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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: Joseph N. Mait
  • Vol. 49, Iss. 13 — May. 1, 2010
  • pp: C75–C79

Guided conversion to enhance cation detection in water using laser-induced breakdown spectroscopy

Yuan Lu, Ying Li, Jianglai Wu, Shilei Zhong, and Ronger Zheng  »View Author Affiliations


Applied Optics, Vol. 49, Issue 13, pp. C75-C79 (2010)
http://dx.doi.org/10.1364/AO.49.000C75


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Abstract

A novel approach, named guided conversion enhancement, has been established to improve the laser-induced breakdown spectroscopy (LIBS) sensitivity of cation detection in water. Two processes were involved in this approach: the main part was replacement reaction that converted the cations in water to solid granules on the surface of an immersed metallic sheet; the other was electric assistance that increased local cation concentration and strengthened the reaction. With the aid of replacement reaction and an electric field, a detection limit of 16 ppb was achieved for copper cation ( Cu 2 + ) detection in a water solution of Cu SO 4 . The obtained results suggest that this approach has significant potential to be developed as an effective method for underwater cation detection.

© 2010 Optical Society of America

OCIS Codes
(140.3440) Lasers and laser optics : Laser-induced breakdown
(300.6210) Spectroscopy : Spectroscopy, atomic
(350.5400) Other areas of optics : Plasmas
(300.6365) Spectroscopy : Spectroscopy, laser induced breakdown

History
Original Manuscript: September 30, 2009
Revised Manuscript: February 1, 2010
Manuscript Accepted: February 1, 2010
Published: March 3, 2010

Citation
Yuan Lu, Ying Li, Jianglai Wu, Shilei Zhong, and Ronger Zheng, "Guided conversion to enhance cation detection in water using laser-induced breakdown spectroscopy," Appl. Opt. 49, C75-C79 (2010)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-49-13-C75


