OSA's Digital Library

Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 42, Iss. 25 — Sep. 1, 2003
  • pp: 5136–5139

Observations of infrared bands of asymmetrical ozone isotopologues 16O16O18O and 16O18O18O

Alain Barbe, Marie-Renée De Backer-Barilly, Vladimir G. Tyuterev, and Serguei A. Tashkun  »View Author Affiliations


Applied Optics, Vol. 42, Issue 25, pp. 5136-5139 (2003)
http://dx.doi.org/10.1364/AO.42.005136


View Full Text Article

Enhanced HTML    Acrobat PDF (188 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations

Abstract

Infrared spectra (0.003 cm-1 resolution) of 16O16O18O and 16O18O18O ozone isotopologues have been recorded and analyzed in the range 600–5000 cm-1. Several thousand rovibrational lines belonging to 32 absorption bands have been measured and assigned. An accurate determination of band centers through the rovibrational analysis has been done, 12 bands being observed for the first time to our knowledge. In addition to atmospheric retrieval applications, these results are also useful for a validation of potential energy surfaces and for the study of isotope effects in dynamic processes of ozone.

© 2003 Optical Society of America

OCIS Codes
(010.4950) Atmospheric and oceanic optics : Ozone
(300.6300) Spectroscopy : Spectroscopy, Fourier transforms
(300.6390) Spectroscopy : Spectroscopy, molecular

History
Original Manuscript: March 27, 2003
Revised Manuscript: June 11, 2003
Published: September 1, 2003

Citation
Alain Barbe, Marie-Renée De Backer-Barilly, Vladimir G. Tyuterev, and Serguei A. Tashkun, "Observations of infrared bands of asymmetrical ozone isotopologues 16O16O18O and 16O18O18O," Appl. Opt. 42, 5136-5139 (2003)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-42-25-5136


Sort:  Author  |  Year  |  Journal  |  Reset  

References

  1. M. R. De Backer-Barilly, A. Barbe, Vl. G. Tyuterev, A. Chichery, M. T. Bourgeois, “High resolution infrared spectra of the 16O18O16O ozone isotopomer in the range 900–5000 cm-1 lines positions,” J. Mol. Spectrosc. 216, 454–464 (2002). [CrossRef]
  2. M. R. De Backer-Barilly, A. Barbe, Vl. G. Tyuterev, “Infrared spectrum of 16O18O16O in the 5μm range. Positions, intensities and atmospheric applications,” Atm. Optics Ocean, 16, 206–211 (2003).
  3. M. R. De Backer-Barilly, A. Barbe, S. A. Tashkun, Vl. G. Tyuterev, A. Chichery, “The 5ν3 bands of 18O enriched ozone: line positions of 16O16O18O, 16O18O16O, 16O18O18O and 18O16O18O,” Mol. Phys. 22, 3499–3506 (2002). [CrossRef]
  4. M. R. De Backer-Barilly, A. Barbe, Vl. G. Tyuterev, “High resolution infrared spectra of the 16O18O16O ozone isotopomer in the range 900–5000 cm-1. Line positions,” J. Mol. Spectrosc. (2003), in press.
  5. Vl. G. Tyuterev, A. Barbe, S. N. Mikhailenko, Y. Babykov, “Spectroscopy and molecular properties of ozone,” http://ozone.univ-reims.fr and http://ozone.iao.ru .
  6. C. Jansen, J. Guenther, K. Mauersberger, D. Krankowsky, “Kinetic origin of the ozone isotope effect: a critical analysis of enrichments and rate coefficients,” Phys. Chem. Chem. Phys. 3, 4718–4721 (2001). [CrossRef]
  7. J. J. Plateaux, A. Barbe, A. Delahaigue, “Reims high resolution F. T. S. data reduction for ozone,” Spectrochim. Acta A 51, 1153–1169 (1995). [CrossRef]
  8. L. Régalia, “Mesures à l’aide d’un spectromètre par transformation de Fourier, des intensités et coefficients d’élargissement de molécules d’intérêt atmosphérique. Etude des précisions: application à N2O, H2O, O3,” M. S. Thesis (Reims University, Reims, France, 1996).
  9. J. J. Plateaux, L. Régalia, C. Boussin, A. Barbe, “A multispectrum fitting technique for data recorded by Fourier Transform spectrometer,” J. Quant. Spectrosc. Radiat. Transfer 68, 507–520 (2001). [CrossRef]
  10. Vl. G. Tyuterev, S. A. Tashkun, D. Schwenke, A. Barbe, “Isotopically invariant potential function of the ozone molecule,” in Proceedings of Highrus Conference, Proc. SPIE (to be published).
  11. Vl. G. Tyuterev, T. Cours, S. A. Tashkun, P. Jensen, A. Barbe “Potential function of the ozone molecule: global calculations of the rovibrational states and the dissociation behaviour,” in the 13th Symposium and School on High-Resolution Molecular Spectroscopy,” L. N. Sinitsa, editor, Proc. SPIE4063, 142–151 (1999).
  12. R. Siebert, P. Fleurat-Lessard, R. Schinke, M. Bittererova, S. C. Farantos, “The vibrational energies of ozone up to the dissociation threshold: dynamics calculations on an accurate potential energy surface,” J. Chem. Phys. 116, 9749–9767 (2002). [CrossRef]
  13. C. Camy-Peyret, J. M. Flaud, A. Perrin, V. Malathy Devi, C. P. Rinsland, M. A. H. Smith, “The hybrid-type bands ν1 and ν3 of 16O16O18O: line positions and intensities,” J. Mol. Spectrosc. 118, 345–354 (1986). [CrossRef]
  14. J. K. G. Watson, “Determination of centrifugal distortion coefficients of asymmetric top molecules,” J. Chem. Phys. 46, 4189–4196 (1967). [CrossRef]
  15. J. M. Flaud, R. Bacis, “The ozone molecule: infrared and microwave spectroscopy,” Spectrochim Acta Part A 54, 3–16 (1998). [CrossRef]
  16. V. I. Perevalov, Vl. G. Tyuterev, “Effective centrifugal distortion Hamiltonian with empirically determinable parameters in the case of Coriolis resonances for asymmetric top molecules,” Opt. Spectrosk. 52, 644–650 (1982).
  17. S. Mikhailenko, A. Barbe, Vl. G. Tyuterev, A. Chichery, “High-resolution IR spectra of the ozone molecule,” Atmos. Oceanic Opt 12, 771–785 (1999).
  18. A. Chichery, A. Barbe, Vl. G. Tyuterev, M. T. Bourgeois, “Analysis of high resolution spectra of 18O3. 1-Spectral range 1300–3100 cm-1,” J. Mol. Spectrosc. 206, 1–13 (2001). [CrossRef] [PubMed]
  19. A. Chichery, A. Barbe, Vl. G. Tyuterev, “Analysis of high resolution spectra of 18O3. 2-Spectral range 3100–4900 cm-1,” J. Mol. Spectrosc. 206, 14–26 (2001). [CrossRef] [PubMed]
  20. S. Mikhailenko, A. Barbe, Vl. G. Tyuterev, “Extended analysis of line positions and intensities of ozone bands in the 2900–3400 cm-1 region,” J. Mol. Spectrosc. 215, 29–41 (2002). [CrossRef]
  21. A. Barbe, “High resolution infrared spectroscopy of ozone: a support for atmospheric observations,” Computational Technologies 7, 12–23 (2002).
  22. J. M. Flaud, C. Camy-Peyret, A. N’Gom, V. Malathy-Devi, C. P. Rinsland, M. A. H. Smith, “The ν2 bands of 16O18O16O and 16O16O18O: line positions and intensities,” J. Mol. Spectrosc. 133, 217–223 (1989). [CrossRef]
  23. A. Perrin, A. M. Vasserot, J. M. Flaud, C. Camy-Peyret, C. P. Rinsland, M. A. H. Smith, V. Malathy-Devi, “The ν2 bands of 18O3, 18O16O18O and 16O18O18O: line positions and intensities,” J. Mol. Spectrosc. 143, 311–317 (1990). [CrossRef]
  24. M. T. Bourgeois, J. M. Flaud, A. Barbe, L. Régalia, C. Camy-Peyret, Plateaux,” The ν1+ν3 bands of 16O18O18O and 18O16O18O,” J. Mol. Spectrosc. 172, 552–558 (1995). [CrossRef]
  25. A. Chichery, A. Barbe, VI. G. Tyuterev, S. Tashkun, “High resolution IR spectra of 18O enriched ozone: band centers of 16O16O18O, 16O18O18O, 18O16O18O and 16O18O16O,” J. Mol. Spectrosc. 205, 347–349 (2001). [CrossRef] [PubMed]

Cited By

Alert me when this paper is cited

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.

Figures

Fig. 1
 

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited