OSA's Digital Library

Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 42, Iss. 12 — Apr. 20, 2003
  • pp: 2085–2093

Optical Emission from Laser-Induced Breakdown Plasma of Solid and Liquid Samples in the Presence of a Magnetic Field

Virendra N. Rai, Awadhesh K. Rai, Fang-Yu Yueh, and Jagdish P. Singh  »View Author Affiliations


Applied Optics, Vol. 42, Issue 12, pp. 2085-2093 (2003)
http://dx.doi.org/10.1364/AO.42.002085


View Full Text Article

Acrobat PDF (163 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations

Abstract

The optical properties of laser-induced plasma generated from solid (Al alloy) and liquid (Mn, Cr, Mg, or Ti solutions) samples expanded across an external, steady magnetic field have been studied by atomic-emission spectroscopy. Various line emissions obtained from the constituents of the Al alloy and of the aqueous solution show an enhancement in intensity in the presence of an ~5-kG magnetic field. The enhancement of the signal was nearly a factor of 2 for the minor constituents of the solid samples and a factor of 1.5 for the elements in liquid phase. Temporal evolution of the emission from the solid sample showed maximum enhancement in emission intensity at 3–10-μs time delay after plasma formation in the laser energy range 10–50 mJ. However, for the liquid sample the maximum signal was for a gate delay of 3–25 μs in the energy range 50–200 mJ. This enhancement in the emission intensity was found to be due to an increase in effective density of the plasma as a result of magnetic confinement when the plasma cooled after expansion. This enhanced emission was due to an increase in the rate of radiative recombination in the plasma.

© 2003 Optical Society of America

OCIS Codes
(120.6200) Instrumentation, measurement, and metrology : Spectrometers and spectroscopic instrumentation
(140.3440) Lasers and laser optics : Laser-induced breakdown
(300.2140) Spectroscopy : Emission
(300.6210) Spectroscopy : Spectroscopy, atomic
(300.6360) Spectroscopy : Spectroscopy, laser

Citation
Virendra N. Rai, Awadhesh K. Rai, Fang-Yu Yueh, and Jagdish P. Singh, "Optical Emission from Laser-Induced Breakdown Plasma of Solid and Liquid Samples in the Presence of a Magnetic Field," Appl. Opt. 42, 2085-2093 (2003)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-42-12-2085


