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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 65,
  • Issue 9,
  • pp. 1068-1072
  • (2011)

Chiral Self-Assembly/Disassembly Transition of Supramolecular Aggregates Characterized by Variable Temperature Circular Dichroism Spectroscopy

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Abstract

Self-assembly and disassembly behavior of a series of chiral sorbitol-based derivatives in n-octanol were investigated by using the variable temperature circular dichroism (CD) technique. An attempt has been made to establish a novel strategy for the characterization of the self-assembly/disassembly transition by measuring the difference of CD signals of chiral aggregates.

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