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Applied Spectroscopy

Applied Spectroscopy

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  • Vol. 24, Iss. 1 — Jan. 1, 1970
  • pp: 36–41

n-π* Electronic Emission and Absorption Spectra of o-Fluorobenzaldehyde in Vapor Phase

M. P. Srivastava and I. S. Singh

Applied Spectroscopy, Vol. 24, Issue 1, pp. 36-41 (1970)


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Abstract

The electronic emission and absorption spectra of o-fluorobenzaldehyde have been studied. The emission spectrum recorded on a Fuess glass and a medium quartz spectrograph lies in the region 26 668–17 862 cm−1 and the absorption spectrum recorded on a Zeiss Q–24 medium quartz spectrograph lies in the region 30 995–24 610 cm−1. The O-O band has been observed at 26 337 cm−1. The C=O stretching frequency 1733 cm−1 in the ground state and 1355 cm−1 in the excited state is most intense and forms progressions of bands both in the emission and absorption spectra. The observed bands have been interpreted as combinations of the C=O stretching frequency and its multiples with other fundamentals. The transition involved is A'–A" (n-π*).

Citation
M. P. Srivastava and I. S. Singh, "n-π* Electronic Emission and Absorption Spectra of o-Fluorobenzaldehyde in Vapor Phase," Appl. Spectrosc. 24, 36-41 (1970)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-24-1-36


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