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Applied Optics

Applied Optics


  • Vol. 38, Iss. 30 — Oct. 20, 1999
  • pp: 6337–6342

Singlet oxygen and dye-triplet-state quenching in solid-state dye lasers consisting of Pyrromethene 567–doped poly(methyl methacrylate)

Mohammad Ahmad, Mark D. Rahn, and Terence A. King  »View Author Affiliations

Applied Optics, Vol. 38, Issue 30, pp. 6337-6342 (1999)

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Solid-state dye lasers based on poly(methyl methacrylate) (PMMA) doped with Pyrromethene 567 dye (P567) have been investigated. The preparation techniques employed provided high photostability and laser damage threshold for P567 in pure PMMA with 270,000 pulses emitted before the conversion efficiency fell to half its initial value for a pump fluence of 0.16 J cm-2. When PMMA was modified with 1,4-diazobicyclo [2,2,2] octane singlet oxygen quencher, the longevity increased to 550,000 pulses, corresponding to a normalized photostability of 270 GJ mol-1. Modification of PMMA with a triplet quencher (perylene) yielded no improvement, but in ethanol solutions both additives enhanced photostability. It is possible that in PMMA, stabilization by means of triplet quenching that depends on dye diffusion is prevented but that stabilization by means of singlet oxygen quenching that depends on the faster oxygen diffusion rate will succeed.

© 1999 Optical Society of America

OCIS Codes
(140.2050) Lasers and laser optics : Dye lasers
(140.3380) Lasers and laser optics : Laser materials
(140.3460) Lasers and laser optics : Lasers
(140.3580) Lasers and laser optics : Lasers, solid-state

Original Manuscript: May 4, 1999
Revised Manuscript: July 14, 1999
Published: October 20, 1999

Mohammad Ahmad, Mark D. Rahn, and Terence A. King, "Singlet oxygen and dye-triplet-state quenching in solid-state dye lasers consisting of Pyrromethene 567–doped poly(methyl methacrylate)," Appl. Opt. 38, 6337-6342 (1999)

