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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: James C. Wyant
  • Vol. 47, Iss. 31 — Nov. 1, 2008
  • pp: G99–G104

Elemental analysis of laser induced breakdown spectroscopy aided by an empirical spectral database

Steven Rock, Aristides Marcano, Yuri Markushin, Chandran Sabanayagam, and Noureddine Melikechi  »View Author Affiliations


Applied Optics, Vol. 47, Issue 31, pp. G99-G104 (2008)
http://dx.doi.org/10.1364/AO.47.000G99


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Abstract

Laser induced breakdown spectroscopy (LIBS) is commonly used to identify elemental compositions of various samples. To facilitate this task, we propose the use of an elemental spectral library for single-pulsed, nanosecond LIBS in the spectral range 198 968 nm . This spectroscopic library is generated by measuring optical emissions from plasmas of 40 pure elements. To demonstrate the usefulness of the proposed database, we measure and analyze the LIBS spectra of pure iron and of ethanol and show that we identify these samples with a high degree of certainty.

© 2008 Optical Society of America

OCIS Codes
(070.4790) Fourier optics and signal processing : Spectrum analysis
(160.2120) Materials : Elements
(300.6210) Spectroscopy : Spectroscopy, atomic
(350.5400) Other areas of optics : Plasmas
(300.6365) Spectroscopy : Spectroscopy, laser induced breakdown

History
Original Manuscript: March 31, 2008
Revised Manuscript: July 16, 2008
Manuscript Accepted: July 18, 2008
Published: September 10, 2008

Citation
Steven Rock, Aristides Marcano, Yuri Markushin, Chandran Sabanayagam, and Noureddine Melikechi, "Elemental analysis of laser induced breakdown spectroscopy aided by an empirical spectral database," Appl. Opt. 47, G99-G104 (2008)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-47-31-G99


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References

  1. K. E. Jarvis, A. L. Gray, and R. S. Houk, Handbook of Inductively Coupled Plasma Mass Spectrometry (Blackie Academic and Professional, 1992).
  2. P. W. J. M. Boumans, “Inductively coupled plasma-atomic emission spectroscopy: its present and future position in analytical chemistry,” Z. J. Anal. Chem. 299, 337-361(1979). [CrossRef]
  3. F. Yueh, J. Singh, and H. Zhang, “Laser-induced breakdown spectroscopy, elemental analysis,” in Encyclopedia of Analytical Chemistry (Wiley, 2000), pp. 2066-2087.
  4. M. Lawrence-Snyder, J. Scaffidi, S. M. Angel, A. P. Michel, and A. D. Chave, “Laser-induced breakdown spectroscopy of high-pressure bulk aqueous solutions,” Appl. Spectrosc. 60, 786-790 (2006). [CrossRef] [PubMed]
  5. P. Fichet, D. Menut, R. Brennetot, E. Vors, and A. Rivollan, “Analysis by laser-induced breakdown spectroscopy of complex solids, liquids, and powders with an echelle spectrometer,” Appl. Opt. 42, 6029-6035 (2003). [CrossRef] [PubMed]
  6. R. Knopp, F. J. Scherbaum, and J. I. Kim, “Laser induced breakdown spectroscopy (LIBS) as an analytical tool for the detection of metal ions in aqueous solutions,” Anal. Bioanal. Chem. 355, 16-20 (1996). [CrossRef] [PubMed]
  7. P. B. Dixon and D. W. Hahn, “Feasibility of detection and identification of individual bioaerosols using laser-induced breakdown spectroscopy,” Anal. Chem. 77, 631-638 (2005). [CrossRef] [PubMed]
  8. J. D. Hybl, G. A. Lithgow, and S. G. Buckley, “Laser-induced breakdown spectroscopy detection and classification of biological aerosols,” Appl. Spectrosc. 57, 1207-1215 (2003). [CrossRef] [PubMed]
  9. A. C. Samuels, F. C. DeLucia, K. L. McNesbby, and A. W. Miziolek, “Laser-induced breakdown spectroscopy of bacterial spores, molds, pollens, and protein: initial studies of discrimination potential,” Appl. Opt. 42, 6205-6209 (2003). [CrossRef] [PubMed]
  10. E. Vors and L. Salmon, “Laser-induced breakdown spectroscopy (LIBS) for carbon single shot analysis of micrometer-sized particles,” Anal. Bioanal. Chem. 385, 281-286 (2006). [CrossRef] [PubMed]
  11. Y. Lee, K. Song, and J. Sneddon, Laser-Induced Breakdown Spectrometry (Nova Science, 2000).
  12. T. Hussain and M. A. Gondal, “Monitoring and assessment of toxic metals in Gulf War Oil Spill contaminated soil using laser-induced breakdown spectroscopy,” Environ Monit. Assess. 136, 391-399 (2007). [CrossRef] [PubMed]
  13. V. Sturm and R. Noll, “Laser-induced breakdown spectroscopy of gas mixtures of air, CO2, N2, and C3H8 for simultaneous C, H, O, and N measurement,” Appl. Opt. 42, 6221-6225 (2003). [CrossRef] [PubMed]
  14. T. Hussain, M. A. Gondal, Z. H. Yamani, and M. A. Baig, “Measurement of nutrients in green house soil with laser-induced breakdown spectroscopy,” Environ. Monit. Assess. 124, 131-139 (2007). [CrossRef]
  15. Z. A. Arp, D. A. Cremers, R. C. Wiens, D. M. Wayne, B. Sallé, and S. Maurice, “Analysis of water ice and water ice/soil mixtures using laser-induced breakdown spectroscopy: application to Mars polar exploration, ”Appl. Spectrosc. 58, 897-909(2004). [CrossRef] [PubMed]
  16. A. K. Rai, F. Y. Yueh, and J. P. Singh, “Laser-induced breakdown spectroscopy of molten aluminum alloy,” Appl. Opt. 42, 2078-84 (2003). [CrossRef] [PubMed]
  17. F. R. Doucet, T. F. Belliveau, J. L. Fortier, and J. Hubert, “Use of chemometrics and laser-induced breakdown spectroscopy for quantitative analysis of major and minor elements in aluminum alloy,” Appl. Spectrosc. 61, 327-32 (2007). [CrossRef] [PubMed]
  18. M. A. Gondal A, T. Hussain, Z. H. Yamani, and A. H. Bakry, “Study of hazardous metals in iron slag waste using laser-induced breakdown spectroscopy,” J. Environ. Sci. Health, Part A Toxic/Hazard. Subst. Environ. Eng. 42, 767-775 (2007). [CrossRef]
  19. K. Loebe, A. Uhl, and H. Lucht, “Microanalysis of tool steel and glass with laser-induced breakdown spectroscopy,” Appl. Opt. 42, 6166-6173 (2003). [CrossRef] [PubMed]
  20. National Institute of Standards and Technology, http://physics.nist.gov/PhysRefData/ASD/index.html
  21. United States Army Research Laboratory,http://www.arl.army.mil/www/default.cfm?Action=247&Page=250
  22. F. J. Gordillo-Vazquez, A. Perea, A. P. McKiernan, and C. N. Afonso, “Electronic temperature and density of the plasma produced by nanosecond ultraviolet laser ablation of LiF,” Appl. Phys. Lett. 86, 181501 (2005). [CrossRef]
  23. M. Capitelli, A. Casavola, G. Colonna, and A. De Giacomo, “Laser-induced plasma expansion: theoretical and experimental aspects,” Spectrochim. Acta, Part B 59271-289(2004) . [CrossRef]

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