Abstract
The infrared and Raman spectra of the bis(2-ethylhexyl)phosphoric acids [(C<sub>8</sub>H<sub>17</sub>O)<sub>2</sub>PO(OH), (C<sub>8</sub>H<sub>17</sub>O)<sub>2</sub>PO(OD)] and its sodium salt (C<sub>8</sub>H<sub>17</sub>O)<sub>2</sub>PO(ONa) were obtained from 4000-100 cm<sup>−1</sup>. On the basis of an approximate normal coordinate treatment and using a cyclic dimeric model, theoretical band assignments were made. These results were compared with those obtained for dimethylphosphinic acid.
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