Sort:  Author  |  Year  |  Journal  |  Reset

References

  1. L. J. Radziemski and D. A. Cremers, eds., Laser Induced Plasma and Applications (Marcel Dekker, New York, 1989).
  2. H. Zhang, F. Y. Yueh, and J. P. Singh, “Laser induced breakdown spectrometry as a multimetal continuous emission monitor,” Appl. Opt. 38, 1459–1466 (1999).
  3. S. G. Buckley, H. A. Johnsen, K. R. Hencken, and D. W. Hahn, “Implementation of laser-induced breakdown spectroscopy as a continuous emissions monitor for toxic metals,” Waste Manage. 20, 455–462 (2000).
  4. F. Y. Yueh, R. C. Sharma, J. P. Singh, and H. Zhang, “Evaluation of the potential of laser induced breakdown spectroscopy for detection of trace elements in liquid,” J. Air Waste Manag. Assoc. 52, 174–185 (2002).
  5. E. D. Lankaster, K. L. McNesby, R. G. Daniel, and A. W. Miziolek, “Spectroscopic analysis of five suppressant and refrigerants by laser-induced breakdown spectroscopy,” Appl. Opt. 38, 1476–1480 (1999).
  6. J. P. Singh, F. Y. Yueh, H. Zhang, and K. P. Karney, “A preliminary study of the determination of uranium, plutonium and neptunium by laser-induced breakdown spectroscopy,” Rec. Res. Dev. Appl. Spectrosc. 2, 59–67 (1999).
  7. D. A. Rusak, B. C. Castle, B. W. Smith, and J. D. Winefordner, “Fundamentals and applications of laser-induced breakdown spectroscopy,” Crit. Rev. Anal. Chem. 27, 257–290 (1997).
  8. K. Song, Y. I. Lee, and J. Sneddon, “Application of laser induced breakdown spectroscopy,” Appl. Spectrosc. Rev. 32, 183–235 (1997).
  9. F. Y. Yueh, J. P. Singh, and H. Zhang, “Laser-induced breakdown spectroscopy: elemental analysis,” in Encyclopedia of Analytical Chemistry, R. A. Meyers, ed., Vol. 3(Wiley, New York, 2000), pp. 2065–2087.
  10. O. Samek, D. C. S. Beddows, J. Kaiser, S. V. Kukhlevsky, M. Liska, H. H. Telle, and J. Young, “Application of laser-induced breakdown spectroscopy to in situ analysis of liquid samples,” Opt. Eng. 38, 2248–2262 (2000).
  11. R. A. Multari, L. E. Foster, D. A. Cremers, and M. J. Ferris, “Effect of sampling geometry on elemental emissions in laser-induced breakdown spectroscopy,” Appl. Spectrosc. 12, 1483–1499 (1996).
  12. R. Sattmann, V. Sturm, and R. Noll, “Laser-induced breakdown spectroscopy of steel using multiple Q switch Nd:YAG laser pulses,” J. Phys. D 28, 2181–2187 (1995).
  13. L. St-Onge, M. Sabasabi, and P. Cielo, “Analysis of solids using laser induced plasma spectroscopy in double pulse mode,” Spectrochim. Acta Part B 53, 407–415 (1998).
  14. D. N. Stratis, K. L. Eland, and S. M. Angel, “Effect of pulse delay time on a pre-ablation dual-pulse LIBS plasma,” Appl. Spectrosc. 55, 1297–1303 (2001).
  15. Y. Ito, O. Ueki, and S. Nakamura, “Determination of colloidal iron in water by laser-induced breakdown spectroscopy,” Anal. Chim. Acta 229, 401–405 (1995).
  16. S. Suckwer, H. Skinner, H. Milchberg, C. Keane, and D. Noorhees, “Amplification of stimulated soft x-ray emission in a confined plasma column,” Phys. Rev. Lett. 55, 1753–1756 (1985).
  17. K. J. Mason and J. M. Goldberg, “Characterization of laser plasma in a pulsed magnetic field: Part I. Spatially resolved emission studies,” Appl. Spectrosc. 45, 370–379 (1991).
  18. K. J. Mason and J. M. Goldberg, “Characterization of a laser plasma in a pulsed magnetic field: Part II. Time resolved emission and absorption studies,” Appl. Spectrosc. 45, 1444–1455 (1991).
  19. V. N. Rai, M. Shukla, and H. C. Pant, “Some studies on pico second laser produced plasma expanding across a uniform external magnetic field,” Laser Part. Beams 16, 431–443 (1998).
  20. A. Neogi and R. K. Thareja, “Laser produced carbon plasma expanding in vacuum low-pressure ambient gas and non-uniform magnetic field,” Phys. Plasmas 6, 365–371 (1999), and references therein.
  21. J. D. Huba, A. B. Hassam, and D. Winske, “Stability of sub-alfvenic plasma expansions,” Phys. Fluids B 2, 1676–1697 (1990).
  22. V. N. Rai, M. Shukla, and H. C. Pant, “An x-ray biplanar photodiode and the x-ray emission from magnetically confined laser produced plasma,” Pramana J. Phys. 52, 49–65 (1999).
  23. H. R. Griem, Plasma Spectroscopy (McGraw Hill, New York, 1964).
  24. M. Sabsabi and P. Cielo, “Quantitative analysis of aluminum alloy by laser-induced breakdown spectroscopy and plasma characterization,” Appl. Spectrosc. 49, 499–507 (1995).
  25. D. E. Kim, K. J. Yoo, H. K. Park, K. J. Oh, and D. W. Kim, “Quantitative analysis of aluminum impurities in Zn alloy by laser induced breakdown spectroscopy,” Appl. Spectrosc. 51, 22–29 (1997).
  26. A. K. Rai, H. Zhang, F. Y. Yueh, J. P. Singh, and A. Weisburg, “Parametric study of fiber-optic laser-induced breakdown spectroscopy probe for analysis of aluminum alloys,” Spectrochim. Acta Part B 56, 2371–2383 (2001).
  27. V. N. Rai, J. P. Singh, F. Y. Yueh, and R. L. Cook, “Dynamics, stability and emission of radiation from laser produced plasma expanding across an external magnetic field,” paper AIAA-2001–2819, presented at the 32nd AIAA Plasma Dynamics and Lasers Conference, Anaheim, Calif., 11–14 June 2001 (American Institute for Aeronautics and Astronautics, Reston, Va., 2001).

Cited By

Alert me when this paper is cited

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.


« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited