Abstract
Savings in man-hours of approximately 50% were gained with even greater reduction in elapsed time when fluorescent x-ray emission replaced classical wet methods to determine Sb (2%–7%), Sn (0.15%–0.75%) and As (0.05%–0.60%). No statistically significant differences were found in results, and scatter was less with the x-ray method. The problem of segregation in the sample was eliminated, and a surface of the required quality was obtained by a special method of sample preparation in which 5–20 ml of molten lead was poured into 1 liter of water, and the resulting granules were pressed to 95% density briquettes at 50 000 psi. The working curves, linear in the ranges stated, were established from alloys calibrated by the classical methods. Standard deviations were calculated from repeated x-ray determinations on a reference alloy (Sb: 5.89%±0.043; Sn: 0.36%±0.012; As: 0.175%±0.008).
PDF Article
More Like This
Cited By
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Login to access Optica Member Subscription