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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 42, Iss. 30 — Oct. 20, 2003
  • pp: 6166–6173

Microanalysis of tool steel and glass with laser-induced breakdown spectroscopy

Klaus Loebe, Arnold Uhl, and Hartmut Lucht  »View Author Affiliations


Applied Optics, Vol. 42, Issue 30, pp. 6166-6173 (2003)
http://dx.doi.org/10.1364/AO.42.006166


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Abstract

A laser microscope system for the microanalytical characterization of complex materials is described. The universal measuring principle of laser-induced breakdown spectroscopy (LIBS) in combination with echelle optics permits a fast simultaneous multielement analysis with a possible spatial resolution below 10 pm. The developed system features completely UV-transparent optics for the laser-microscope coupling and the emission beam path and enables parallel signal detection within the wavelength range of 200–800 nm with a spectral resolution of a few picometers. Investigations of glass defects and tool steels were performed. The characterization of a glass defect in a tumbler by a micro-LIBS line scan, with use of a 266-nm diode-pumped Nd:YAG laser for excitation, is possible by simple comparison of plasma spectra of the defect and the surrounding area. Variations in the main elemental composition as well as impurities by trace elements are detected at the same time. Through measurement of the calibration samples with the known concentration of the corresponding element, a correlation between the intensity of spectral lines and the element concentration was also achieved. The change of elemental composition at the transient stellite solder of tool steels has been determined by an area scan. The two-dimensional pictures show abrupt changes of the element distribution along the solder edge and allow fundamental researches of dynamic modifications (e.g., diffusion) in steel.

© 2003 Optical Society of America

OCIS Codes
(140.3440) Lasers and laser optics : Laser-induced breakdown
(180.5810) Microscopy : Scanning microscopy
(300.6190) Spectroscopy : Spectrometers
(300.6210) Spectroscopy : Spectroscopy, atomic
(300.6320) Spectroscopy : Spectroscopy, high-resolution
(300.6500) Spectroscopy : Spectroscopy, time-resolved

History
Original Manuscript: January 28, 2003
Revised Manuscript: August 13, 2003
Published: October 20, 2003

Citation
Klaus Loebe, Arnold Uhl, and Hartmut Lucht, "Microanalysis of tool steel and glass with laser-induced breakdown spectroscopy," Appl. Opt. 42, 6166-6173 (2003)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-42-30-6166


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References

  1. K. Laqua, “Analytical spectroscopy using laser atomizers,” in Chemical Analysis, J. D. Winefordner, ed. (Wiley, New York, 1997), pp. 47–118.
  2. L. Moenke-Blankenburg, “Laser microanalysis,” in Chemical Analysis, J. D. Winefordner, ed. (Wiley, New York, 1989). [CrossRef]
  3. D. W. Hahn, W. L. Flower, K. R. Henecken, “Discrete particle detection and metal emissions monitoring using laser-induced breakdown spectroscopy,” Appl. Spectrosc. 51, 1836–1844 (1997). [CrossRef]
  4. A. Ciucci, M. Corsi, V. Palleschi, S. Rastelli, A. Salvetti, E. Tognoni, “New procedure for quantitative elemental analysis by laser-induced plasma spectroscopy,” Appl. Spectrosc. 53, 960–964 (1999). [CrossRef]
  5. C. Geertsen, J.-L. Lacour, P. Mauchien, L. Pierrard, “Evaluation of laser ablation optical emission spectrometry for microanalysis in aluminium samples,” Spectrochim. Acta Part B 51, 1403–1416 (1996). [CrossRef]
  6. I. B. Gornushkin, B. W. Smith, H. Nasajpour, J. D. Winefordner, “Identification of solid materials by correlation analysis using a microscopic laser-induced plasma spectrometer,” Anal. Chem. 71, 5157–5164 (1999). [CrossRef]
  7. K. Bange, H. Müller, C. Strubel, “Characterization of defects in glasses and coatings on glasses by microanalytical techniques,” Mikrochim. Acta 132, 493–503 (2000). [CrossRef]
  8. S. Florek, H. Becker-Ross, T. Florek, “Adaptation of an echelle spectrograph to a large CCD detector,” Fresenius. J. Anal. Chem. 355, 269–271 (1996).
  9. H. Becker-Ross, M. Okruss, S. Florek, U. Heitmann, M. D. Huang, “Echelle-spectrograph as a tool for studies of structured background in flame atomic absorption spectrometry,” Spectrochim. Acta Part B 57, 1493–1504 (2002). [CrossRef]
  10. I. Bassiotis, A. Diamantopoulou, A. Giannoudakos, F. Roubani-Kalantzopoulou, M. Kompitsas, “Effects of experimental parameters in quantitative analysis of steel alloy by laser-induced breakdown spectroscopy,” Spectrochim. Acta Part B 56, 671–683 (2001). [CrossRef]
  11. U. Panne, C. Haisch, M. Clara, R. Niessner, “Analysis of glass and glass melts during the vitrification process of fly and bottom ashes by laser-induced plasma spectroscopy. Part I: Normalization and plasma diagnostics,” Spectrochim. Acta Part B 53, 1957–1968 (1998). [CrossRef]
  12. V. Detalle, R. Héon, M. Sabsabi, L. St-Onge, “An evaluation of a commercial Echelle spectrometer with intensified charge-coupled device detector for materials analysis by laser-induced plasma spectroscopy,” Spectrochim. Acta Part B 56, 1011–1025 (2001). [CrossRef]
  13. A. Uhl, K. Loebe, L. Kreuchwig, “Fast analysis of wood preservers using laser induced breakdown spectroscopy,” Spectrochim. Acta Part B 56, 795–806 (2001). [CrossRef]
  14. P. Fichet, P. Mauchien, J.-F. Wagner, C. Moulin, “Quantitative elemental determination in water and oil by laser induced breakdown spectroscopy,” Analytica Chim. Acta 429, 269–278 (2001). [CrossRef]
  15. U. Panne, R. E. Neuhauser, C. Haisch, H. Fink, R. Niessner, “Remote analysis of a mineral melt by laser-induced plasma spectroscopy,” Applied Spectrosc. 56, 375–380 (2002). [CrossRef]

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