OSA's Digital Library

Applied Spectroscopy

Applied Spectroscopy

| PUBLISHED BY SAS — AVAILABLE FROM SAS AND OSA

  • Vol. 19, Iss. 5 — Sep. 1, 1965
  • pp: 150–154

The Nuclear Magnetic Resonance Spectra of Compounds Related to DDT. I. Non-Aromatic Protons

Norman E. Sharpless and Robert B. Bradley

Applied Spectroscopy, Vol. 19, Issue 5, pp. 150-154 (1965)


View Full Text Article

Acrobat PDF (444 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations
  • Export Citation/Save Click for help

Abstract

The nuclear magnetic resonance spectra of a series of compounds related to DDT have been studied as they are influenced by ring or aliphatic substituents or by aliphatic structural changes The chemical shift of the benzylic or α proton follows the Hammett equation for ring substituents and the Taft variation of this equation for aliphatic substituents. Alkoxy substituents on the ring show alternation of chemical shift of the –OCH2– group protons with chain length and limiting behavior of the terminal methyl group with chain length. Dehydrochlorination of o,p-DDD produces cis-trans isomers. Coupling constants are shown to be influenced by ring substitution, particularly ortho chlorine.

Citation
Norman E. Sharpless and Robert B. Bradley, "The Nuclear Magnetic Resonance Spectra of Compounds Related to DDT. I. Non-Aromatic Protons," Appl. Spectrosc. 19, 150-154 (1965)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-19-5-150


Sort:  Journal  |  Reset

References

References are not available for this paper.

Cited By

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited