Abstract

Mass spectra of seventeen bis(alkylmercapto) alkanes of the general formula R.S.C_nH_2nS R are presented and discussed Major ions occur by· 1) simple C-C or C-S cleavage to give ions of the type R S C_mH_2m+1⁺; 2) cleavage of a C-S bond accompanied by hydrogen rearrangement; and 3) further loss of an alkyl group. The consecutive nature of breakdown in cases of double cleavage and rearrangement is established by metastable transitions.

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Infrared and Raman Spectra of Some Tin-Alkyls

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