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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: James C. Wyant
  • Vol. 45, Iss. 30 — Oct. 20, 2006
  • pp: 7818–7825

Dispersion and thermal properties of lithium aluminum silicate glasses doped with Cr3+ ions

Fouad El-Diasty, Manal Abdel-Baki, Fathy A. Abdel Wahab, and Hussein Darwish  »View Author Affiliations


Applied Optics, Vol. 45, Issue 30, pp. 7818-7825 (2006)
http://dx.doi.org/10.1364/AO.45.007818


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Abstract

A series of new lithium aluminum silicate (LAS) glass systems doped with chromium ion is prepared. The reflectance and transmittance of the glass slabs are recorded. By means of an iteration procedure, the glass refractive index n and the extinction coefficient k and their dispersions are obtained. Across a wide spectral range of 0.2 1.6   μm , the dispersion curves are used to determine the atomic and quantum constants of the prepared glasses. These findings provide the average oscillator wavelength, the average oscillator strength, oscillator energy, dispersion energy, lattice energy, and material dispersion of the glass materials to be calculated. For optical waveguide applications, the wavelength for zero material dispersion is obtained. Dilatometric measurements are performed and the thermal expansion coefficient is calculated to throw some light on the thermo-optical properties of the present glasses correlating them with their structure and the presence of nonbridging oxygen ions.

© 2006 Optical Society of America

OCIS Codes
(160.2750) Materials : Glass and other amorphous materials
(160.4670) Materials : Optical materials
(160.4760) Materials : Optical properties
(160.6990) Materials : Transition-metal-doped materials

History
Original Manuscript: April 26, 2006
Revised Manuscript: June 7, 2006
Manuscript Accepted: June 23, 2006

Citation
Fouad El-Diasty, Manal Abdel-Baki, Fathy A. Abdel Wahab, and Hussein Darwish, "Dispersion and thermal properties of lithium aluminum silicate glasses doped with Cr3+ ions," Appl. Opt. 45, 7818-7825 (2006)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-45-30-7818


