Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 40,
  • Issue 8,
  • pp. 1103-1107
  • (1986)

Phase Transitions and Surface Characterization of Poly (Butylene Terephthalate) Fibers by Photoacoustic and Diffuse Reflectance Fourier Transform Infrared Spectroscopy

Not Accessible

Your library or personal account may give you access

Abstract

Diffuse reflectance and photoacoustic (PAS) IR techniques are used for spectral measurements of poly(butylene terephthalate) (PBT) fibers. The spectral observations on the fibers are similar to those observed in films. The stress-induced phase transformation is reversible with annealing of the drawn fibers. The annealing process also increases the amount of crystallinity in the fiber. With the use of recently developed PAS methodology to study orientation of the surface species, the orientation of surface aromatic and carbonyl groups is analyzed. In the alpha phase, the surface aromatic rings are preferentially perpendicular on the surface whereas carbonyl groups are preferentially parallel. A similar orientation is observed in the drawn fibers. Annealing of the drawn fibers changes the orientation of the aromatic rings. Upon annealing, the phenyl rings are preferentially parallel to the surface. The depth of penetration at 3000 cm<sup>−1</sup> in PBT fibers is found to be approximately 4 μ.

PDF Article
More Like This
Photoacoustic phase-controlled Fourier-transform infrared spectroscopy

Santeri Larnimaa, Mikhail Roiz, and Markku Vainio
Opt. Continuum 2(3) 564-578 (2023)

Quantitative Fourier transform IR photoacoustic spectroscopy of condensed phases

Y. C. Teng and B. S. H. Royce
Appl. Opt. 21(1) 77-80 (1982)

High temperature Fourier transform photoacoustic spectroscopy: sample emission effects

S. McGovern, B. S. H. Royce, and J. Benziger
Appl. Opt. 24(10) 1512-1514 (1985)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved