. S. Tailor, “Dispersive solid-state dye laser oscillators,” Opt. Quantum Electron. 29, 461–472 (1997). [CrossRef]
  5. F. J. Duarte, “Solid-state dispersive dye laser oscillator: very compact cavity,” Opt. Commun. 117, 480–484 (1995). [CrossRef]
  6. F. J. Duarte, “Solid-state multiple-prism grating dye-laser oscillators,” Appl. Opt. 33, 3857–3860 (1994). [CrossRef] [PubMed]
  7. Although it is customary in the literature to use the term photodestruction, it would be more suitable to use photodegradation or photobleaching (i.e., losing excitation-radiation properties) instead. Indeed, no direct physical destruction of dye molecule bonds takes place under photoexcitation in the lasing medium, but reconfiguration of the conjugated electronic shells responsible for radiation does occur. This reconfiguration leads to an aggregation of dye molecules into higher oligomers or to chemical reactions that destroy the dye molecules. However, we follow the tradition and use the term photodestruction.
  8. R. E. Hermes, T. H. Allik, S. Chandra, J. A. Hutchinson, “High-efficiency pyrromethene doped solid-state dye lasers,” Appl. Phys. Lett. 63, 877–879 (1993). [CrossRef]
  9. A. Costela, I. Garsia-Moreno, J. M. Figuera, F. Amat-Guerri, J. Barroso, R. Sastre, “Solid-state dye laser based on Coumarin 540A-doped polymeric matrices,” Opt. Commun. 130, 44–50 (1996). [CrossRef]
  10. A. Costela, F. Florido, I. Garsia-Moreno, R. Duchowicz, F. Amat-Guerri, J. M. Figuera, R. Sastre, “Solid-state dye lasers based on copolymers of 2-hydroxyethyl methacrylate and methyl methacrylate doped with rhodamine 6G,” Appl. Phys. B 60 (60), 383–389 (1995).
  11. R. Sastre, A. Costela, “Polymeric solid-state dye lasers,” Adv. Mater. 7(2), 198–202 (1995). [CrossRef]
  12. T. G. Pavlopoulos, J. H. Boyer, M. Shah, K. Thangaraj, M.-L. Soong, “Laser action from 2,6,8-position trisubstituted 1,3,5,7-tetramethylpyrromethene-BF2 complexes: part 1,” Appl. Opt. 29, 3885–3886 (1990). [CrossRef] [PubMed]
  13. F. J. Duarte, “Opportunity beckons for solid-state dye lasers,” Laser Focus World 31(5), 187–189 (1995).
  14. F. J. Duarte, “Solid-state dye laser oscillators,” in Proceedings of the International Conference on Lasers ’93, V. J. Corcoran, T. A. Goldman, eds. (STS, McLean, Va., 1994), pp. 400–404.
  15. F. J. Duarte, “Multiple-prism near-grazing-incidence grating solid-state dye-laser oscillator,” Opt. Laser Technol. 29, 513–516 (1997). [CrossRef]
  16. K. H. Drexhage, “Structure and properties of laser dye,” in Dye Lasers, F. P. Schäfer, ed. (Springer-Verlag, Berlin, 1990), pp. 155–201.
  17. G. Jones, “Photochemistry of laser dyes,” in Dye Laser Principles, F. J. Duarte, L. W. Hillman, eds. (Academic, New York, 1990), pp. 287–345. [CrossRef]
  18. A. Maslyukov, S. Sokolov, M. Kaivola, K. Nyholm, S. Popov, “Solid-state dye laser with modified poly(methyl methacrylate)-doped active elements,” Appl. Opt. 34, 1516–1518 (1995). [CrossRef] [PubMed]
  19. R. M. O’Connell, T. T. Saito, “Plastics for high-power laser applications: a review,” Opt. Eng. 22, 393–399 (1983).
  20. D. W. Van Krevelen, Properties of Polymers (Elsevier, New York, 1990), pp. 525–540.
  21. M. Rodriguez, A. Costela, I. Garcia-Moreno, F. Florido, J. M. Figuera, R. Sastre, “A simple rotating system to avoid early degradation of solid-state dye lasers,” Meas. Sci. Technol. 6, 971–978 (1995). [CrossRef]
  22. A. Costela, I. Garsia-Moreno, J. M. Figuera, R. Mallavia, M. D. Santa-Maria, R. Sastre, “Solid-state dye lasers based on modified rhodamine 6G dyes copolymerized with methacrylic monomers,” J. Appl. Phys. 80(6), 3167–3173 (1996). [CrossRef]
  23. G. Jones, J. Morais, M. L. Trudell, T. H. Chen, J. H. Boyer, “Fluorescence properties of laser dyes in polymeric media,” in Proceedings of the International Conference on Lasers ’95, V. J. Corcoran, T. A. Goldman, eds. (STS, McLean, Va., 1996), pp. 375–382.
  24. V. S. Nechitailo, “About the polymer free volume theory,” Int. J. Polym. Mater. 16, 171–177 (1992). [CrossRef]
  25. E. T. Knobbe, B. Dunn, P. D. Fuqua, F. Nishida, “Laser behavior and photostability characteristics of organic dye doped silicate gel materials,” Appl. Opt. 29, 2729–2733 (1990). [CrossRef] [PubMed]

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