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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: James C. Wyant
  • Vol. 45, Iss. 6 — Feb. 20, 2006
  • pp: 1275–1287

Multiwavelength discrimination and measurements of a two-gas mixture by use of a broadly tunable mid-infrared semiconductor laser

Chuan Peng, Han Q. Le, Rui Q. Yang, and Cory J. Hill  »View Author Affiliations


Applied Optics, Vol. 45, Issue 6, pp. 1275-1287 (2006)
http://dx.doi.org/10.1364/AO.45.001275


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Abstract

Spectroscopic detection of gases can be achieved by measuring a few species-specific absorption lines, requiring very accurate wavelength control. Alternatively, it can be achieved by using many wavelengths spread over a wide range; each wavelength need not be optimal spectroscopically, but all collectively form a unique fingerprint for the species of interest. Statistical regression can be used to quantify their concentrations. An experimental evaluation of this concept involved using a 3.1 μm broadly tunable Sb-based mid-IR laser to discriminate and measure mixtures of acetylene and water vapor with absorption spectral overlaps. As many as 30 wavelengths from 3200 to 3280   cm 1 were used to measure 5 × 5 combinations of the two-gas concentration. Statistical analysis of the results validates the concept. Each gas concentration was consistently and reliably measured without any problem of interference from the other. In addition, the method was sufficiently sensitivite to detect unusual discrepancies by use of statistical analysis. Optimization of the system's detection capability and its receiver-operating characteristics is demonstrated. The results suggest that the statistical multiwavelength broadband approach to detection of gas mixture can be a highly effective alternative to species-specific single-line spectroscopy.

© 2006 Optical Society of America

OCIS Codes
(140.3070) Lasers and laser optics : Infrared and far-infrared lasers
(140.3600) Lasers and laser optics : Lasers, tunable
(280.3420) Remote sensing and sensors : Laser sensors
(300.6340) Spectroscopy : Spectroscopy, infrared
(300.6360) Spectroscopy : Spectroscopy, laser

ToC Category:
Spectroscopy

History
Original Manuscript: July 21, 2005
Revised Manuscript: August 28, 2005
Manuscript Accepted: September 16, 2005

Citation
Chuan Peng, Han Q. Le, Rui Q. Yang, and Cory J. Hill, "Multiwavelength discrimination and measurements of a two-gas mixture by use of a broadly tunable mid-infrared semiconductor laser," Appl. Opt. 45, 1275-1287 (2006)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-45-6-1275

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