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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 47,
  • Issue 5,
  • pp. 654-664
  • (1993)

Correlation of the Molecular Structure and Spectral Characteristics of Some Hydroxamic Acid Derivatives

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Abstract

The electronic absorption spectra of some hydroxamic acid oxime derivatives and Schiff's base derivatives in polar (ethanol) and nonpolar (CCl<sub>4</sub>) solvents, as well as in some other organic solvents of different polarities, were investigated; the variation of absorbance with pH was utilized for the determination of pK<sub>a</sub> and Δ<i>G</i>* values. The important bands in the IR spectra as well as the main signals of the NMR spectra are also discussed in relation to the molecular structure.

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