A femtosecond air spark has recently been combined with a nanosecond ablative pulse in order to map the spatial and temporal interactions of the two plasmas in femtosecond–nanosecond orthogonal preablation spark dual-pulse laser-induced breakdown spectroscopy (LIBS). Good spatial and temporal correlation was found for reduced atomic emission from atmospheric species (nitrogen and oxygen) and increased atomic emission from ablated species (copper and aluminum) in the femtosecond–nanosecond plasma, suggesting a potential role for atmospheric pressure or nitrogen/oxygen concentration reduction following air spark formation in generating atomic emission enhancements in dual-pulse LIBS.
© 2004 Optical Society of America
Original Manuscript: December 8, 2003
Revised Manuscript: June 4, 2004
Published: September 20, 2004
Jon Scaffidi, William Pearman, Marion Lawrence, J. Chance Carter, Bill W. Colston, and S. Michael Angel, "Spatial and temporal dependence of interspark interactions in femtosecond-nanosecond dual-pulse laser-induced breakdown spectroscopy," Appl. Opt. 43, 5243-5250 (2004)