Abstract

The infrared studies in connection with the bidentate complexes of <i>o</i>-phenylenediamine were directed toward the study of N–H vibrations. Similar investigations have been undertaken with regard to the N–H stretching and bending vibrations of aniline and α-naphthylamine. Deuteration studies were made. As a result of these studies and by comparison with the assignment of frequencies made in the above mentioned investigations, stretching, scissors, and wagging frequencies are assigned to the chelates of <i>o</i>-phenylenediamine. The absorption in the region of ND₂ wagging vibrations of the deuterated palladium complex failed to show splitting and therefore coupling with the C–H out-of-plane vibrations, as was evident in the spectra of the corresponding complexes of α-napthylamine and aniline.

Comparison of the frequencies of NH₃, CO₂, H₂O, N₂O, CO, and CH₄ as infrared calibration standards

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Diagnosis of methylglyoxal in blood by using far-infrared spectroscopy and o-phenylenediamine derivation

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N₂ and CO vibrational CARS and H₂ rotational CARS spectroscopy of CH₄/N₂O flames

Kenneth Aron, Leonce E. Harris, and Joanne Fendell
Appl. Opt. 22(22) 3604-3611 (1983)

Some Observations on the Use of Elliptically Polarized Light to Study Metal Surfaces*

Frederick P. Mertens, Paul Theroux, and Robert C. Plumb
J. Opt. Soc. Am. 53(7) 788-796 (1963)

Mechanism of Energy Transfer in Some Rare-Earth Chelates

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Appl. Opt. 4(S1) 214-215 (1965)