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Applied Optics

Applied Optics


  • Vol. 41, Iss. 9 — Mar. 20, 2002
  • pp: 1704–1713

High-repetition-rate, narrow-band dye lasers with water as a solvent for dyes

Alok K. Ray, Sucharita Sinha, Soumitra Kundu, Sasi Kumar, Sivagiriyal Karunakaran Sreenivasan Nair, Tamal Pal, and Kamalesh Dasgupta  »View Author Affiliations

Applied Optics, Vol. 41, Issue 9, pp. 1704-1713 (2002)

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The performance of a copper vapor laser-pumped narrow-band dye laser in oscillator-amplifier configuration with water-based binary mixture solvents is described. Although oscillator efficiency in water-surfactant (sodium lauryl sulfate) solvent was comparable with that that employed pure ethanolic solvent, amplifier efficiency was found to be lower. Experiments that were carried out with vertically polarized pump beams and either horizontally or vertically polarized signal beams show that, in case of both the pump and signal having orthogonal polarization (horizontal) and same polarization (vertical), the extraction efficiency for both ethanolic and water-micelle media increased substantially from 15.7% to 18.5% and from 10% to 12.5%, respectively. However, the relative difference remained nearly the same, indicating that a slower orientational diffusion of excited dye molecules in a micellar medium is not responsible for a decrease in amplifier efficiency. Amplifier efficiency comparable with that containing ethanolic dye solutions could be obtained with a binary solvent that comprises a mixture of water and about 30% n-propanol. The performances of two efficient dyes, Rhodamine-6G and Kiton Red S, using water-based solvents were studied.

© 2002 Optical Society of America

OCIS Codes
(140.2050) Lasers and laser optics : Dye lasers
(140.3600) Lasers and laser optics : Lasers, tunable
(300.1030) Spectroscopy : Absorption
(300.2140) Spectroscopy : Emission

Original Manuscript: April 27, 2001
Revised Manuscript: October 17, 2001
Published: March 20, 2002

Alok K. Ray, Sucharita Sinha, Soumitra Kundu, Sasi Kumar, Sivagiriyal Karunakaran Sreenivasan Nair, Tamal Pal, and Kamalesh Dasgupta, "High-repetition-rate, narrow-band dye lasers with water as a solvent for dyes," Appl. Opt. 41, 1704-1713 (2002)

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  1. Ulrich Brackmann, Lambdachrome Laser-grade Dyes Data Sheets (Lambda Physik GmbH, Germany, 1986).
  2. D. Klick, “Industrial application of dye lasers,” in Dye Laser Principles with Applications, (Academic, New York, 1990), pp. 345–398. [CrossRef]
  3. C. E. Webb, “High power dye lasers pumped by copper vapor lasers,” in High-Power Dye Lasers, F. J. Duarte, ed., Vol. 65 of Springer Series in Optical Sciences, (Springer-Verlag, Berlin, 1991), pp. 177–179.
  4. O. G. Peterson, “Dye lasers,” in Methods of Experimental Physics: Quantum Electronics, C. L. Tang, ed. (Academic, New York, 1979), Vol. 15, part A, pp. 266–267,
  5. E. Rabinowitch, L. F. Epstein, “Polymerization of dyestuffs in solution: thionine and methylene blue,” J. Am. Chem. Soc. 63, 69–78 (1941). [CrossRef]
  6. O. G. Peterson, S. A. Tuccio, B. B. Snavely, “cw operation of an organic dye solution laser,” Appl. Phys. Lett. 17, 245–247 (1970). [CrossRef]
  7. F. P. Schafer, “Principles of dye laser operation,” in Dye Lasers, F. P. Schafer, ed. (Springer-Verlag, Berlin, 1977), pp. 21–24, 158–159.
  8. R. H. Baker, M. Gratzel, R. Steiger, “Drastic fluorescence enhancement and photochemical stabilization of cyanine dyes through micellar systems,” J. Am. Chem. Soc. 102, 847–848 (1980). [CrossRef]
  9. Z. Konefal, E. Lisicki, T. Marszalek, “The influence of energy migration in micellar dye solutions on the performance of dye lasers,” Acta Phys. Pol. A 52, 149–155 (1977).
  10. A. A. Shahinian, “Correlation between the micelle structure and the lasing efficiency of micelle incorporated dye,” Laser Phys. 5, 711–718 (1995).
  11. K. Igarshi, M. Maeda, T. Takao, M. Uchiumi, I. Oki, K. Shimamoto, “Operation of Rhodamine 6G dye laser in water solution,” Jpn. J. Appl. Phys. 34, 3093–3096 (1995). [CrossRef]
  12. M. E. Diaz Garcia, A. Sanz-Medel, “Dye-surfactant interactions: a review,” Talanta 33, 255–264 (1986). [CrossRef]
  13. D. Magde, G. E. Rojas, P. G. Seybold, “Solvent dependence of the fluorescence lifetimes of Xanthene dyes,” Photochem. Photobiol. 70, 737–744 (1999). [CrossRef]
  14. J. E. Selwyn, J. I. Steinfeld, “Aggregation equilibria of Xanthene dyes,” J. Phys. Chem. 76, 762–774 (1972). [CrossRef]
  15. Kh. L. Arvan, N. E. Zaitseva, “Spectral investigation of the influence of the solvent on the aggregation of organic dyes,” Opt. Spectrosc. 10, 272–276 (1961).
  16. G. A. K. Wallece, J. H. Flint, S. C. Wallace, “Resonance energy transfer between lasing dyes in micellar media,” Chem. Phys. Lett. 32, 71–75 (1975). [CrossRef]
  17. S. Sinha, A. K. Ray, S. Kundu, S. Kumar, S. K. S. Nair, K. Dasgupta, “Photostability of laser dye solutions under copper vapour laser excitation,” Appl. Phys. B 72, 617–621 (2001). [CrossRef]
  18. V. K. Kelkar, B. S. Valaulikar, J. T. Kunjappu, C. Manohar, “Aggregation characteristics of laser dye Rhodamine 6G in aqueous surfactant solutions, “ Photochem. Photobiol. 52, 717–721 (1990). [CrossRef]
  19. J. H. Fendler, E. J. Fendler, Micellar and Macromolecular Systems, (Academic, New York, 1975) p. 20.
  20. F. J. Duarte, J. A. Piper, “Narrow linewidth high prf copper laser-pumped dye laser oscillators,” Appl. Opt. 23, 1391–1394 (1984). [CrossRef]
  21. K. Dasgupta, “Development of high repetition rate pulse dye lasers and their application in multistep excitation spectroscopy of atoms,” Ph.D. dissertation (University of Bombay, India, 1989).
  22. I. L. Bass, R. E. Bonanno, R. P. Hackel, P. R. Hammond, “High-average-power dye laser at Lawrence Livermore National Laboratory,” Appl. Opt. 31, 6993–7006 (1992). [CrossRef] [PubMed]
  23. C. H. Chen, J. L. Fox, F. J. Duarte, J. J. Ehrlich, “Lasing characteristic of new coumarin-analog dyes: broadband and narrow-linewidth performances,” Appl. Opt. 27, 443–445 (1988). [CrossRef] [PubMed]
  24. C.-M. Hu, R. Zwanzig, “Rotational friction coefficients for spheriods with the slipping boundary condition,” J. Chem. Phys. 60, 4354–4357 (1974). [CrossRef]

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