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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 43, Iss. 31 — Nov. 1, 2004
  • pp: 5901–5910

Rayleigh-calibrated fluorescence quantum yield measurements of acetone and 3-pentanone

Jon D. Koch, Ronald K. Hanson, Wieland Koban, and Christof Schulz  »View Author Affiliations


Applied Optics, Vol. 43, Issue 31, pp. 5901-5910 (2004)
http://dx.doi.org/10.1364/AO.43.005901


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Abstract

We measured fluorescence quantum yields of acetone and 3-pentanone as a pure gas and with nitrogen diluent at room temperature at 20, 507, and 1013 mbar using 248, 266, and 308 nm excitation by calibrating the optical collection system with Rayleigh scattering from nitrogen. At 20 mbar with 308-nm excitation, the fluorescence quantum yields for acetone and 3-pentanone are 7 ± 1 × 10-4 and 1.1 ± 0.2 × 10-3, respectively, and each decreases with decreasing excitation wavelength. These directly measured values are significantly lower than earlier ones that were based on a chain of relative measurements. The observed pressure and excitation wavelength dependence is in qualitative agreement with a previously developed fluorescence quantum yield model, but the absolute numbers disagree. Changing acetone’s fluorescence rate constant to 3 × 105 s-1 from its previous value of 8 × 105 s-1 resulted in good agreement between our measurements and the model.

© 2004 Optical Society of America

OCIS Codes
(120.5820) Instrumentation, measurement, and metrology : Scattering measurements
(140.3610) Lasers and laser optics : Lasers, ultraviolet
(300.2530) Spectroscopy : Fluorescence, laser-induced

History
Original Manuscript: October 20, 2003
Revised Manuscript: April 30, 2004
Manuscript Accepted: May 21, 2004
Published: November 1, 2004

Citation
Jon D. Koch, Ronald K. Hanson, Wieland Koban, and Christof Schulz, "Rayleigh-calibrated fluorescence quantum yield measurements of acetone and 3-pentanone," Appl. Opt. 43, 5901-5910 (2004)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-43-31-5901


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