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  1. M. D. Rahn, T. A. King, “Comparison of solid-state dye laser performance in various host media,” in Solid State Lasers VIII, R. Scheps, ed., Proc. SPIE3613, 94–105 (1999). [CrossRef]
  2. H. Schmidt, “Organic modification of glass structure, new glass or new polymer?” J. Non-Cryst. Solids 112, 419–423 (1989). [CrossRef]
  3. G. Gall, X. Li, T. A. King, “Optical characterisation of sol-gel optical composites,” J. Sol-Gel Sci. Technol. 2, 775–778 (1994). [CrossRef]
  4. X. Li, T. A. King, F. Pallikari-Viras, “Characteristics of composites based on PMMA modified gel-silica glasses,” J. Non Cryst. Solids 170, 243–249 (1994). [CrossRef]
  5. M. D. Rahn, T. A. King, “High-performance solid-state dye laser based on Perylene-Orange doped polycom glass,” J. Mod. Opt. 45, 1259–1267 (1998).
  6. D. A. Gromov, K. M. Dyumaev, A. A. Manenkov, A. P. Maslukov, G. A. Matyushin, V. S. Nechitailo, A. M. Prokhorov, “Efficient plastic-host dye lasers,” J. Opt. Soc. Am. B 27, 1028–1031 (1985). [CrossRef]
  7. S. M. Giffin, I. T. McKinnie, W. J. Wadsworth, A. D. Woolhouse, G. J. Smith, T. G. Haskell, “Solid state dye lasers based on 2-hydroxyethyl methacrylate and methyl methacrylate co-polymers,” Opt. Commun. 161, 163–170 (1999). [CrossRef]
  8. A. Costela, I. Garcia-Moreno, J. Barroso, R. Sastre “Studies on laser action from polymeric matrices doped with Coumarin 503,” Appl. Phys. B 67, 167–173 (1998). [CrossRef]
  9. G. Seybold, G. Wagenblast, “New perylene and violanthrone dyestuffs for fluorescent collectors,” Dyes Pigm. 11, 303–317 (1989). [CrossRef]
  10. M. Shah, K. Thangaraj, M. L. Soong, L. T. Wolford, J. H. Boyer, I. R. Politzer, T. G. Pavlopoulos, “Pyrromethene-BF2 complexes as laser dyes. 1,” Heteroatom. Chem. 1, 389–399 (1990). [CrossRef]
  11. M. P. Oneil, “Synchronously pumped visible laser dye with twice the efficiency of Rhodamine 6G,” Opt. Lett. 18, 37–38 (1993). [CrossRef]
  12. A. A. Gorman, I. Hamblett, T. A. King (Laser Photonics Research Group, Department of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK), and M. D. Rahn, are preparing a manuscript with the title “A pulse radiolysis and pulsed laser study of the Pyrromethene 567 triplet state.”
  13. M. Faloss, M. Canva, P. Georges, A. Brun, F. Chaput, J.-P. Boilot “Toward millions of laser pulses with pyrromethene- and perylene-doped xerogels,” Appl. Opt. 36, 6760–6763 (1997). [CrossRef]
  14. D. Pacheco, H. R. Aldag, “Comparison of the laser performance of solid state dye media under long- and short-pulse excitation,” in Solid-State Lasers VII, R. Scheps, ed., Proc. SPIE3265, 2–12 (1998). [CrossRef]
  15. R. S. Anderson, R. E. Hermes, G. A. Matyushin, V. S. Nechitailo, S. C. Picarello, “Photostability of dye doped modified polymer at extremely high intensities: Medlite™ laser system,” in Solid-State Lasers VII, R. Scheps, ed., Proc. SPIE3265, 13–20 (1998). [CrossRef]
  16. R. E. Hermes, T. H. Allik, S. Chandra, J. A. Hutchinson, “High efficiency pyrromethene doped solid state dye laser,” Appl. Phys. Lett. 63, 877–879 (1993). [CrossRef]
  17. M. D. Rahn, T. A. King, A. A. Gorman, I. Hamblett, “Photostability enhancement of Pyrromethene 567 and Perylene Orange in oxygen free liquid and solid dye lasers,” Appl. Opt. 36, 5862–5871 (1997). [CrossRef] [PubMed]
  18. T. I. Suratwala, K. Davidson, Z. Gardlund, D. R. Uhlmann, S. Bonilla, N. Peyghambarian, “Molecular engineering and photostability of laser dyes within sol-gel hosts,” in Solid-State Lasers VI, R. Scheps, ed., Proc. SPIE2986, 141–152 (1997). [CrossRef]
  19. P. R. Ogilby, M. P. Dillon, M. Kristiansen, R. L. Clough, “Quenching of singlet oxygen in solid organic polymers,” Macromolecules 25, 3399–3405 (1992). [CrossRef]
  20. A. A. Gorman, I. Hamblett, C. Lambert, B. Spencer, M. C. Standern, “Identification of both preequilibrium and diffusion limits for reaction of singlet oxygen, O2(1Δg), with both physical and chemical quenchers—variable temperature, time resolved infrared luminescence studies,” J. Am. Chem. Soc. 110, 8053–8059 (1988). [CrossRef]
  21. G. Buntinx, P. Valat, V. Wintgens, O. Poizat, “Photoreduction of 4,4′-bipyridine by triethylamine and by 1,4-diazabicylclo[2.2.2]octane in acetonitrile as studied by nanosecond absorption and Raman spectroscopies,” J. Phys. Chem. 95, 9347–9352 (1991). [CrossRef]
  22. K. I. Priyadarsini, J. P. Mittal, “Effect of 1,4-diazabicyclo-[2,2,2]-octane on the laser properties of 7-amino coumarin dyes,” J. Photochem. Photobiol. A 61, 381–388 (1991). [CrossRef]

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