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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Editor: Joseph N. Mait
  • Vol. 52, Iss. 23 — Aug. 10, 2013
  • pp: 5606–5610

Photoluminescence properties of Tm3+/Tb3+/Eu3+ tri-doped phosphate glass and glass ceramics for white-light-emitting diodes

Yin Yu, Feng Song, Chengguo Ming, Jun Zhang, and Fengxiao Wang  »View Author Affiliations


Applied Optics, Vol. 52, Issue 23, pp. 5606-5610 (2013)
http://dx.doi.org/10.1364/AO.52.005606


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Abstract

Tm3+/Tb3+/Eu3+ tri-doped phosphate glasses are synthesized to explore new white-light-emitting materials. Under 365 nm excitation, the CIE coordinates (x=0.339, y=0.341) of the Eu0.07 glass sample are close to the standard equal energy white-light illumination (x=0.333, y=0.333). The quantum efficiency is very high (72.27%). The energy transition from Tb3+ to Eu3+ is reasonably interpreted based on the analysis of the luminescence lifetimes. To enhance the white-light emission, Tm3+/Tb3+/Eu3+ tri-doped phosphate glass ceramics are prepared.

© 2013 Optical Society of America

OCIS Codes
(160.4670) Materials : Optical materials
(160.4760) Materials : Optical properties
(160.5690) Materials : Rare-earth-doped materials
(260.2160) Physical optics : Energy transfer

ToC Category:
Physical Optics

History
Original Manuscript: April 3, 2013
Revised Manuscript: May 21, 2013
Manuscript Accepted: May 25, 2013
Published: August 5, 2013

Citation
Yin Yu, Feng Song, Chengguo Ming, Jun Zhang, and Fengxiao Wang, "Photoluminescence properties of Tm3+/Tb3+/Eu3+ tri-doped phosphate glass and glass ceramics for white-light-emitting diodes," Appl. Opt. 52, 5606-5610 (2013)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-52-23-5606