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References

  1. C. Pasquini, J. Cortez, L. M. C. Silva, and F. B. Gonzaga, “Laser induced breakdown spectroscopy,” J. Braz. Chem. Soc. 18, 463-512 (2007). [CrossRef]
  2. M. Hananfi, M. M. Omar, and Y. E. Gamal, “Study of laser-induced breakdown spectroscopy of gases,” Radiat. Phys. Chem. 57, 11-20 (2000). [CrossRef]
  3. R. Bruder, D. L'Hermite, A. Semerok, L. Salmon, and V. Detalle, “Near-crater discoloration of white lead in wall paintings during laser induced breakdown spectroscopy analysis,” Spectrochim. Acta Part B 62, 1590-1596 (2006). [CrossRef]
  4. S. Rosenwasser, G. Asimellis, B. Bromley, R. Hazlett, J. Martin, and A. Zigler, “Development of a method for automated quantitative analysis of ores using LIBS,” Spectrochim. Acta Part B 56, 707-714 (2001). [CrossRef]
  5. B. Bousquet, J.-B. Sirven, and L. Canioni, “Towards quantitative laser-induced breakdown spectroscopy analysis of soil samples,” Spectrochim. Acta Part B 62, 1582-1589 (2007). [CrossRef]
  6. V. Burakov, N. Tarasenko, M. Nedelko, and S. Isakov, “Time-resolved spectroscopy and imaging diagnostics of single pulse and collinear double pulse laser induced plasma from a glass sample,” Spectrochim. Acta Part B 63, 19-26 (2008). [CrossRef]
  7. S. Acquqviva, E. D'Anna, M. L. De Giorgi, and F. Moro, “Laser-induced breakdown spectroscopy for compositional analysis of multielemental thin films,” Spectrochim. Acta Part B 61, 810-816 (2006). [CrossRef]
  8. C. Lopez-Moreno, S. Palanco, J. J. Laserna, F. Delucia, Jr., A. W. Miziolek, J. Rose, R. A. Walters, and A. I. Whitehouse, “Test of a stand-off laser-induced breakdown spectroscopy sensor for the detection of explosive residues on solid surfaces,” J. Anal. At. Spectrom. 21, 55-60 (2006). [CrossRef]
  9. R. S. Harmon, F. C. Delucia, C. E. McManus, N. J. McMillan, T. F. Jenkins, M. E. Walsh, and A. Miziolek, “Laser-induced breakdown spectroscopy: an emerging chemical sensor technology for real-time field-portable, geochemical, mineralogical, and environmental applications,” Appl. Geochem. 21, 730-747 (2006). [CrossRef]
  10. B. Salle, J.-L. Lacour, E. Vors, P. Fichet, S. Maurice, D. A. Cremers, and R. C. Wiens, “Laser-induced breakdown spectroscopy for Mars surface analysis: capabilities at stand-off distances and detection of chlorine and sulfur elements,” Spectrochim. Acta Part B 59, 1413-1422 (2004). [CrossRef]
  11. X. K. Shen, H. Wang, Z. Q. Xie, Y. Gao, H. Ling, and Y. F. Lu, “Detection of trace phosphorus in steel using laser-induced breakdown spectroscopy combined with laser-induced fluorescence,” Appl. Opt. 48, 2551-2558 (2009). [CrossRef] [PubMed]
  12. L. Dai, C. Wang, J. Wu, Y. Li, Z. Cui, and R. Zheng, “Laser-induced breakdown spectroscopy characterization of Al in different matrix,” Opto-electron. Lett. 3, 148-151 (2007).
  13. J. Wu, Y. Fu, Y. Li, Y. Lu, Z. Cui, and R. Zheng, “Detection of metal ions in water solution by laser induced breakdown spectroscopy,” Spectrosc. Spectral Anal. (Beijing) 28, 1979-1982(2008).
  14. J. O. Caceres, J. Torneto-Lopez, H. H. Telle, and A. Gonzalez-Urena, “Quantitative analysis of trace metal ions in ice using laser-induced breakdown spectroscopy,” Spectrochim. Acta Part B 56, 831-838 (2001). [CrossRef]
  15. V. N. Rai, A. Kunnar, F. Y. Yueh, and J. P. Singh, “Enhancement in the sensitivity of LIBS using magnetic field and sequential double laser pulse,” in Laser-Induced Breakdown Spectroscopy (Optical Society of America, 2002), paper ThE24-1-3.
  16. P. Yaroshchyk, R. J. S. Morrison, D. Body, and B. L. Chadwick, “Quantitative determination of wear metals in engine oils using LIBS: the use of paper substrates and a comparison between single- and double-pulse LIBS,” Spectrochim. Acta Part B 60, 1482-1485 (2005). [CrossRef]
  17. C. R. Dockery, J. E. Pender, and S. R. Goode, “Speciation of chromium via laser-induced nreakdown spectroscopy of ion exchange polymer membranes,” Appl. Spectrosc. 59, 252-257 (2005). [CrossRef] [PubMed]
  18. D. M. Diaz Pace, C. A. D'Angelo, D. Bertuccelli, and G. Bertyccelli, “Analysis of heavy metals in liquids using laser induced breakdown spectroscopy by liquid-to-solid matrix conversion,” Spectrochim. Acta Part B 61, 929-933 (2006). [CrossRef]
  19. Z. Chen, H. Li, M. Liu, and R. Li, “Fast and sensitive trace metal analysis in aqueous solution by laser-induced breakdown spectroscopy using wood slice substrates,” Spectrochim. Acta Part B 63, 64-68 (2008). [CrossRef]
  20. Z. Chen, H. Li, F. Zhao, and R. Li, “Ultra-sensitive trace metal analysis of water by laser-induced breakdown spectroscopy after electrical-depositon of the analytes on an aluminum surface,” J. Anal. At. Spectrom. 23, 871-875 (2008). [CrossRef]

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