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Applied Spectroscopy

Applied Spectroscopy

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  • Vol. 24, Iss. 1 — Jan. 1, 1970
  • pp: 53–59

Electronic Absorption and Fluorescence Spectra of Matrix-Isolated CoCl2 Molecules

J. R. Clifton and D. M. Gruen

Applied Spectroscopy, Vol. 24, Issue 1, pp. 53-59 (1970)


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Abstract

The absorption spectrum of CoCl2 molecules isolated in a nitrogen matrix and the fluorescence spectrum of CoCl2 molecules isolated in an argon matrix have been measured at liquid helium temperatures in the range 4000–50 000 cm−1. The absorption and fluorescence spectra in the 4000–25 000 cm−1 region were not mutually observable in the same host. Interpretations of the spectra are given, based on axial ligand field calculations for a 3d7 configuration including spin-orbit coupling interactions.

Citation
J. R. Clifton and D. M. Gruen, "Electronic Absorption and Fluorescence Spectra of Matrix-Isolated CoCl2 Molecules," Appl. Spectrosc. 24, 53-59 (1970)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-24-1-53


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