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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 42, Iss. 30 — Oct. 20, 2003
  • pp: 6221–6225

Laser-induced breakdown spectroscopy of gas mixtures of air, CO2, N2, and C3H8 for simultaneous C, H, O, and N measurement

Volker Sturm and Reinhard Noll  »View Author Affiliations


Applied Optics, Vol. 42, Issue 30, pp. 6221-6225 (2003)
http://dx.doi.org/10.1364/AO.42.006221


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Abstract

Laser-induced breakdown spectroscopy (LIBS) was applied for simultaneous measurement of the elements C, H, N, and O in CO2–air, C3H8–CO2, and C3H8–N2 gas mixtures at atmospheric pressure. A single 7-mm-diameter aperture at the sample chamber was used for 1064-nm Nd:YAG laser irradiation and plasma signal output to an echelle spectrometer. Double-pulse laser bursts of ∼8-ns pulse width (FWHM) and 250-ns interpulse separation were applied to increase the plasma signal. Calibration curves of the LIBS signal versus the partial pressure or the atomic abundance ratios were taken by dilution series in intervals that are relevant in the combustion of heptane (C7H16) near an equivalence ratio of 1.

© 2003 Optical Society of America

OCIS Codes
(120.0120) Instrumentation, measurement, and metrology : Instrumentation, measurement, and metrology
(120.1740) Instrumentation, measurement, and metrology : Combustion diagnostics
(120.6200) Instrumentation, measurement, and metrology : Spectrometers and spectroscopic instrumentation
(140.3440) Lasers and laser optics : Laser-induced breakdown
(300.6210) Spectroscopy : Spectroscopy, atomic

History
Original Manuscript: January 20, 2003
Revised Manuscript: May 13, 2003
Published: October 20, 2003

Citation
Volker Sturm and Reinhard Noll, "Laser-induced breakdown spectroscopy of gas mixtures of air, CO2, N2, and C3H8 for simultaneous C, H, O, and N measurement," Appl. Opt. 42, 6221-6225 (2003)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-42-30-6221


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References

  1. J. F. Ready, Effects of High-Power Laser Radiation (Academic, Orlando, Fla., 1971), pp. 396–399.
  2. C. Haisch, R. Niessner, O. I. Matveev, U. Panne, N. Omenetto, “Element-specific determination of chlorine in gases by laser-induced-breakdown-spectroscopy (LIBS),” Fresenius J. Anal. Chem. 356, 21–26 (1996). [CrossRef]
  3. M. Tran, B. W. Smith, D. Hahn, J. D. Winefordner, “Detection of gaseous and particulate fluorides by laser-induced breakdown spectroscopy,” Appl. Spectrosc. 55, 1455–1461 (2001). [CrossRef]
  4. D. H. Plemmons, C. Parigger, J. W. L. Lewis, J. O. Hornkohl, “Analysis of combined spectra of NH and N2,” Appl. Opt. 37, 2493–2498 (1998). [CrossRef]
  5. A. H. Schwebel, A. M. Ronn, “Spectroscopy of laser-induced dielectric breakdown in gas mixtures,” Chem. Phys. Lett. 100, 178–182 (1983). [CrossRef]
  6. M. Casini, M. A. Harith, V. Palleschi, A. Salvetti, D. P. Singh, M. Vaselli, “Time-resolved LIBS experiment for quantitative determination of pollutant concentrations in air,” Laser Part. Beams 9, 633–639 (1991). [CrossRef]
  7. L. J. Radziemski, D. A. Cremers, T. R. Loree, “Detection of beryllium by laser-induced-breakdown spectroscopy,” Spectrochim. Acta Part B 38, 349–355 (1983). [CrossRef]
  8. D. W. Hahn, W. L. Flower, K. R. Hencken, “Discrete particle detection and metal emissions monitoring using laser-induced breakdown spectroscopy,” Appl. Spectrosc. 12, 1836–1844 (1997). [CrossRef]
  9. J. E. Carranza, B. T. Fisher, G. D. Yoder, D. W. Hahn, “On-line analysis of ambient air aerosols using laser-induced breakdown spectroscopy,” Spectrochim. Acta Part B 56, 851–864 (2001). [CrossRef]
  10. M. Noda, Y. Deguchi, S. Iwasaki, N. Yoshikawa, “Detection of carbon content in a high-temperature and high-pressure environment using laser-induced breakdown spectroscopy,” Spectrochim. Acta Part B 57, 701–709 (2002). [CrossRef]
  11. A. Brysch, V. Sturm, R. Noll, H. Denecke-Arnold, H. Brinkmann, K. Mühlheims, A. Opfermann, K. Mavrommatis, H. W. Gudenau, K. Heinänen, “Laser-based elemental analysis of the top gas of a blast furnace,” in Proceedings of International Symposium on Photonics in Measurement, VDI-Berichte 1694 (VDI Verlag, Düsseldorf, Germany, 2002), pp. 117–123.
  12. I. Glassman, Combustion (Academic, San Diego, Calif., 1996), pp. 20–29.
  13. A. K. Sandrowitz, J. M. Cooke, N. G. Glumac, “Flame emission spectroscopy for equivalence ratio monitoring,” Appl. Spectrosc. 52, 658–662 (1998). [CrossRef]
  14. R. W. Schmieder, “Combustion applications of laser-induced breakdown spectroscopy,” in Proceedings of the Electro-Optics Laser Conference (Cahners, Chicago, Ill., 1981), pp. 17–27.
  15. T. X. Phuoc, F. P. White, “Laser-induced spark for measurements of the fuel-to-air ratio of a combustible mixture,” Fuel 81, 1761–1765 (2002). [CrossRef]
  16. R. Sattmann, V. Sturm, R. Noll, “Laser-induced breakdown spectroscopy of steel samples using multiple Q-switch Nd:YAG laser pulses,” J. Phys. D 28, 2181–2187 (1995). [CrossRef]
  17. V. Sturm, L. Peter, R. Noll, “Steel analysis with laser-induced breakdown spectrometry in the vacuum ultraviolet,” Appl. Spectrosc. 54, 1275–1278 (2000). [CrossRef]
  18. K. Fieweger, R. Blumenthal, G. Adomeit, “Self-ignition of S.I. engine model fuels: shock tube investigation at high pressure,” Combust. Flame 109, 599–619 (1997). [CrossRef]
  19. K. Kuwahara, H. Ando, “Diagnostics of in-cylinder flow, mixing and combustion in gasoline engines,” Meas. Sci. Technol. 11, R95–R111 (2000). [CrossRef]
  20. D. R. Lide, ed., CRC Handbook of Chemistry and Physics, 73rd ed. (CRC Press, Boca Raton, Fla., 1992), p. 14–11.

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