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References

  1. C. Jiang and W. B. Xu, “Theoretical model of Yb3+-Er3+-Tm3+-codoped system for white light generation,” J. Display Technol. 5, 312–318 (2009). [CrossRef]
  2. W. B. Xu and C. Jiang, “Modeling of tunable luminescence in multiple rare earth co-doped glasses,” J. Display Technol. 6, 298–305 (2010). [CrossRef]
  3. C. Jiang and W. B. Xu, “Modeling multiple rare earth-doped system for white light generation,” J. Display Technol. 5, 431–437 (2009). [CrossRef]
  4. C. C. Lin, Y. S. Tang, S. F. Hu, and R. S. Liu, “KBaPO4:Ln (Ln=Eu, Tb, Sm) phosphors for UV excitable white light-emitting diodes,” J. Lumin. 129, 1682–1684 (2009). [CrossRef]
  5. X. G. Zhang and M. L. Gong, “Eu2+-doped halo-phosphate/borate phosphors for color temperature tunable near UV-based white light-emitting diodes,” Mater. Chem. Phys. 124, 1243–1247 (2010). [CrossRef]
  6. F. Xiao, Y. N. Xue, Y. Y. Ma, and Q. Y. Zhang, “Ba2Ca(B3O6):Eu2+, Mn2+: a potential tunable blue–white–red phosphors for white light-emitting diodes,” Phys. B 405, 891–895 (2010). [CrossRef]
  7. Y. Narukawa, I. Niki, K. Izuno, M. Yamada, Y. Murazki, and T. Mukai, “Phosphor-conversion white light emitting diode using InGaN near-ultraviolet chip,” Jpn. J. Appl. Phys. 41, 371–373 (2002). [CrossRef]
  8. Z. J. Chao, C. Parent, G. L. Flem, and P. Hagenmuller, “White light emitting glasses,” J. Solid State Chem. 93, 17–29 (1991). [CrossRef]
  9. H. Lin, S. Tanabe, L. Lin, D. L. Yang, K. Liu, W. H. Wong, J. Y. Yu, and E. Y. B. Pun, “Infrequent blue and green emission transitions from Eu3+ in heavy metal tellurite glasses with low phonon energy,” Phys. Lett. A 358, 474–477 (2006). [CrossRef]
  10. S. Liu, G. Zhao, H. Ying, J. Wang, and G. Han, “Eu/Dy ions co-doped white light luminescence zinc–aluminoborosilicate glasses for white LED,” Opt. Materials 31, 47–50 (2008). [CrossRef]
  11. G. Lakshminarayana, H. Yang, and J. Qiu, “White light emission from Tm3+/Dy3+ co-doped oxyfluoride germanate glasses under UV light excitation,” J. Solid State Chem. 182, 669–676 (2009). [CrossRef]
  12. P. Babu, K. H. Jang, E. S. Kim, L. Shi, H. J. Seo, F. E. Lopez, U. R. Rodriguez-Mendoza, V. Lavin, R. Vijaya, C. K. Jayasankarm, and L. R. Moorthy, “Spectral investigations on Dy3+-doped transparent oxyfluoride glasses and nanocrystalline glass ceramics,” J. Appl. Phys. 105, 013516 (2009). [CrossRef]
  13. Q. Luo, X. Qiao, X. Fan, H. Yang, X. Zhang, S. Cui, L. Wang, and G. Wang, “Luminescence behavior of Ce3+ and Dy3+ codoped oxyfluoride glasses and glass ceramics containing LaF3 nanocrystals,” J. Appl. Phys. 105, 043506 (2009). [CrossRef]
  14. Y. Zheng and A. G. Clare, “Rare earth doped glasses for conversion of near ultraviolet light to white light,” Phys. Chem. Glasses 46, 467–471 (2005).
  15. D. Chen, Y. Wang, K. Zheng, T. Guo, Y. Yu, and P. Huang, “Bright upconversion white light emission in transparent glass ceramic embedding Tm3+/Er3+/Yb3+:β-YF3 nanocrystals,” Appl. Phys. Lett. 91, 251903 (2007). [CrossRef]
  16. A. S. Gouveia-Neto, L. A. Bueno, R. F. do Nascimento, E. A. da Silva, E. B. da Costa, and V. B. do Nascimento, “White light generation by frequency upconversion in Tm3+/Ho3+/Yb3+-codoped fluorolead germanate glass,” Appl. Phys. Lett. 91, 091114 (2007). [CrossRef]
  17. N. K. Giri, D. K. Rai, and S. B. Rai, “White light upconversion emissions from Tm3++Ho3++Yb3+ codoped tellurite and germanate glasses on excitation with 798 nm radiation,” J. Appl. Phys. 104, 113107 (2008). [CrossRef]
  18. D. Tu, Y. J. Liang, R. Liu, and D. Y. Li, “Eu/Tb ions co-doped white light luminescence Y2O3 phosphors,” J. Lumin. 131, 2569–2573 (2011). [CrossRef]
  19. X. M. Zhang, W. L. Li, and H. J. Seo, “Luminescence and energy transfer in Eu2+, Mn2+ co-doped Li4SrCa(SiO4)2 for white light-emitting-diodes,” Phys. Lett. A 373, 3486–3489 (2009). [CrossRef]
  20. J. Sokolnicki, “Rare earths (Ce, Eu, Tb) doped Y2Si2O7 phosphors for white LED,” J. Lumin. 134, 600–606 (2013). [CrossRef]
  21. R. Mart, A. Speghini, M. Bettinelli, C. Falcony, and U. Caldino, “White light generation through the zinc metaphosphate glass activated by Ce3+, Tb3+ and Mn2+ ions,” J. Lumin. 129, 1276–1280 (2009). [CrossRef]
  22. S. Das, A. A. Reddy, S. S. Babu, and G. V. Prakash, “Controllable white light emission from Dy3+-Eu3+ co-doped KCaBO3 phosphor,” J. Mater. Sci. 46, 7770–7775 (2011). [CrossRef]
  23. R. G. Ye, S. Q. Xu, D. G. Deng, Y. J. Hua, H. P. Wang, C. X. Li, S. L. Zhao, and L. H. Huang, “Luminescence and energy transfer of Eu2+/Mn2+ co-doped SiO2-Al2O3-ZnO-K2O glass ceramics for white LEDs,” J. Lumin. 130, 2385–2389 (2010). [CrossRef]
  24. G. Zhu, Y. H. Wang, Z. P. Ci, B. T. Liu, Y. R. Shi, and S. Y. Xin, “Ca8Mg(SiO4)(4)Cl-2:Ce3+, Tb3+: a potential single-phased phosphor for white-light-emitting diodes,” J. Lumin. 132, 531–536 (2012). [CrossRef]

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