Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group

Solid State Studies by Means of Fourier Transform Spectroscopy

Not Accessible

Your library or personal account may give you access

Abstract

A commercially available Michelson interferometer has been adapted to meet the needs of our research. Transmission and reflection measurements of solid state materials can be made over the wavelength range of 25–1000 μ (400–10 cm−1). Provision has been made for the samples in each case to be studied from 4°K to 700°K with suitable cryostats and heated sample holders. These devices can easily be interchanged in the interferometer and also in a single beam far ir vacuum gratings pectrometer so that the measurements can be duplicated when necessary, using conventional spectroscopic techniques. The interferometer has the unique advantage of covering a broad frequency range without changing the operating conditions. A suitable choice of beam splitter thickness and ionic crystal powder filter combinations provides maximum efficiency in the area of interest. The region beyond 250 μ shows a rapid deterioration in signal to noise, and the relative merits of various cooled detectors and the Golay detector have been studied. Polarization measurements on solids have also been of interest, and various polarizers have been investigated. Applications of interferometry applied to a number of solid state problems are described. These include the dielectric dispersion in perovskites, compound semiconductors, internal molecular and lattice vibrations in inorganic materials and other related compounds. The relative advantages of single-sided vs double-sided interferograms in terms of accurate intensity measurements are compared. Examples of each are discussed.

© 1966 Optical Society of America

Full Article  |  PDF Article
More Like This
The History and Current Status of Fourier Transform Spectroscopy

Ernest V. Loewenstein
Appl. Opt. 5(5) 845-854 (1966)

High-Resolution Fourier Transform Spectroscopy in the Far-Infrared

P. L. Richards
J. Opt. Soc. Am. 54(12) 1474-1484 (1964)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Figures (10)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (1)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (7)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All rights reserved, including rights for text and data mining and training of artificial technologies or similar technologies.