Theoretical results for the far-wing line shapes and corresponding absorption coefficients in the high-frequency wing of the ν3 fundamental band of self-broadened CO2 are presented for a number of temperatures between 218 and 751 K. These first-principles calculations are made assuming binary collisions within the framework of a quasi-static theory with a more accurate interaction potential than in previous calculations. The theoretical results are compared with existing laboratory data and are in good agreement for all the temperatures considered.
© 1999 Optical Society of America
[Optical Society of America ]
Qiancheng Ma, Richard H. Tipping, Christian Boulet, and Jean-Pierre Bouanich, "Theoretical Far-Wing Line Shape and Absorption for High-Temperature CO2," Appl. Opt. 38, 599-604 (1999)