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Applied Optics

Applied Optics

APPLICATIONS-CENTERED RESEARCH IN OPTICS

  • Vol. 6, Iss. 1 — Jan. 1, 1967
  • pp: 87–93

Laser Probe Excitation in Spectrochemical Analysis. II: Investigation of Quantitative Aspects

Stanley D. Rasberry, Bourdon F. Scribner, and Marvin Margoshes  »View Author Affiliations


Applied Optics, Vol. 6, Issue 1, pp. 87-93 (1967)
http://dx.doi.org/10.1364/AO.6.000087


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Abstract

A study has been made of quantitative analysis by a laser probe with spark excitation of the sample vapor. Random errors come largely from variations in laser energy and from photometric errors. The parameters of the spark circuit affect the line intensities; however, these factors are well controlled. Correlations have been established between the energy of the laser beam, the size of the pit formed, and spectral intensities. For most purposes, single-spike laser operation has been found to be preferable to multiple-spike operation. At present, the coefficients of variation for analysis are 15% to 40%.

© 1967 Optical Society of America

History
Original Manuscript: July 27, 1966
Published: January 1, 1967

Citation
Stanley D. Rasberry, Bourdon F. Scribner, and Marvin Margoshes, "Laser Probe Excitation in Spectrochemical Analysis. II: Investigation of Quantitative Aspects," Appl. Opt. 6, 87-93 (1967)
http://www.opticsinfobase.org/ao/abstract.cfm?URI=ao-6-1-87


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References

  1. S. D. Rasberry, B. F. Scribner, M. Margoshes, Appl. Opt. 6, 81 (1967). [CrossRef] [PubMed]
  2. C. H. Corliss, Spectrochim. Acta 5, 378 (1953). [CrossRef]
  3. R. E. Michaelis, H. Yakowitz, G. A. Moore, National Bureau of Standards Miscellaneous Publication 260-3 (1964).
  4. H. Piepmeier, H. V. Malmstadt, Paper 128, Fifth National Meeting, Society for Applied Spectroscopy, Chicago, June 1966 (Abstract).
  5. J. F. Ready, J. Appl. Phys. 36, 462 (1965). [CrossRef]
  6. H. T. Yura, Rand Corporation Memorandum No. RM3560-PR (1963).
  7. G. A. Klotzbaugh, A. L. Wolfe, J. E. Paterson, T. A. Osial, Report to Air Force Cambridge Research Laboratories, Contract No. AF19 (628)-4184 (1965).

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