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References

  1. O. Güldal and C. Apak, "A study on Cr3+/Cr6+ equilibria in industrial emerald green glasses," J. Non-Cryst. Solids 38-39, 251-256 (1986).
  2. G. Fuxi, D. He, and L. Huiming, "Paramagnetic resonance study on transition metal ions in phosphate, fluorophosphate and fluoride glasses. Part I: Cr3+ and Mo3+," J. Non-Cryst. Solids 52, 135-141 (1985).
  3. Y. G. Choi, K. H. Kim, Y. S. Han, and J. Heo, "Oxidation state and local coordination of chromium dopant in soda-lime-silicate and calcium-aluminate glasses," Chem. Phys. Lett. 329, 370-376 (2000). [CrossRef]
  4. D. Godeke, M. Muller, and C. Russel, "Thermal radiation of chromium-doped glass melts," Glass. Sci. Technol. 47, 277-282 (2001).
  5. G. S. Rao and N. Veeraiah, "Influence of Cr33+ ions on the structure and certain physical properties of PbO-As2O3 glasses," Eur. Phys. J. Appl. Phys. 16, 11-22 (2001). [CrossRef]
  6. D. K. Durga and N. Veeraiah, "Physical properties of ZnF<2sub>-As<2sub>O<3sub>-TeO<2sub> glasses doped with Cr3+ ions," Physica B 324, 127-141 (2002). [CrossRef]
  7. X. Feng and S. Tanabe, "Spectroscopy and crystal-field analysis for Cr(IV) in alumino-silicate glasses," Opt. Mater. 20, 63-72 (2002). [CrossRef]
  8. A. Aboukaïs, L. D. Bogomolova, E. Cattaruzza, A. A. Deshkovskaya, N. A. Krasilnikova, S. A. Prushinsky, and E. A. Zhilinskaya, "Study of chromium states in silica glass implanted with Cr+ ions to high fluences," Opt. Mater. 22, 177-185 (2003). [CrossRef]
  9. A. M. Malyarevich, Yu. V. Volk, K. V. Yumashev, V. K. Pavlovskii, S. S. Zapalova, O. S. Dymshits, and A. A. Zhilin, "Absorption, emission and absorption saturation of Cr4+ ions in calcium aluminate glass," J. Non-Cryst. Solids 351, 3551-3555 (2005). [CrossRef]
  10. C. L. Kanth, B. V. Raghavaiah, B. Appa Rao, and N. Veeraiah, "Spectroscopic investigations on ZnF2-MO-TeO2 (MO=ZnO, CdO and PbO) glasses doped with chromium ions," J. Quant. Spectrosc. Radiat. Transfer 90, 97-113 (2005). [CrossRef]
  11. T. H. Maiman, R. H. Hoskins, I. T. D'Haenens, C. K. Aswa, and V. Evtuhov, "Stimulated optical emission in fluorescent solids. II. Spectroscopy and stimulated emission in ruby," Phys. Rev. 123, 1151-1157 (1961). [CrossRef]
  12. V. Petricevic, S. K. Gayen, and R. R. Alfano, "Laser action in chromium-activated forsterite for near-infrared excitation: is Cr4+ the lasing ion?," Appl. Phys. Lett. 53, 2590-2592 (1988). [CrossRef]
  13. M. A. Khashan and A. M. El-Naggar, "A new method of finding the optical constants of a solid from the reflectance and transmittance spectrograms of its slab," Opt. Commun. 174, 445-453 (2000). [CrossRef]
  14. C. Dayanand, G. Bhikshamaiah, and M. Salagram, "IR and optical properties of PbO glass containing a small amount of silica," Mater. Lett. 23, 309-315 (1995). [CrossRef]
  15. A. Paul, Chemistry of Glasses (Chapman & Hall, 1982). [CrossRef]
  16. R. W. Ditchburn, Light (Dover, 1991), p. 457.
  17. M. Born and E. Wolf, Principles of Optics (Pergamon, 1980), p. 93.
  18. V. Lucarini, F. Bassani, K. Peiponen, and J. J. Saarinen, "Dispersion theory and sum rules in linear and nonlinear optics," Rev. Nuovo Cimento 26, 1-120 (2003).
  19. S. H. Wemple and M. Di Domenico, "Behavior of the electronic dielectric constant in covalent and ionic materials," Phys. Rev. B 3, 1338-1351 (1971). [CrossRef]
  20. S. H. Wemple, "Refractive-index behavior of amorphous semiconductors and glasses," Phys. Rev. B 7, 3767-3777 (1973). [CrossRef]
  21. S. H. Wemple, "Material dispersion in optical fibers," Appl. Opt. 18, 31-35 (1979). [CrossRef] [PubMed]
  22. H. Poignant, "Dispersive and scattering properties of a ZrF4 based glass," Electron. Lett. 17, 973-974 (1981). [CrossRef]
  23. S. Hirota and T. Izumitani, "Effect of cations on the inherent absorption wavelength and the oscillator strength of ultraviolet absorptions in borate glasses," J. Non-Cryst. Solids 29, 109-117 (1978). [CrossRef]
  24. K. Nassau and S. H. Wemple, "Material dispersion slope in optical-fibre waveguides," Electron. Lett. 18, 450-451 (1982). [CrossRef]
  25. E. F. Chillcce, E. Rodriguez, A. A. R. Neves, W. C. Moreira, C. L. Cersar, and L. C. Barbosa, "Er3+-Tm3+ co-doped tellurite fibers for broadband optical fiber amplifier around 1550 nm band," Opt. Fiber Technol. 12, 185-195 (2006). [CrossRef]
  26. H. Darwish, S. N. Salama, and S. M. Salman, "Contribution of germanium dioxide to the thermal expansion characteristics of some borosilicate glasses and their corresponding glass-ceramics," Thermochim. Acta 374, 129-135 (2001). [CrossRef]
  27. G. Gavriliu, "Thermal expansion and characteristic points of −NaNa2O-SiONa2 glass with added oxides," J. Eur. Ceram. Soc. 22, 1375-1379 (2002). [CrossRef]
  28. J. Zarzycki, Glass and the Vitreous State (Cambridge U. Press, 1991).
  29. D. Huang, C. H. Drummond, J. Wang, and R. D. Blume, "Incorporation of chromium(III) and chromium(VI) oxides in a simulated basaltic, industrial waste glass-ceramic," J. Am. Ceram. Soc. 87, 2047-2052 (2004). [CrossRef]

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