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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: Joseph N. Mait
  • Vol. 49, Iss. 13 — May. 1, 2010
  • pp: C8–C15

Identification of vapor-phase chemical warfare agent simulants and rocket fuels using laser-induced breakdown spectroscopy

Jaime A. Stearns, Sarah E. McElman, and James A. Dodd  »View Author Affiliations


Applied Optics, Vol. 49, Issue 13, pp. C8-C15 (2010)
http://dx.doi.org/10.1364/AO.49.0000C8


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Abstract

Application of laser-induced breakdown spectroscopy (LIBS) to the identification of security threats is a growing area of research. This work presents LIBS spectra of vapor-phase chemical warfare agent simulants and typical rocket fuels. A large dataset of spectra was acquired using a variety of gas mixtures and background pressures and processed using partial least squares analysis. The five compounds studied were identified with a 99% success rate by the best method. The temporal behavior of the emission lines as a function of chamber pressure and gas mixture was also investigated, revealing some interesting trends that merit further study.

© 2010 Optical Society of America

OCIS Codes
(140.3440) Lasers and laser optics : Laser-induced breakdown
(300.2140) Spectroscopy : Emission
(300.6210) Spectroscopy : Spectroscopy, atomic
(300.6365) Spectroscopy : Spectroscopy, laser induced breakdown

History
Original Manuscript: October 2, 2009
Revised Manuscript: December 31, 2009
Manuscript Accepted: January 4, 2010
Published: February 3, 2010

Citation
Jaime A. Stearns, Sarah E. McElman, and James A. Dodd, "Identification of vapor-phase chemical warfare agent simulants and rocket fuels using laser-induced breakdown spectroscopy," Appl. Opt. 49, C8-C15 (2010)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-49-13-C8


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