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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 22,
  • Issue 4,
  • pp. 297-304
  • (1968)

Infrared and Raman Studies of Arsenic Compounds

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Abstract

It was found that water solutions of arsenic oxide contain the compounds As<sub>4</sub>O<sub>6</sub> · XH<sub>2</sub>O and As(OH)<sub>3</sub>. The acid OAsOH is not present in these solutions. The presence of alkali halide in arsenic oxide solutions results in the formation of an <i>ortho</i> arsenite. Oxyarsenic halides and AsCl<sub>4</sub>− are not present in solutions of AsCl<sub>3</sub>. The stability of these ions is questioned.

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